• Title/Summary/Keyword: Inert gas

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Anaerobic/Aerobic Biological Reaction Characteristics of the Marine Products Industry Wastewater (수산물가공폐수의 혐기.호기 생물학적 반응특성)

  • Choi, Yong-Bum;Kim, Gau-You;Kwon, Jae-Hyouk
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.452-458
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    • 2008
  • This study was undertaken to establish the biological reaction characteristics of the marine products industry wastewater which contains high concentrations of organic matter and saline. As the S/I is varied from 0.3 to 1.2, the results were follows : the observed ultimate anaerobic biodegradability varied from 72.0 to 88.0%, the first order reaction rate varied from 0.1735 to $0.3420\;day^{-1}$ and the second order reaction rate varied from 0.0132 to $0.0295\;day^{-1}$. When S/I was 0.9, the first order reaction rate had a maximum value, but the variations of the second order reaction rate were less than 1st-order reaction rate. When the operation time exceeded 2 days the gas production rapidly increased. The source of this rapid increase was due to that the activity of the granular sludge used in this study being faster than that of conventional sludge. Under aerobic condition, the characteristics of organic matter were as follows: the marine industry wastewater used in this study contained about 81% of biodegradable matter, and it was divided into readily biodegradable COD(Ss), slowly biodegradable COD(Xs), soluble COD(Si) and inert suspended COD (Xi). The percentages of each COD were 87.3%, 23.9%, 6.4% and 12.4% respectively.

Changes of the Flame Temperature and OH Radical in the Unsteady Extinction Process (비정상 소화 과정에서의 화염 온도 및 OH 라디칼의 변화)

  • Lee, Uen-Do;Lee, Ki-Ho;Oh, Kwang-Chul;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1557-1566
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    • 2004
  • A flame extinction phenomenon is a typical unsteady process in combustion. Flame extinction is characterized by various physical phenomena, such as convection, diffusion, and the production of heat and mass. Flame extinction can be achieved by either increasing the strain rate or curvature, by diluting an inert gas or inhibitor, or by increasing the thermal or radiant energy loss. Though the extinction is an inherently transient process, steady and quasi-steady approaches have been used as useful tools for understanding the flame extinction phenomenon. Recently, unsteady characteristics of flames have been studied by many researchers, and various attempts have been made to understand unsteady flame behavior, by using various extinction processes. Representative parameters for describing flame, such as flame temperature, important species related to reactions, and chemi-luminescence of the flame have been used as criterions of flame extinction. In these works, verification of each parameter and establishing the proper criterions of the extinction has been very important. In this study, a time-dependent flame temperature and an OH radical concentration were measured using optical methods, and the instantaneous change of the flame luminosity was also measured using a high-speed ICCD (HICCD) camera. We compare the unsteady extinction points obtained by three different methods, and we discuss transient characteristics of maximum flame temperature and OH radical distribution near the extinction limit.

Annealing and In Interlayer Effects on the Photovoltaic Properties of CBD-In2S3/CIGS Solar Cells (열처리와 In 중간층 적용에 의한 CBD-In2S3/CIGS 태양전지의 특성 향상)

  • Kim, Hee-Seop;Kim, Ji-Hye;Shin, Dong-Hyeop;Ahn, Byung-Tae
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.432-438
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    • 2011
  • In this study, chemical bath deposited (CBD) indium sulfide buffer layers were investigated as a possible substitution for the cadmium sulfide buffer layer in CIGS thin film solar cells. The performance of the $In_2S_3$/CIGS solar cell dramatically improved when the films were annealed at $300^{\circ}C$ in inert gas after the buffer layer was grown on the CIGS film. The thickness of the indium sulfide buffer layer was 80 nm, but decreased to 60 nm after annealing. From the X-ray photoelectron spectroscopy it was found that the chemical composition of the layer changed to indium oxide and indium sulfide from the as-deposited indium hydroxide and sulfate states. Furthermore, the overall atomic concentration of the oxygen in the buffer layer decreased because deoxidation occurred during annealing. In addition, an In-thin layer was inserted between the indium sulfide buffer and CIGS in order to modify the $In_2S_3$/CIGS interface. The $In_2S_3$/CIGS solar cell with the In interlayer showed improved photovoltaic properties in the $J_{sc}$ and FF values. Furthermore, the $In_2S_3$/CIGS solar cells showed higher quantum efficiency in the short wavelength region. However, the quantum efficiency in the long wavelength region was still poor due to the thick buffer layer.

Development of low deformation ATIG welding process for high penetration aspect ratio in thick stainless steel welding (후판 스테인리스 용접에서 높은 용입형상비의 저변형 ATIG용접 공정 개발)

  • Ham, Hyo-Sik;Seo, Ji-Seok;Ha, Jong-Moon;Im, Sung-Bin;Oh, Dong-Soo;Cho, Sang-Myung
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.7-7
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    • 2009
  • TIG 용접에서는 후판 용접의 경우 용입의 한계 때문에 깊고 넓은 그루브 가공을 하여 다층 용접을 한다. 이 때, 그루브를 채우는 용착금속에 의한 응고 수축과 과대한 입열로 인한 변형이 문제시 되고 있다. 변형을 줄이기 위해서는 용착금속의 양과 입열량을 줄여야 한다. 이러한 문제를 해결하기 위해 그루브의 루트패이스를 두껍게 하고 그루브각을 줄여서 용착량을 줄인다. 이때, 좁은 그루브에서 두꺼운 루트패이스를 완전 용입할 수 있는 용접 프로세스가 필요하다. 비드가 좁고 깊은 용입 특성을 가지는 Plasma welding(PAW) 경우에는 좁은 그루브 속에 토치가 접근하기 어려워 적용하기 어렵다. 따라서 접근성이 용이한 TIG 용접에서 높은 용입형상비를 가지는 용접공정 개발이 필요하다. 선행연구로 높은 용입 형상비를 가지는 Active flux Tungsten Inert Gas(ATIG) 용접이 연구되었다. ATIG의 용입 증가 메커니즘으로는 Marangoni effect, 음이온들로 인한 아크 수축 효과, 절연 플럭스에 의한 아크 수축효과 등으로 알려져 있다. 또한 선행연구에서 ATIG에서 Ar가스에 He 또는 $H_2$ 가스를 첨가하면 용입이 더욱 증가하는 것을 확인하였다. 본 연구에서는 A-TIG에 He 가스를 적용하고 아크길이 0.5mm, 1.0mm, 2.0mm와 전극 선단각 30도, 60도, 90도에 따른 용입 형상비와 변형량을 검토하기 위해 실험을 하였다. 실험 결과는 아크길이가 감소할수록 전극 선단각이 증가할수록 용입 형상비는 증가하였고, 변형량은 감소하였다.

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A Study on Combusiton Properties of Natural Fiber Dust (천연섬유분진의 연소특성에 관한 연구)

  • 이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.13 no.1
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    • pp.3-10
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    • 1999
  • We had investigated combustion properties of natural textile dusts. Decomposition properles of natural textile dusts scavenged by precipitator of spinning factoη were investigated using D DSC(Differential Scanning Calorimeter) and TGA(Thermogravimetric Analysis) by temperature c changes. Combustion pro야rties of natural textile according to size distribution and amount were c checked as temperature variation according to time using spontan$\infty$us ignition apparatus. M Moreover, combustion properties with blowing or without blowing condition were checked in order to investigate combustion prope$\pi$ies in spontaneous ignition apparatus according to flow c condition of air. As results of thermal analyses, increase in r머sing tern야:rature causes initial smold벼ng t temperature to move towards low temperature section 뻐d i띠디떠 smoldering temperature was d de$\sigma$eased more remarkably in atmosphere than in inert gas and that condition allowed heating v value to increase considerably. In addition, as amount and size distribution of natural textile d dusts were increased, i띠ti머 smoldering temperature was lowered. All of combustion forms were s smoldering combustion. Initial smold밍ing temperature was low more slightly with blowing c condition than without blowing condition in sp$\alpha$ltaneoUS ignition apparatus, which condition m made heatim;!; value high.

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A study on dehydration of rare earth chloride hydrate (염화 희토류 수화물의 탈수화에 관한 연구)

  • Lee, Tae-Kyo;Cho, Yong-Zun;Eun, Hee-Chul;Son, Sung-Mo;Kim, In-Tae;Hwang, Taek-Sung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.125-132
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    • 2012
  • The dehydration schemes of rare earth (La, Ce, Nd, Pr, Sm. Eu, Gd, Y) chloride hydrates was investigated by using a dehydration apparatus. To prevent the formation of the rare earth oxychlorides, the operation temperature was changed step by step ($80{\rightarrow}150{\rightarrow}230^{\circ}C$) based on the TGA (thermo-gravimetric analysis) results of the rare earth chloride hydrates. A vacuum pump and preheated Ar gas were used to effectively remove the evaporated moisture and maintain an inert condition in the dehydration apparatus. The dehydration temperature of the rare earth chloride hydrate was increased when the atomic number of the rare earth nuclide was increased. The content of the moisture in the rare earth chloride hydrate was decreased below 10% in the dehydration apparatus.

Durability Characteristics of Limestone Powder added Concrete for Environment-Friendly Concrete (석회석미분말을 첨가한 친환경 시멘트콘크리트의 내구 특성)

  • Choi, Woo Hyeon;Park, Cheol Woo;Jung, Won Kyung;Jeon, Beom Joon;Kim, Gyu Seon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.5
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    • pp.59-67
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    • 2012
  • During the manufacturing of Portland cement, CO2 gas is also necessarily produced through both decarbonation of calcium carbonate and kiln burning. By partially replacing the Portland cement with limestone powder, which is an inert filler in a concrete mixture, CO2 consumption can be reduced in a construction field. This study is to investigate the fundamental durability characteristics of limestone powder added concrete. Experimental variable was the replacement ratio of limestone powder from 0% to 25% with 5% increment. Durability characteristics were investigated by resistance to freeze-thaw, alkali-silica reaction and de-icing chemical in addition to the properties of fresh concrete. From test results, it was observed that the addition of limestone powder did not significantly affect the resistance to freeze-thaw reaction and de-icing chemical. The addition of limestone powder reduced the occurrence potential of alkali-silica reaction by reducing an alkali content in Portland cement.

Pore Structure and Characteristics of Hollow Spherical Carbon Foam According to Carbonization Temperature and Re-immersion Treatment (탄화온도 및 재담금 처리에 따른 중공형 탄소다공체의 기공구조 및 특성)

  • Yi, Eunju;Lee, Changwoo;Kim, Yangdo;Rhyim, Youngmok
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.24-30
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    • 2013
  • Today, the modification of carbon foam for high performance remains a major issue in the environment and energy industries. One promising way to solve this problem is the optimization of the pore structure for desired properties as well as for efficient performance. In this study, using a sol-gel process followed by carbonization in an inert atmosphere, hollow spherical carbon foam was prepared using resorcinol and formaldehyde precursors catalyzed by 4-aminobenzoic acid; the effect of carbonization temperature and re-immersion treatment on the pore structure and characteristics of the hollow spherical carbon foam was investigated. As the carbonization temperature increased, the porosity and average pore diameter were found to decrease but the compression strength and electrical conductivity dramatically increased in the temperature range of this study ($700^{\circ}C$ to $850^{\circ}C$). The significant differences of X-ray diffraction patterns obtained from the carbon foams carbonized under different temperatures implied that the degree of crystallinity greatly affects the characteristics of the carbon form. Also, the number of re-impregnations of carbon form in the resorcinol-formaldehyde resin was varied from 1 to 10 times, followed by re-carbonization at $800^{\circ}C$ for 2 hours under argon gas flow. As the number of re-immersion treatments increased, the porosity decreased while the compression strength improved by about four times when re-impregnation was repeated 10 times. These results imply the possibility of customizing the characteristics of carbon foam by controlling the carbonization and re-immersion conditions.

Influence of the Nozzle Contraction Angles of Gaseous Extinguishing Systems on Discharge Noise (가스계 소화시스템 노즐 수축각이 방출소음에 미치는 영향)

  • Kim, Yo-Hwan;Yoo, Han-Sol;Hwang, In-Ju;Kim, Youn-Jea
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.77-82
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    • 2019
  • Fire extinguishing systems are essential equipment in all indoor facilities to address unexpected fire scenarios, and appropriate fire extinguishing agent should be used depending on the place and object to protect. Among these, gaseous fire-extinguishing systems are used to protect electronic equipment. Therefore, inert gases that do not undergo chemical reactions are used mainly in those systems. On the other hand, recently, owing to the high integration of electronic equipment, there are some cases, in which large noise generated from gaseous systems damage the electronic equipment. In this study, numerical analysis of the discharge noise with various nozzle contraction angles was carried out to improve the gas fire extinguishing system. Numerical analysis was carried out using ANSYS FLUENT ver 18.1. The causes of the noise were elucidated using the swirl distribution. The noise level of the modified model was reduced by approximately 6 dB compared to the reference model, which is similar to the result of a previous study, confirming the validity of the method.

The influence of heating rate on the carbonization of sulfuric acid-impregnated cellulose (황산첨가 셀룰로오스의 탄화에서 승온속도의 영향)

  • 김대영
    • Journal of Korea Foresty Energy
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    • v.22 no.1
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    • pp.37-43
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    • 2003
  • The influence factors for char yield in the carbonization process of natural cellulose are the carbonization temperature, the heating rate and the atmosphere in the furnace. In general, it is well known that the improvement of char yield is expected under the conditions of the lower carbonization temperature, the slower heating rate and the presence of inert gas in the furnace. In this study, it has been investigated the effect of the heating rate control with sulfuric acid as a dehydrating agent for the improvement of char yield in the carbonization process of natural cellulose. The cellulose treated with sulfuric acid has shown the weak dependency of heating rate in char yield, whereas the untreated cellulose has shown the strong dependency. These findings clearly suggest that it can be useful to control heating rate with appropriate dehydrating agent in the carbonization process to improve the char yield and shortening the carbonization time.

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