• Title/Summary/Keyword: Inert gas

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Visible Emission Sepctra of o-Xylyl Radical

  • Choe, Ik Sun;Lee, Sang Guk
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.281-284
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    • 1995
  • The visible emission spectra of the o-xylyl radical in the gas phase have been obtained using a Fourier transform spectrometer coupled with a technique of supersonic expansion. The o-xylyl radical was generated in a jet by expansion with an inert buffer gas He from a high voltage dc discharge of the precursor o-xylene. The spectra were analyzed on the basis of the rotational contours of the vibronic bands as well as the known vibrational frequencies by a matrix isolation method.

Performance Improvement of TIG Welders Using Intelligent Control Algorithm (지능제어 알고리즘을 이용한 펄스 인버터 TIG 용접기의 성능 향상)

  • 김규식
    • Proceedings of the KIPE Conference
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    • 2000.07a
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    • pp.556-559
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    • 2000
  • Pulse inverter-type TIG(Tungsten Inert Gas) arc welders are studied to investigate the dynamic performance of welding. Welding currents are controlled to be pulse waveforms resulting in stable are better welding performance. The hybrid-type controller is proposed to control the welding current. Todemonstrate the practical significance of our results we present some simulation results.

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Unsteady Flow Effects on Extinguishing Concentrations in Jet Diffusion Flames (제트확산화염 소화농도의 비정상 유동효과)

  • Ji, Jung-Hoon;Oh, Chang-Bo;Lee, Eui-Ju
    • Journal of the Korean Society of Safety
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    • v.24 no.6
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    • pp.27-31
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    • 2009
  • An experimental study on the unsteady effect of the extinction limit was performed in ethene jet diffusion flames. To impose the unsteadiness on jet flames, the amplitude and frequency of a co-flow velocity was varied, and the two inert gases, $N_2$ and $CO_2$, were used to dilute the oxidizer for extinguishing concentration. The experimental results shows that large amplitude of velocity induces a low extinguishing concentration, which implies that flow variation affects the blow out mechanism. Also, the flow oscillation effects under high frequency attenuates the flame extinction. These results means that flow unsteadiness extends the extinction limit and finally minimum extinction concentration by inert gases. When the Stoke's 2nd Problem is introduced to explain the flow unsteadiness on extinction concentration, the solution predicts the effect of amplitude and frequency of velocity well, and hence it is concluded the effect of low frequency velocity excitation was attributed only to flow effect.

테트라키스 피콜리나토류 텅그스텐(Ⅳ) 착물의 Inertness에 관한 연구

  • Jang, Ju Hwan;Ronald D. Archer
    • Journal of the Korean Chemical Society
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    • v.34 no.1
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    • pp.85-90
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    • 1990
  • The inertness of eight-coordinate tetrakis(picolinato)tungsten(IV) complex has been investigated by spectroscopic method in nonpolar solvent at 60$^{\circ}C$, 75$^{\circ}C$, 90$^{\circ}C$, 120$^{\circ}C$, and reflux condition. Until 2 days, showed the inertness whether existance of oxygen or not. After 2 days, showed the oxidation of W(IV) complex much more rapidly than substitution, which had $k_{obs}(sec^{-1}) {\varpropto} 1/[ligand]^2$. On sealing the sample under Ar gas, showed the inertness until 50 days, which had $k_{obs}(sec^{-1}) = 8.8{\times} 10^{-7}$. The$^1H$-NMR peak of $H_6$ in complex was diminished, otherwise that of free ligand was grown up. This result indicated that this complex was very inert.

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COMBUSTION CHARACTERISTICS OF WASTE-PYROLYSIS GASES IN AN INTERNAL COMBUSTION ENGINE

  • Shudo, T.;Nagano, T.;Kobayashi, M.
    • International Journal of Automotive Technology
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    • v.4 no.1
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    • pp.1-8
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    • 2003
  • Wastes such as shredder dust of disposed vehicles can be decomposed into low calorific flammable gases by Pyrolysis gasification. A stationary electric Power generation using an internal combustion engine fuelled with the waste-pyrolysis gas is an effective way to ease both waste management and energy saving issues. The waste-pyrolysis gas mainly consists of H$_2$, CO, $CO_2$ and $N_2$. The composition and heating value of the gas generated depend on the conversion process and the property of the initial waste. This research analyzed the characteristics of the combustion and the exhaust emissions in a premixed charge spark ignition engine fuelled with several kinds of model gases, which were selected to simulate the pyrolysis-gases of automobile shredder dusts. The influences of the heating value and composition of the fuel were analyzed parametrically. Furthermore, optical analyses of the combustion flame were made to study the influence of the fuel's inert gas on the flame propagation.

Measuring calorific values of natural gases using sound velocity and thermal conductivity (천연가스 음속과 열전도도 상관식을 이용한 발열량 측정기술)

  • Lee, Ju-Haeng;Choi, Byungchul;Choi, Inchul
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.57-59
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    • 2015
  • A method to measure heating value of natural gas using sound velocity and thermal conductivity is proposed to solve the low heating value issues of imported natural gas in South Korea. Natural gas generally consists of methane, butane, ethane, and inert gases. Heating value changes as the gas material properties, such as density, wobbe index, etc., varies. It is highly important to measure heating values of natural gases accurately because measuring the heating value depends on the given natural gases' components. Therefore, sound velocity and thermal conductivity is measured to estimate indirectly heating value of Natural gas with their changed components.

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A Study on the Thrust Throttling Using Gas Injection in Swirl Injectors (기체주입을 이용한 와류형 분사기들에서의 가변추력 연구)

  • Lee, Wongu;Yoon, Youngbin;Ahn, Kyubok
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.159-168
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    • 2018
  • Thrust throttling in a liquid rocket engine can be implemented via several ways such as high pressure drop injector, dual manifold, multiple chamber, pintle injector, and gas injection. Thrust throttling using gas injection controls thrust by usually injecting inert gas into propellant through an aerator to reduce the propellant's bulk density. In this study, the outside-in aerator was used in the propellant line to create two phase flow. Closed-type, open-type, and screw-type bi-swirl coaxial injectors were utilized for investigating throttling characteristics such as pressure drop, mixture density, and discharge coefficient according to gas-liquid mass ratio.

Effects of inert gas (Ne) on thermal convection of mercurous chloride system of $Hg_2Cl_2$ and Ne during physical vapor transport

  • Choi, Jeong-Gil;Lee, Kyong-Hwan;Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.225-231
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    • 2008
  • For an aspect ratio (transport length-to-width) of 5, Pr=1.13, Le=1.91, Pe=4.3, Cv=1.01, $P_B=20\;Torr$, the effects of addition of inert gas Ne on thermally buoyancy-driven convection ($Gr=2.44{\times}10^3$) are numerically investigated for further understanding and insight into essence of transport phenomena in two dimensional horizontal enclosures. For $10K{\leq}{\Delta}T{\leq}50\;K$, the crystal growth rate increases from 10 K up to 20 K, and then is slowly decreased until ${\Delat}T=50\;K$, which is likely to be due to the effects of thermo-physical properties stronger than the temperature gradient corresponding to driving force for thermal convection. The dimensional maximum velocity gratitude reflecting the intensity of thermal convection is directly and linearly proportional to the temperature difference between the source and crystal regions. The rate is first order-exponentially decreased for $2{\leq}Ar{\leq}5$. This is related to the finding that the effects of side walls tend to stabilize convection in the growth reactor. In addition, the rate is first order exponentially decayed for $10{\leq}P_B{\leq}200\;Torr$.

Design and Output Characteristic of AC Pulse Current for MIG Welding of Ai Sheet (박판 Al MIG 용접용 AC펄스 전류 파형의 설계 및 출력특성)

  • 조상명;김태진;이창주;임성룡;공현상;김기정
    • Journal of Welding and Joining
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    • v.21 no.2
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    • pp.57-63
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    • 2003
  • Since new types of vehicles or structures made from thin aluminum alloy are under rapid development and some products are already on the market, welding of aluminium sheet is increasing. MIG(Metal Inert Gas), MIG-Pulse, TIG(Tungsten Inert Gas) welding are the typical Ai welding. MIG welding has the advantage of high speed, but it is difficult to apply to the thin plate, because of bum-through by the high heat input and spatter. MIG-Pulse welding can weld without spatter and burn-through, but when the gap exists at the welding joint, there is quite a possibility of bum-through. TIG welding is difficult to weld at a high speed. AC Pulse welding alternates between DCEP(Direct Current Electrode Positive) and DCEN(Direct Current Electrode Negative). DCEN is higher wire melting rate than DCEP, while lower temperature of droplet than DCEP. In AC Pulse welding, far fixed welding current, wire melting rate increases as the EN ratio increases. For fixed wire feed rate, welding current decreases as the EN ratio increases. Because of these features, the temperature of droplet, the depth of penetration, the width of bead decrease and the reinforcement height increases as EN ratio increases, and these are able to weld at a high speed, lower heat input. It is the purpose of this study that design of AC pulse current waveform for MIG welding of Al sheet and estimation of output characteristic.

Sintering Characteristics of Au and Ag Nanoparticles Prepared by Inert Gas Condensation (불활성 증발 응축방법으로 제조된 금과 은 나노입자의 소결특성)

  • Lee, Seung-Hyun;Min, Dong-Ryoul;Lee, Kwang-Min
    • Journal of Powder Materials
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    • v.14 no.3 s.62
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    • pp.165-172
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    • 2007
  • The purpose of this study was to analyze the sintering characteristics of gold and silver nanoparticles. In this study, gold and silver nanoparticles were prepared by using Inert Gas Cndensation (IGC). The sintering temperatures for gold and silver nanoparticles were $100{\sim}1000^{\circ}C\;and\'100{\sim}500^{\circ}C$, respectively. The sintering characteristics of gold and silver nanoparticles prepared by IGC were evaluated by X-ray diffraction(XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). Gold and silver nanoparticles with the size of $1{\sim}100\;nm\;and\;10{\sim}100\;nm$, respectively, were obtained. The size of sintered gold and silver nanoparticles increased with an increase in the sintering temperature. XRD data showed that silver nanoparticles were similar with polycrystal single-phase.