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Reductive Dechlorination of Chlorinated Oraganic Compounds Using Zero-Valent Iron (0가 철분을 이용한 유기염소화합물의 환원적 탈염소화)

  • Lee, Chang-soo;Bae, Woo-keun
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.4
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    • pp.427-432
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    • 2001
  • The purpose of study is to examine the sensitivity of the rate of degradation to initial TCE concentration and iron concentration in the solution. The batch tests were executed to assess the degradation rate at varying initial conditions. First order rate constants($k_a$) were more rapid with the lower initial TCE concentration, Howere the correleation was not always linear between $k_a$ and initial TCE concentration. $k_a$ was proportionally increased as the increasing surface area. It implied that the effective reactive surface area acted as the limiting factor on the reductive dechlorination of TCE by iron.

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Optimization of Repulping Process of Unsorted ONP for Pulp Mold (II) - Pilot trial -

  • Cho, Byoung-Uk;Ryu, Jeong-Yong;Fabry, Benjamin;Song, Bong-Keun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.5
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    • pp.39-44
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    • 2007
  • In order to utilize unsorted ONP, which contains leaflets (printed coated papers), as a raw material to produce pulp mold, optimum conditions for repulping were investigated with the pilot Helico pulper at Centre Technique du Paper (CTP), France. Two major process factors were focused: repulping concentration and rotor speed. Repulping at a higher concentration showed more rapid defibering kinetics. Increasing the rotational speed of rotor at the optimum repulping concentration accelerated the defibering kinetics while it also led to higher fines generation and faster decrease in drainage property of the produced pulp. Hence, an alternative way was suggested: starting repulping at a conventional rotor speed and then accelerating the rotor speed for the last minute(s) of repulping.

A Study on Work's Exposure to Dust, Crystalline Free Silica and Lead in Ceramic Industry (일부 요업사업장의 분진, 결정형 유리규산 및 납의 폭로에 관한 연구)

  • Oh, Se-Min;Shin, Yong-Chul;Park, Dong-Wook;Lee, Na-Roo;Park, Sueng-Hyun;Yi, Gwang-Yong;Moon, Young-Hahn
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.4 no.2
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    • pp.168-179
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    • 1994
  • In some ceramic industries, worker exposure to dust, crystalline free silica and lead were determined and evaluated. The conclusions are as follows. 1. Crystalline silica in bulk samples was 10.5 % in sanitary ware industry, 9.4 % in tile industry, and 2.1 % in ceramic insulator industry respectively. The free silica content of air filter sample was 8.03 % in table ware industry, 5.59 % in sanitary ware industry, and 1.32 % in ceramic insulator industry. Because silica content in ceramic dust is relatively high, it is should be considered silica as important factor in evaluating for ceramic industry. 2. The silica contents in dust from tile, sanitary ware and table ware industries are above 5%, it should be classified as "Type" 2 dust. 3. The airborne concentration of respirable crystalline silica was $27.9{\mu}g/m^3$ in a sanitary ware factory and $5.8{\mu}g/m^3$ in a ceramic insualtor factory. Three of ten samples sampled the above factories were exceeded the occupational exposure levels, $100{\mu}g/m^3$. 4. Geometric mean(GM) of total dust in 11 factories was $1.00mg/m^3$ and GM of respirable dust concentration in 5 factories was $0.33mg/m^3$. Sanitary ware industry had the highest concentration of total dust, $1.62mg/m^3$ and of respirable dust, $0.88mg/m^3$. 5. Average lead concentration in air was $0.05mg/m^3$ in glazing process of 2 factories manufacturing table ware. Five of ten sample(50%) were exceeded $0.05mg/m^3$. Therefore lead exposure in pottery industry should be considered as important problem.

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Antibacterial Effect of PVP/PEG/Carrageenan/Silver Acetate Hydrogels by γ-ray (γ-ray를 이용하여 합성한 PVP/PEG/Carrageenan/Silver acetate 하이드로겔의 항균효과)

  • Lim, Youn-Mook;Youn, Young;Gwon, Hui-Jeong;Park, Jong-Seok;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.4 no.1
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    • pp.73-77
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    • 2010
  • In recent day, there is much interest in the biocidal activity of silver since silver is known to be safe and effective as disinifectant and biocidal material against coliforms and viruses. In this study, hydrogels containing silver acetate as antibacterial agent have been prepared using gamma rays irradiation. The hydrogels are composed of poly(vinyl pyrrolidone) (PVP), poly(ethylene glycol) (PEG), carrageenan and silver acetate. The concentration of solution was 9 wt%. The ratio of PVP : PEG : carrageenan was 6 : 1 : 2. The concentration of the silver acetate were 0, 0.01, 0.03, 0.05 and 0.07% and Gamma irradiation dose was 25 kGy. The Gamma irradiation dose in hydrogels with 0.01% silver acetate were 20 kGy, 35 kGy, 50 kGy, 65 kGy, and 80 kGy. The results showed that 0.01% silver acetate concentration of hydrogels by 25 kGy irradiation dose showed the highest antibacterial activity against E. coli and Staphylococcus aureus. Moreover, antibacterial activity of various Gamma irradiation dose in hydrogels treated 0.01% silver acetate showed highest 35 kGy irradiation dose against Staphylococcus aureus.

Natural Scavengers of Reactive Oxygen Species in Rumex crispus as natural colorant

  • Suh, Hwa-Jin;Ahn, In-Yong;Song, Eun-Young;Na, Seon-Young;Park, Jin-Woo;Park, Ji-Ju;Kwon, Oh-Oun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.41-41
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    • 2011
  • The aims of this study were to examine the efficacy of phytochemicals of Rumex crispus as anti-oxidant and anti-browning agent. The bioactive properties of Rumex crispus as natural colorants were studied by total phenolic contents, DPPH radical scavenging, ABTS radical scavenging,lipid peroxidation, cell viability, singlet oxygen quenching and photoprotection effect. Among all of the results ($IC_{50}$: the concentration of various extracts required to exert 50% reducing effect), the higher activity of the extract was found in the ethyl acetate and butanol extracts. Anti-browning activity was evaluated by monitoring the change $L^*$, $a^*$, $b^*$ values and total color differences(${\Delta}E$). It was found that ethyl acetate and butanol extracts effectively inhibited browning in apple juice at a concentration below 0.3 mg/ml. Rumex crispus extracts used natural colorants could be of good resources as anti-oxidant and anti-browning agents. The results suggest that our study may contribute to the development of natural and functional materials with potential application to reduce oxidative damage.

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Degradation of p-nitrophenol by Gamma Irradiation

  • Lee, O Mi;Kim, Tae-Hun;Yu, Seungho;Jung, In-ha;Lee, Myunjoo
    • Journal of Radiation Industry
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    • v.5 no.4
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    • pp.353-357
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    • 2011
  • Degradation of p-nitrophenol has been carried out using only gamma irradiation or gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$. Effects of different operating parameters such as initial concentration ($50mg\;l^{-1}$, $100mg\;l^{-1}$, $200mg\;l^{-1}$, $300mg\;l^{-1}$, $400mg\;l^{-1}$, $500mg\;l^{-1}$ and $600mg\;l^{-1}$) on the extent of degradation has been investigated. At 5 kGy, $50mg\;l^{-1}$ p-nitrophenol was completely degraded, and the radiolytic degradation of p-nitrophenol was described by the pseudo-first-order kinetic model. The combination of gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$ leads to an enhanced effect, which remarkably increased the degradation efficiency of p-nitrophenol and TOC removal. However, at high $H_2O_2$ concentration, the efficacy of p-nitrophenol degradation is reduced because ${\cdot}OH$ radicals are scavenged by $H_2O_2$ and $Na_2S_2O_8$.

Characterization of Radiation Fabricated Imidazole Based Hydrogel (이미다졸 기반 수화겔의 방사선 합성 및 특성 평가)

  • Gwon, Hui-Jeong;Jeong, Jin-Oh;Jeong, Sung In;Park, Jong-Seok;Lim, Youn-Mook
    • Journal of Radiation Industry
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    • v.12 no.4
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    • pp.349-353
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    • 2018
  • Metronidazole (MD), which is used as an antibiotic, is largely used as an oral and skin application agent, and has inhibiting effect on the production of the fungus causing malodor. However, the maximum drug inclusion concentration is 0.75% of skin ointment in commercially available. In this study, hydrogels containing high concentration of metronidazole were prepared by using radiation crosslinking technique based on biocompatible polymers, and release characteristics and antimicrobial properties were evaluated. This study was preliminary carried out to investigate whether it could be used effectively as antibacterial dressing materials.

A Specific Character on the Urinary Hippuric Acid Excretions of Workers Exposed to Toluene in Specific Character of Manufacturing Industry (작업장 특성에 따른 톨루엔 노출 근로자의 마뇨산 배출 특성)

  • Park Heung-Jai;Kim Hyung-Joon;Jeong Seong-Wook;Lee Byung-Ho
    • Journal of Environmental Science International
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    • v.14 no.2
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    • pp.201-207
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    • 2005
  • This study was carried out to investigate the correlation between toluene in air and hippuric acid in human urine, which is based in the results of the health check-in and measure of working environment, was investigated for five years. Toluene in air and hippuric acid in urine were checked 116 workers who exposed to toluene in five type of industry. The Mean concentration of toluene in air by type of industry and every year and sex distinction, had positive correlation.(p<0.01) The Mean concentration of hippuric acid in urine by type of industry, every year, sex distinction, disparity of age and term of duty had positive correlation.(p<0.01).

Changes in the Handsheet Properties by Low Concentration Sodium Hydroxide Swelling and Beating (저농도 NaOH 팽윤과 고해에 따른 수초지 특성 변화)

  • Choi, Kyoung-Hwa;Kim, Ah-Ram;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.69-75
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    • 2014
  • Effects of alkali swelling of HwBKP (hardwood bleached kraft pulp) at a low concentration below 2 percent (based on the oven-dried weight of pulp) on handsheet properties were investigated. Swelling treatment of HwBKP was performed at various low NaOH concentrations with/without beating. Then, the changes in handsheet properties were evaluated in terms of bulk, optical and strength properties. It was found that bulk was slightly increased when the alkali concentration was increased. When the pulp was only swollen without beating, paper optical and strength properties was slightly decreased or not changed with alkali concentration. When the pulp was alkali-swollen after beating, paper strength and opacity showed almost no changes while brightness was increased. When the pulp was beaten after NaOH swelling, alkali concentration showed almost no effect on brightness and opacity of paper. Paper strength was slightly decreased with alkali concentration, suggesting that alkali pretreatment before refining could adversely affect refining efficiency.

Changes in Fiber Characteristics by Low Concentration Sodium Hydroxide Swelling and Beating (저농도 NaOH 팽윤과 고해에 따른 섬유특성 변화)

  • Kim, Ah-Ram;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.65-72
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    • 2014
  • In this study, effects of alkali swelling at low concentration below 2 percent on properties of hardwood bleached kraft pulp (HwBKP) were elucidated. Swelling treatment of HwBKP was performed at various NaOH concentrations with/without beating. Then, the swelling characteristics of pulp fiber was evaluated by measuring the solvent retention values such as water retention value (WRV) and isopropyl alcohol retention value (LRV). It was found that fiber characteristics were influenced by NaOH swelling even at low alkali concentration and beating treatment as well. The values of WRV and LRV were decreased when the alkali concentration was increased. It is the result from the decreased acidic groups of pulp which were formed during beating. The acidic groups could be neutralized and then removed by alkali. The difference between WRV and LRV was decreased with increasing alkali concentration while the difference was increased when the alkali swollen pulp was beaten. In addition, the crystalline structure of HwBKP was almost not changed while the crystallinity was influenced by swelling treatment at a low alkali concentration.