• 한국응용과학기술학회지
• /
• 제27권3호
• /
• pp.300-309
• /
• 2010

Melamincyanurate(MC), as an non halogen flame retardant are used as the polymer and plastic materials. In this study, melamine and cyanuric acid were used for the synthesis of MC. The optimum condition of synthetic MC were controlled by different molar ratio of melamine to cyanuric acid. MC was modified by coupling reaction with four different agents. The influences of modified MC were based on the coupling agent types. Preparation methods are available to offer the prospect of improved morphology control deposit stability in polyol. The results reveal that glycidoxypropyltrimethoxysilane(GDS) has the best storage stability. The best properties were obtained with melamine and cyanuric acid from 1:1 molar ratio. Modification of MC through coupling agent can efficiently enhanced the deposit stability in polyol up to 30 %.

• 대한금속재료학회지
• /
• 제49권10호
• /
• pp.790-796
• /
• 2011

To reduce the heat released during intermetallic reaction, Ni-50at%Al powder compact has been previously annealed at several conditions before the reaction. The effects of the pre-annealing conditions on the reaction synthesis process have been investigated. Experimental results show that the heat released during the reaction synthesis decreased proportionally with increase of the pre-annealing temperature and duration time. The reaction duration period was significantly increased when the intermetallics were formed in the powder compact during the pre-annealing. This was attributed to the fact that the reaction occurred by solid-state diffusion between the un-reacted elemental atoms and that the $NiAl_3$ phase formed predominantly during pre-annealing.

• Bulletin of the Korean Chemical Society
• /
• 제11권2호
• /
• pp.140-143
• /
• 1990

Ethanolic tetra carbonylhydridoferrate solution combined with dialdehyde (no of carbon; 4,5,6) is very efficient for the selective transformation of amino group into N-heterocyclic compound. However, a large variety of both aliphatic and aromatic amines react with the ferrate-pimelaldehyde at room temperature under an atmospheric pressure of carbon monoxide to give the corresponding N-(cyclohexylmethyl)-N-alkyiamine derivatives in moderate yields instead of the corresponding N-substituted perhydroazocine derivatives.

• 산업공학
• /
• 제24권3호
• /
• pp.187-195
• /
• 2011

The automatic radiopharmaceutical module consists of several 2-way valves, couple of syringes, gas supply unit, heating(cooling) unit and sensors to control the chemical reagents as well as to help the chemical reaction. In order to control the actuators of radiopharmaceutical module, the process is tabulated using spread sheet as like excel. Unlike the common program, a trivial error is too critical to allowed in the process because the error can lead to leak the radioactive reagent and to cause the synthesis equipment failure during synthesizing. Hence, the synthesis process has been validated using graphic simulation while the operator checks the whole process visually and undergoes trial and error. The verification of the synthesis process takes a long time and has a difficulty in finding the error. This study presents a methodology to verify the process algebraically while the radiopharmaceutical module is converted to the network model. The proposed method is validated using actual synthesis process.

• 대한화학회지
• /
• 제68권2호
• /
• pp.82-86
• /
• 2024

This paper presents the solid-state synthesis of insoluble Prussian blue (Fe₄[Fe(CN)₆]₃·xH₂O, PB) in a ball mill, utilizing the fundamental components of PB. Solid-state synthesis offers several advantages, such as being solvent-free, quantitative, and easily scalable for industrial production. Traditionally, the solid-state synthesis of PB has been limited to the reaction between iron(II/III) ions and hexacyanoferrate(II/III) complex ions, essentially an extension of the solution-based coprecipitation method to solid-state reaction. Taking a bottom-up approach, a reaction is designed where the reactants consist of the basic building blocks of PB: Fe²⁺ ions and CN^- ions. The reaction, with a molar ratio of Fe²⁺ and CN^- corresponding to 1:2.8, yields PB, while a ratio of 1:6.6 results in a mixture of potassium hexacyanoferrate(II) (K₄Fe(CN)₆), potassium chloride (KCl), and potassium cyanide (KCN). This synthetic approach holds promise for environmentally friendly methods to synthesize multimetallic PB with maximum entropy in nearly quantitative yield.

• 한국산학기술학회논문지
• /
• 제12권1호
• /
• pp.45-54
• /
• 2011

본 논문은 소형 냉동 시스템에서 왕복동식 압축기는 주요한 진동원이자 소음원으로서 압축기의 외부 구조 동특성을 변경함으로써, 진동과 소음을 줄이는 방법에 관한 것이다. 구조 동특성의 변경은 유한요소 모델에 의한 해석적 방법을 적용하고, 구조 변경의 시도는 두 유한요소들 간의 모드합성법(CMS)을 적용한다. 효과적인 CMS의 적용방법을 찾아내고, 이 방법에 대하여 압축기 모델에 대한 실험적 검증을 통하여 검증하였다.

• 한국염색가공학회지
• /
• 제27권4호
• /
• pp.245-260
• /
• 2015

The effect of salt milling process on the crystal size, morphology, and color characteristics of C.I. Pigment Red 57:1 was studied. The primitive morphology and color properties of the pigment after synthesis were studied in the former series work. The size and morphology of primary particles and the second aggregation features should be considered because they are very important to determine pigment quality. We compared the primary morphology of pigment particles before drying with the secondary aggregated morphology of pigment particles after drying and salt milling process. Morphological properties were investigated by particle size analysis, X-ray diffraction, and scanning electron microscopy and color measurement was carried out. Significant reduction in particle size as well as enhanced crystallite size after salt milling process was observed. This result might give a difference in color of the pigment, turning into brighter and more blue-toned red color. It was revealed that synthesis condition affect the morphology and color of the pigment even after milling. Increase in HCl concentration in the synthesis process enhanced crystal size and quality forming bluer-red pigments but an increase in $CaCl_2$ concentration resulted in more amorphous crystals forming darker-red pigments after salt milling.

• 한국산학기술학회논문지
• /
• 제12권11호
• /
• pp.5278-5283
• /
• 2011

초고속 한국어 형태소 분석을 위한 하나의 방법은 사전에 형태소 결과를 미리 저장해 놓고 이를 이용하는 것이다. 이러한 형태소 패턴 사전을 수작업으로 구축하려면 많은 비용이 들 뿐만 아니라 적지 않은 오류가 포함될 수 있다. 본 논문은 한국어 형태소 합성을 이용하여 자동으로 형태소 패턴을 생성하는 방법을 제안한다. 실험을 통해, 올바른 형태소 분석을 위해 사용한 형태소 패턴의 86%를 자동으로 생성함을 알 수 있었다. 형태소 패턴을 이용한 형태소 분석기가 403MB의 한국어 코퍼스를 분석하는 데 걸린 시간은 2.8GHz 윈도우 시스템에서 52.68초였다.

• Journal of Industrial and Engineering Chemistry
• /
• 제68권
• /
• pp.153-160
• /
• 2018

An environmentally favorable (chlorine-free) solid oxidizer, guanidinium dinitramide [GDN; $NH_2C(NH_2)NH_2N(NO_2)_2$], was newly synthesized from guanidine carbonate [$NH_2C(=NH)NH_2{\cdot}1/2H_2CO_3$]. Two different crystalline forms (${\alpha}-type$ and ${\beta}-type$) appeared according to the applied solvents and synthesis conditions. Moisture, during extraction, might become trapped in a crystal between inner molecules. Therefore, despite having the same chemical composition, Raman-IR and TGA-DSC revealed different physical characteristics of the two forms. Peaks of Raman shift near $1000cm^{-1}$ implied different chemical structures. Thermal analysis revealed an exothermic temperature $155.7^{\circ}C$ for ${\alpha}-type$ but one of $191.6^{\circ}C$ for ${\beta}-type$. The caloric value of ${\alpha}-type$ was 536.4 J/g, which was 2.5 times larger than that of the ${\beta}-type$, which was 1310 J/g. While the synthesized GDN of ${\alpha}-type$ showed a steep exothermic decomposition, the ${\beta}-type$ was slowly decomposed after melting through an endothermic process. This work implied that despite of the same molecular formula some different core thermal properties would appear depending on synthesis conditions.

• 공업화학
• /
• 제33권3호
• /
• pp.258-271
• /
• 2022

Ferrate (VI) [Fe(VI)] has multi-functional features, which include potential oxidant, coagulant, and disinfectant. Because of these distinctive properties, numerous studies on the synthesis of ferrate (VI) and its possible applications in a wide research areas have been investigated. This review highlights the recent development made on different synthesis methods for ferrate including wet chemical, electrochemical, and thermal methods. The recent advancements achieved in ferrate (VI) oxidation and the synergistic effect of the oxidative properties of ferrate (VI) in the presence of various compounds or materials are also included. Moreover, this review discusses the applications of ferrate (VI) for degrading various types of water pollutants and its reaction mechanism. The optimized experimental conditions and interaction mechanisms of ferrate (VI) with micro-pollutants, dyes, and other organic compounds are also elaborated upon to provide greater insight for future studies. Lastly, the limitations and prospects of the ferrate use in the treatment of polluted water are described.