• Title/Summary/Keyword: Increasing rate of temperature

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Thermal Properties of Semiconductive Materials(Shield) by Sonic Impurities in Carbon Black (카본블랙내 이온성 불순물들에 따른 반도전 재료(층)의 열적특성)

  • Lee Yong-Sung;Choi Yong-Sung;Park Dae-Hee;Lee Kyoung-Yong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.149-153
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    • 2005
  • We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Heat capacity (${\Delta}$H), glass transition temperature (Tg) and melting temperature (Tm) were measured by DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from -100($^{\circ}C$) to 100($^{\circ}C$), and heating rate was 4($^{\circ}C$/min). And then thermal diffusivity was measured by LFA 447. The dimension of measurement temperature was 25[$^{\circ}C$]. Glass transition temperature of specimens was showed near -25[$^{\circ}C$] and the heat capacity and the melting temperature from the DSC results were simultaneously decreased according to increasing the content of carbon black, while thermal diffusivity was increased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

Etching Reaction of $UO_2\;with\;CF_4/O_2$ Mixture Gas Plasma

  • Kim, Yongsoo;Jinyoung Min;Kikwang Bae;Myungseung Yang
    • Nuclear Engineering and Technology
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    • v.31 no.2
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    • pp.133-138
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    • 1999
  • Research on the etching reaction of UO$_2$ with CF$_4$/O$_2$gas mixture plasma is carried out. The reaction rates are investigated as a function of CF$_4$/O$_2$ ratio, plasma power, and substrate temperature. It is found that there exists an optimum CF$_4$/O$_2$ ratio around 4:1 at all temperatures up to 37$0^{\circ}C$ and surface analysis using XPS X-ray Photoelectron Spectroscopy) confirms the result. Peak rate at the optimum gas composition increases with increasing temperature. Highest rate obtained in this study leaches 1050 monolayers/min. at 37$0^{\circ}C$ under r. f. power of 150 W, which is equivalent to about 0.5${\mu}{\textrm}{m}$/min. The rate also increases with increasing r. f. power, thus, higher power and higher substrate temperature will undoubtedly raise the etching reaction rate much further. This reaction seems to be an activated process, whose activation energy will be derived in the following experiments.

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Oxidation Study on the Fabrication of Fe-36Ni Oxide Powder from Its Scrap

  • Yun, Jung Yeul;Park, Man Ho;Yang, Sangsun;Lee, Dong-Won;Wang, Jei-Pil
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.48-52
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    • 2013
  • A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

Effect of Heat Treatment and Platinum Loading on CdS Particles in the Photocatalytic Alanine Synthesis

  • Lee, Bu-Yong;Kim, Bong-Gon;Cho, Cheol-Rae;Sakada, Tadayoshi
    • Bulletin of the Korean Chemical Society
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    • v.14 no.6
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    • pp.700-704
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    • 1993
  • The photocatalytic alanine and hydrogen production reaction were studied by using CdS as a semiconductor photocatalysts. The rate of alanine and hydrogen production depends strongly on the temperature in heat treatment of CdS powder. In particular, the rate of alanine production, which was observed using Pt/CdS(A)-(CdS from Mitsuwa), was increased about six times than that of using Pt/CdS(B)-(CdS from Furruchi) under the same heat treatment condition at 500$^{\circ}$C. And the photocatalytic activity for alanine production using bare CdS(A) or Pt/CdS(A) was almost same with increasing temperature in heat treatment in the range of 100-600$^{\circ}$C. From X-ray diffraction data and photoluminescence spectrum, we conclude that the crystal structure changes of CdS(A) or strong interaction at interface of Pt and CdS contribute to increasing the rate of alanine and hydrogen production reaction.

An Experimental Study on Low Nox Combustor Performance at High Pressure and Temperature for 20kW Class Microturbines (20kW급 마이크로터빈용 저공해 연소기의 고압고온 성능실험 연구)

  • Yoon, JeongJung;Oh, Jongsik;Lee, Heonseok
    • 유체기계공업학회:학술대회논문집
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    • 2002.12a
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    • pp.183-190
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    • 2002
  • In order to reduce NOx emissions in the 20kw class microturbines under development, the low NOx characteristics, as being an application to the lean premixed combustion technology, have been investigated. The study has been conducted at the conditions of high temperature and pressure. Air from a compressor with the temperature of 500K to 650K and the pressure of 0.3bar gauge to 0.7bar gauge, was supplied to the combustor through an air preheat-treatment. Sampling exhaust gases were measured at the immediate exit of the combustor. for the effect of temperature on NO and CO emissions. though NOx was increased, CO was decreased with increasing inlet air temperature. With increasing inlet air pressure, NOx and CO were increased also. NOx was decreased, but CO was increased with increasing inlet air mass flow rate. The test has been performed on the equivalent ratios of 0.10 to 0.25 in a lean region. NOx was increased with increasing equivalent ratios, but CO was decreased as an influence of flame temperature. In the very lean region of the equivalent ratio below 0.12, CO was increased suddenly, due to instability. As the results of this study, NOx and CO are found to be reduced to the similar level at the same time when operated at optimal conditions.

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A Study on the Corrosive Wear Mechanism on Atmospherical Temperature of STS 304 Steel (STS 304강의 분위기온도에 따른 부식마멸기구에 관한 연구)

  • 전태옥;박흥식;주창식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.399-406
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    • 1990
  • This paper is studied to know corrosive wear mechanism of STS304 steel on atmospherical temperature against mating material as the same. The corrosive test was carried out by rubbing the annular surface of two test pieces in distilled water and NaCl aqueous solution. The corrosive wear mechanism was investigated by S.E.M. The experimental results show that there is one Lcr transferring from severe wear to mild wear on change of NaCl concentration and atmospherical temperature, and which is the other still remaining in server wear state. It was found that the critical sliding distance Lcr shorten with increasing NaCl concentration but it is longer with ascending atmospherical temperature and the mild wear state still continues under the condition of high generation rate and elimination rate of the corrosive product. Considering upon the result, the model of corrosive wear mechanism is proposed.

The Effect of Sr Addition and Mold Preheating Temperature on the Solidification and Microstructure of Al-7wt%Si-0.3wt%Mg Alloy (Al-7wt%Si-0.3wt%Mg 합금의 응고 및 미세조직에 미치는 Sr 첨가와 금형예열온도의 영향)

  • Kwon, Il-Soo;Kim, Kyoung-Min;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.608-614
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    • 1997
  • The effect of mold preheating temperature on the microstructure such as grain size, eutectic silicon morphology was investigated for the Al-7wt%Si-0.3wt%Mg alloy. Microstructural variations have been characterized as a function of Sr addition and cooling rate during solidification. Microstructures were correlated with cooling rate, local solidification time and eutectic nucleation temperature, etc. In this study, Sr addition caused increase of local solidification time, undercooling and reduction of eutectic plateau temperature. In logarithmic scale, local solidification time was in inverse proportion to cooling rate. Eutectic nucleation temperature was in inverse proportion to cooling rate of logarithmic scale. Increasing the cooling rate refined dendrite arm spacing and eutectic silicon. Dendrite arm spacing was logarithmically in inverse proportion to cooling rate. Without modifier addition, eutectic silicon was modified at cooling rate of $7^{\circ}C/s$ or higher.

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Deformation Characteristic by Compression in High-Nitrogen Austenitic Stainless Steel (고질소강 오스테나이트계 스테인레스강의 압축변형특성)

  • Lee, J.W.;Kim, D.S.;Kim, B.K.;Lee, M.R.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.10a
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    • pp.139-141
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    • 2007
  • Compression tests were carried out to investigate morphologies of compressed specimen, deformation microstructure and stress-strain relation in high-nitrogen austenite stainless steel. Tests were performed under a wide range of temperature and, with true strain rates up to $\dot{\varepsilon}$ =0.05, 0.1, 0.5 and $1.0s^{-1}$. The activation energy of loading force was equal to plastic deformation energy within the temperature range of $900^{\circ}C$ to $1250^{\circ}C$. Dynamically recrystallized grain size decreased with an increasing strain rate and temperature. Flow stresses and deformation microstructures, were used to quantify the critical strain rate and recrystallized grain size. The grain size versus strain rate-temperature map obtained in the study was in good agreement with the deformation microstructures of compressed specimens.

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Deposition of $\alpha$-Si:H thin films by PECVD method (플라즈마 화학증착법을 이용한 $\alpha$-Si:H박막의 제조)

  • 정병후;문대규;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.63-67
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    • 1991
  • Amorphous silicon films were deposited on glass, [100] single crystal silicon wafer with thermally grown silicon dioxide, and [100] silicon wafer substrates by Plasma Enhanced Chemical Vapor Deposition(with argon diluted silane source gas). Growth rate, UV optical band edge, and the hydrogen quantity in the amorphous silicon films have been investigated as a function of the preparation conditions by measuring film thickness, UV-absorbency, and FT-IR transmittance. The growth rate of the ${\alpha}$-Si:H films increases with increasing substrate temperture, flow rate and R.F. power density. The UV optical band edge shifts to blue with the increases in the deposition pressure. Increasing substrate temperature shifts the UV optical band edge of the films to red. Hydrogen quantity in the ${\alpha}$-Si:H films increases with an increases in the R.F. powr and decreases with an increase in the substrate temperature.

Dielectric and Piezoelectric Characteristic of Low Temperature Sintering PMN-PNN-PZT Ceramics according to the Heating Rate (승온속도에 따른 저온소결 PMN-PNN-PZT 세라믹스의 유전 및 압전특성)

  • Kim, Kook-Jin;Yoo, Ju-Hyun;Hong, Jae-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.253-254
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    • 2007
  • In this study, in order to develop low temperature sintering multilayer piezoelectric actuator, PMN-PNN-PZT system ceramics were fabricated using $Li_2CO_3-Bi_2O_3$-CuO as sintering aids and their piezoelectric and dielectric characteristics were investigated as a function of heating rate. At sintering temperature of $900^{\circ}C$, with increasing heating rate, electromechanical coupling factor(kp), mechanical quality factor(Qm) and dielectric constant $({\varepsilon}_r)$ were increased.

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