• 제목/요약/키워드: Increasing rate of temperature

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질산 인듐 수용액의 초음파 분무열분해에 의한 산회인듐 입자의 제조 (Preparation of Indium Oxide Particles by Spary Pyrolysis of Indium Nitrate)

  • 김기영;박승민
    • 한국세라믹학회지
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    • 제35권6호
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    • pp.529-534
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    • 1998
  • Agglomeration-free indium oxide particles were produced by ultrasonic pyrolysis of indium nitrate(3 hy-drate) solution. Th mean size of particles was increased from 3 $\mu\textrm{m}$ to 11$\mu\textrm{m}$ with increasing intial con-centrations of indium nitrate from 0.05mol% to 4.83 mol% When the input rate of indium nitrate solution was increased from 0.1 cm3/min to 0.8cm3/min the size of particles remained same and only the pro-duction rate of particles was increased. At 300$^{\circ}C$ the particles were white color with low crystallinity. But the color turned into yellow with increasing reaction temperature. The change of particle size was not ob-served with increasing temperatuer up to 700$^{\circ}C$ IR spectrum and TGA analysis confirmed that the purity of indium oxide was increased with temperature of reaction.

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터보과급 디이젤기관의 성능에 관한 실험적 연구 (An Experimental Study on the Performance of Turbocharged Diesel Engine)

  • 채재우;정성찬;백중현
    • 한국자동차공학회논문집
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    • 제2권6호
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    • pp.76-86
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    • 1994
  • Combustion of diesel engine depends on the mixing of air and evaporating fuel during ignition delay greatly. Variation of air-fuel mixing rate and ignition delay for engine operating condition causes difference of combustion, performance and exhaust emissions. This study is investigated in a turbocharged diesel engine of IDI swirl chamber type. In the results, As injection timing is advanced until $12.6^{\circ}$ BTC, ignition delay decreases. NOx concentration and smoke level in exhaust gas increases for advanced injection timing Ignition delay, combustion period, pressure rise rate and exhaust gas temperature are increased with increasing engine speed. And ignition delay at high load is more decreased than that at low load. Ignition delay and combustion period are decreased with increasing intake pressure. Power increases, temperature and CO, NOx concentration in exhaust gas decreases as intake pressure increases. With increasing load, ignition delay is decreased and combustion period, motoring pressure are increased.

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Poly(N-vinylpyrrolidone)이 그래프트된 Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) 공중합체의 합성 및 결정화 거동 (Preparation and Crystallization Behavior of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Grafted with Poly(N-vinylpyrrolidone))

  • Wang, Wei;Zhang, Yu;Chen, Yanmo
    • 폴리머
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    • 제31권5호
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    • pp.385-392
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    • 2007
  • Poly (N-vinylpyrrolidone) (PVP) groups were grafted onto a poly(3-hydroxybutyrate-co-3-hydroryvalerate) (PHBV) backbone in order to modify its properties and synthesize a novel biocompatible copolymer. The crystallization behavior of PHBV and grafted PHBV was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). During the cooling-induced crystallization process, the crystallization temperature and the crystallization rate of the grafted PHBV decreased with increasing PVP weight fraction. On the heating scans of all grafted PHBV samples, a new crystallization exothermic peak appeared at almost the same temperature, suggesting the operation of a recrystallization process, while the melting temperature ($T_m$) and the apparent enthalpy of fusion (${\Delta}H_f$) were not affected by graft modification. During the isothermal crystallization process at the same temperature, the presence of side PVP groups decreased the spherulitic growth rate and the spherulitic band spacing with increasing PVP weight fraction in samples.

메탄-수소-공기 예혼합기의 연소특성( I ) (Combustion Characteristics of Methane-Hydrogen-Air Premixture( I ))

  • 김봉석;권철홍
    • 한국자동차공학회논문집
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    • 제3권3호
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    • pp.129-139
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    • 1995
  • This study investigates the combustion characteristics of methane-hydrogen-air premixture in a constant volume combustion chamber. Primary factors of the combustion characteristics of methane- hydrogen-air premixture are the equivalence ratio and hydrogen supplement rate. In the case of $\phi$= 1.1, maximum combustion pressure and heat release rate have peaks, and they increase as the initial pressure and hydrogen supplement rate increase. The total burning time is also the shortest at the $\phi$= 1.1, it shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature is shown at the $\phi$= 1.0, and increasing the initial pressure and hydrogen supplement rate, it increases. The concentration of NO reveals the highest value at the $\phi$= 0.9, and it increases by increasing the initial pressure and hydrogen supplement rate. It is also found that the limit of lean inflammability of methane-hydrogen-air premixture is greatly widened by increasing the hydrogen supplement rate.

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마이크로파 조사에 따른 금속이 담지 된 활성탄의 특성 연구 (A Study on the Characteristics of Activated Carbons Supported Metal by Microwave Irradiation)

  • 김성욱;김정배;최성우
    • 한국환경과학회지
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    • 제18권5호
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    • pp.501-508
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    • 2009
  • In this study, the characteristics of granular activated carbon (GAC) supported metal was investigated in an area influenced by flame discharge and temperature variation during irradiating microwave. The modified GAC was formulated by impregnating metal hydroxides of nickel (Ni/GAC), barium (Ba/GAC), copper (Cu/GAC), zinc (Zn/GAC), cobalt (Co/GAC) and lanthanum (La/GAC). Ba/GAC was selected as it showed lack of spark discharge and temperature increasing aspects. Comparison of adsorption and desorption amount of GAC and Ba/GAC showed that adsorption and desorption rate of the GAC were higher than those of Ba/GAC. The results show that the presence of barium can decrease adsorption/desorption rate because of plugging pore of GAC. Toluene regeneration rate of Ba/GAC was better than that of GAC due to barium loading. Finally, GAC with barium can be controled a rapid increasing temperature and spark discharge, increased the regeneration rate of toluene during desorption by irradiating microwave.

Gelatinization and retrogradation characteristics of Korean rice cake in the presence of citric acid

  • Timilehin Martins Oyinloye;Won Byong Yoon
    • Journal of Applied Biological Chemistry
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    • 제66권
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    • pp.90-97
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    • 2023
  • The effect of citric acid on rice starch gelatinization and low-temperature (4 ℃) storage was studied in order to produce rice cake with a lower retrogradation rate. A citric acid solution in the ratio of 0, 0.5, 1.0, and 1.5% (w/w) of the water used during production was utilized. The gelatinization properties, gel strength, thermal properties, and texture analysis were evaluated to determine the retrogradation rate. The result showed that acid hydrolysis occurred in samples treated with citric acid. Thus, increasing citric acid decreased gelatinization temperature (58.63±1.98 to 45.84±1.24 ℃). The moduli of elasticity increased with increasing citric acid concentration, indicating an increased gel strength. Thermal analysis of starch showed that the onset, peak, and conclusion temperatures of retrogradation were increased significantly with the storage period and decreased with citric acid concentration. After 72 h of low-temperature storage (4 ℃), the retrogradation rate was lowest in the rice cake with 1.5% citric acid solution, with an increased ratio of 12.01 to 13.60% compared to the control sample, with a ratio of 12.99 to 43.54%. This shows a high retrogradation rate in the control sample. Additionally, sensory properties and retrogradation ratio suggest that the addition of 1.0% citric acid solution during rice cake production is efficient in retarding the retrogradation without an adverse effect on the rice cake modeling and acceptance.

극초고압 충돌분무시 충돌면의 온도거동에 관한 연구 (A Study on the Temperature Behavior of Impinging Plate in Impinging Spray with Ultra High pressure)

  • 정대용;김홍준;이종태
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.442-447
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    • 2003
  • The characteristics of instantaneous wall-surface temperature of impinging plate in case of ultra high pressure injection have been measured and analyzed by using thin film instantaneous temperature probe and ultra high pressure injection equipment. The decreasing rate of temperature was greater in case of higher temperature of impinging plate. Temperature drop was largest at center of piston and it was slight for others. Instantaneous temperature decreases rapidly with increasing injection pressure. But above 2,500bar of injection pressure, the decreasing rates are slightly affected by increasing injection pressure.

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적외선 열화상 데이터를 이용한 초기온도 상승률에 따른 철근의 부식률 예측 기법 (Prediction Method of Rebar Corrosion Level Using Infrared Thermographic Data according to Increasing Rate of Early Temperature)

  • 유주영;백인관;조승호;노영숙;정란
    • 한국방재학회:학술대회논문집
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    • 한국방재학회 2007년도 정기총회 및 학술발표대회
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    • pp.425-428
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    • 2007
  • In order to measure corrosion level of reinforcement rebar which is inside reinforced concrete structure, infrared thermographic technique was employed. Experimental test parameters were ambient temperatures, various levels of corrosion states. After analysis of temperature distributions of concrete surface, the amount of heat flux from the concrete surface is directly proportional to the corrosion level which is inside of concrete.

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Fretting Wear and Friction of lnconel 690 for Steam Generator Tube in Elevated Temperature Water

  • Lee, Young-Ze;Lim, Min-Kyu;Oh, Se-Doo
    • KSTLE International Journal
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    • 제3권1호
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    • pp.49-53
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    • 2002
  • Inconel 690 for nuclear steam generator tube has more chromium than the conventionally used Inconel 600 in order to increase the corrosion resistance. TD evaluate the tribological characteristics under fretting condition the fretting tests as well as sliding tests were carried out in elevated temperature water environment. Fretting tests of the cross-cylinder type were done under various vibrating amplitudes and applied normal loads in order to measure the friction forces and wear volumes. Also, the conventional sliding tests of pin-en-disk type were carried out to compare the test results. In fretting, the friction was very sensitive to the load and the amplitude. The friction coefficient decreased with increasing load and decreasing amplitude. Also, the wear of Inconel 690 can be predictable using the work rate model. Depending on normal loads and vibrating amplitudes, distinctively different wear mechanisms and of ten drastically different wear rates can occur. It was fecund that the fretting wear coefficients in water were increased as increasing the temperature of water.

산화철의 환원-산화 반응을 이용한 수소저장에 미치는 Rh/Ce/Zr의 효과 (The effect of Rh/Ce/Zr additives on the redox cycling of iron oxide for hydrogen storage)

  • 이동희;차광서;박주식;강경수;김영호
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.49-52
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    • 2007
  • We investigated hydrogen storage and production properties using redox system of iron oxide($Fe_{3}O_{4}$ + $4H_{2}$ ${\leftrightarrows}$ 3Fe + $4H_{2}O$) modified with rhodium, ceria and zirconia under atmospheric pressure. Reduction of iron oxide with hydrogen(hydrogen storage) and re-oxidation of reduced iron oxide with steam(hydrogen evolution) was carried out using a temperature programmed reaction(TPR) technique. On the temperature programmed studies, the effects of amounts of cerium and zirconium on the re-oxidation rate of partial reduced iron oxides were increased with increasing metal additives amount, but the rhodium amount showed little effect on the re-oxidation rate. On the thermal studies, the re-oxidation rates were enhanced with increasing temperature(300 $^{\circ}C$ < 350 $^{\circ}C$).

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