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Effects of a Radiation Crosslinking on a Drawn Microporous HDPE Film with a Nucleating Agent

  • Park, Jong-Seok;Gwon, Sung-Jin;Lim, Youn-Mook;Nho, Young-Chang
    • Macromolecular Research
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    • v.17 no.8
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    • pp.580-584
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    • 2009
  • The effects of crystallinity and radiation crosslinking on the physical properties of a microporous high density polyethylene (HDPE) film with Millad3988 as a nucleating agent were investigated. The pores of the HDPE film were affected by the crystallinity. The crystallinity of the HDPE films increased with increasing Millad3988 amount up to 0.1 wt% but decreased with further addition. The mechanical characteristics of the HDPE containing Millad3988 films improved with increasing irradiation dose up to 50 kGy, but decreased at 75 kGy due to severe degradation. The thermal shrinkage behavior of the HDPE films decreased with increasing radiation dose up to 50 kGy. The porosity of the stretched HDPEIMillad3988 films after ${\gamma}$-ray radiation increased with increasing y-ray radiation dose up to 50 kGy. The pores of the irradiated films were formed more easily by a stretching due to the formation of a crosslinked structure.

Preparation and Characterization of Novel Temperature and pH Sensitive (NIPAM-co-MAA) Polymer Microgels and Their Volume Phase Change with Various Salts (pH 감응성 NIPAM-co-MAA 고분자 마이크로젤의 제조 및 분석과 염 종류에 따른 부피상 변화)

  • Khan, Mohammad Saleem;Khan, Gul Tiaz;Khan, Abbas;Sultana, Sabiha
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.794-801
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    • 2013
  • Novel microgels of N-isopropylacrylamide (NIPAM)-co-methacrylic acid (MAA) (NIPAM-co-MAA) with different contents of N,N-methylene bis acrylamide (MBA) were prepared by emulsion polymerization technique and were studied by Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS) and zeta potential measurement. Effect of pH, temperature and different salts concentration on the microgel particles was investigated. DLS results have shown that the hydrodynamic radius of the microgel increased upon increasing pH and decreased upon increasing temperature. The swelling/deswelling behaviors as determined by DLS showed the ionic repulsions of the carboxyl group of the methacrylic acid and hydrophobic interaction of NIPAM. The effect of various salts on volume phase transition temperature (VPTT) was also investigated. Upon increasing salt concentration, VPTT became broad and shifted to a lower temperature. Electrophoretic mobility measurements showed an increase with increasing pH and temperature at a constant ionic strength.

Effect of Solution Annealing on the Microstructure and Mechanical Properties of Modified 440A Martensitic Stainless Steel (Mod. 440A 마르텐사이트 스테인리스강의 미세조직과 기계적 성질에 미치는 오스테나이트화 처리의 영향)

  • Kim, Young-Chul;Kwon, Soon-Doo;Jung, Byong-Ho;Kang, Chang-Yong
    • Journal of Power System Engineering
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    • v.17 no.4
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    • pp.103-108
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    • 2013
  • This study was investigated the effect of austenitizing treatment the microstructure and mechanical properties in modified 440A steel, and the results were as follows. The amount of remaining carbide decreases with increasing the austenitizing treatment temperature, and all carbide is completely dissolved at $1250^{\circ}C$. The amount of remaining carbide decreases with increasing the austenitizing treatment time, but the carbide remains insoluble up to 120 minutes at $1050^{\circ}C$. The strength and hardness gradually decrease with increasing the austenitizing treatment temperature and is significantly lower at $1250^{\circ}C$, while the elongation and the impact value rapidly increase. The strength and hardness rapidly decrease, the elongation and impact value rapidly insrease with increasing the austenitizing treatment time and exhibit no change at above 120 minutes. The austenitizing treatment modified 440A steel is required for temperature of above $1050^{\circ}C$ and time of above 60 minutes.

Recrystallization Behaviors of Ordered and Disordered Structures in Ll2 Type Ni3Fe Alloy (Ll2형 Ni3Fe 합금에서 규칙격자와 불규칙격자의 재결정거동)

  • Choi, C.S.;Kang, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.2
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    • pp.47-53
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    • 1991
  • Recrystallization behaviors of ordered and disordered structures in $Ll_2$ type $Ni_3Fe$ alloy were studied through hardness measurement and differential thermal analysis. When the disordered structure was isothermally aged at $480^{\circ}C$ below order-disorder transition temperature, the hardness of the structure was increased due to progressive ordering with increasing aging time. The hardness of the disordered structure was increased rapidly with increasing deformation degree up to 10%, and then gradually increased with further deformation degree. while the hardness of the ordered structure was increased rapidly with increasing deformation degree up to 10%, showing a constant hardness value up to 50% and gradually decreased with further deformation degree. The hardness of the ordered structure was higher than that of the disordered structure at all same deformation degrees. The recrystallization temperature of the ordered and disordered structures were decreased with increasing deformation degree. At the same deformation degrees, the recrystallization temperature of the ordered structure was lower than that of the desordered structure.

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The Quality Characteristics of Bacsulgi with Sea Mustard((Undaria pinnatifida) powder (미역 가루를 첨가한 백설기의 품질특성)

  • Jun, Na-Young;Kim, Sung-Ok;Han, Jin-Suk
    • Korean journal of food and cookery science
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    • v.22 no.5 s.95
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    • pp.591-599
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    • 2006
  • The purpose of this study was to investigate the effect of the addition of various concentrations of sea mustard powder on the quality characteristics of Bacsulgi. The sea mustard powder was added to rice powder at ratios of 3, 5, 7, and 9%(w/w). The moisture contents and salinity of Bacsulgi were increased with the addition of sea mustard powder. The incorporation of sea mustard powder in Bacsulgi lowered the lightness values but increased the blueness and yellowness values. Rheology test showed that hardness was significantly (p<0.05) decreased with increasing sea mustard powder content. The springiness and cohesiveness were decreased, whereas the adhesiveness was increased, with increasing sea mustard powder content. Scanning electron microscopy showed that the size of the air cells increased and the surface of rice powder swelled with increasing sea mustard powder content. The result of sensory evaluation showed that there were significant (p<0.05) differences in the scores of smell and taste sensory characteristics among the samples. The overall eating quality was the highest in the control and decreased with increasing sea mustard powder level. The study results suggested that Bacsulgi prepared with up to 5% addition of sea mustard powder was as acceptable as Bacsulgi prepared without sea mustard powder.

Effects of Air Blast Thawing Combined with Infrared Radiation on Physical Properties of Pork

  • Hong, Geun-Pyo;Shim, Kook-Bo;Choi, Mi-Jung;Min, Sang-Gi
    • Food Science of Animal Resources
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    • v.29 no.3
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    • pp.302-309
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    • 2009
  • This study investigated the effects of infrared (IR) radiation combined with air blast thawing on the physical properties of pork. Regardless of air velocity, increasing IR dosage produced an exponential increase in the thawing rate of pork. This rate increased further when air blast velocity was increased. IR treatments showed significantly lower thawing loss than that of 0 Watt treatment, while increasing air velocity significantly increased thawing loss of pork (p<0.05). Increasing both IR power and air velocity tended to decrease the cooking loss of pork. Moreover, increased IR power tended to decrease the water holding capacity and shear force of pork. The shear force changes were not significant (p>0.05). Shear force also increased with increasing air velocity. In addition, the higher the air velocity the higher the shear force of pork. In Commission Internationale de l'Eclairage (CIE) colour determination, control of temperature prevented discolouration from overheating of sample surface. The results suggest that IR dosage combined with air blast has potential in thawed meat quality aspects, and that humidity control could prevent surface drying.

Dielectric Properties of Ta2O5 Films Annealed at Various Temperature by MOCVD and MOD (MOCVD법과 MOD법으로 제작된 Ta2O5 박막의 열처리 온도에 따른 유전특성연구)

  • Kang, Pil-Kyu;Jhin, Jung-geun;Byun, Dong-jin;Bae, Jae-jun;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.801-805
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    • 2003
  • To explore the annealing temperature dependence of dielectric properties $Ta_2$$O_{5}$ thin films were prepared by MOCVD(metal-organic chemical vapor deposition) and MOD(metal-organic decomposition). The $Ta_2$$O_{5}$thin films fabricated MOCVD and MOD were annealed in $O_2$at temperature between 600 and 90$0^{\circ}C$. The measured dielectric constant of both films at 100 KHz was the highest value at $650^{\circ}C$ and decreased with increasing annealing temperature above $650^{\circ}C$. Plane-view SEM image showed that the boundary seems to be crack broke out with increasing annealing temperature. It was confirmed that outbreak of boundary influenced a decrease of dielectric constant with increasing annealing temperature. The leakage current density increased with increasing annealing temperature.

Influence of Change of Ni Concentration in Baths Fabricated by Dissolving Metal Ni Powders on Properties of Electrodeposited Ni Film (금속 Ni 분말을 용해하여 제조된 용액에서 Ni 농도 변화가 전기도금 된 Ni 필름 특성에 미치는 영향)

  • Yoon, Pilgeun;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.78-83
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    • 2019
  • Chloride baths for electrodeposited Ni thin films were fabricated by dissolving metal Ni powders with the mixed solution consisting of HCl and de-ionized water. Current efficiency, residual stress, surface morphology and microstructure of Ni films with the change of metal ion ($Ni^{2+}$) concentrations in the plating solution were studied. Current efficiency was measured to be more than 90% with increasing $Ni^{2+}$ concentrations in the plating solution. Residual stress of Ni thin film was increased from about 400 to 780 MPa with increasing $Ni^{2+}$ concentration from 0.2 to 0.5 M. It is gradually decreased to 650 MPa at 0.9 M $Ni^{2+}$ concentration. Smooth surface morphologies were observed over 0.3 M $Ni^{2+}$ concentration, but nodule surface morphology at 0.2 M. Ni films consist of FCC(111), FCC(200), FCC(220) and FCC(311) peaks in XRD patterns. Preferred orientation of FCC(111) was observed and its intensity was slightly decreased with increasing $Ni^{2+}$ concentration. The average grain size was slightly increased at 0.3 M $Ni^{2+}$ concentration and then slightly decreased with increasing $Ni^{2+}$ concentration.

Voltage dependent pulse shape analysis of Geiger-Müller counter

  • Almutairi, B.;Akyurek, T.;Usman, S.
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1081-1090
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    • 2019
  • Detailed pulse shape analysis of a Geiger-$M{\ddot{u}}ller$ counter is performed to understand the pulse shape dependence on operating voltage. New data is presented to demonstrate that not all pulses generated in a GM counter are identical. In fact, there is a strong correlation between the operating voltage and the pulse shape. Similar to detector deadtime, pulse shapes fall in three distinct regions. For low voltage region, where deadtime was reported to reduce with increasing voltage, pulse generated in this region was observed to have a fixed pulse width with a variable tail. The pulse width and fall time of the tail was observed to be a function of applied voltage; exponentially reducing with increasing voltage with an exponent of negative 6E-04 and 2E-03 respectively. The second region showed a pulse without any significant tail. During this time the detector deadtime was earlier reported to be at its minimum. The highest voltage region demonstrated a different deadtime mechanism where the second pulse was reduced in width. During this time the deadtime seemed to be increasing with increasing voltage. This data allows us to gain some unique insight into the phenomenon of GM detector deadtime not reported thus far.

Effects of TDS on formation of THMs in drinking water treatment (정수처리에서 TDS가 THMs 생성에 미치는 영향)

  • Lee, Seulki;Kwak, Yeonwoo;Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.3
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    • pp.225-234
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    • 2019
  • This study is focused on effects of factors that affect the formation of THMs during chlorination in drinking water treatment. During the chlorination, chlorine consumption is increased by increasing the initial chlorine dose, the pH and the total dissolved solid (TDS) concentration. Also THMs formation is increased up to $58.82{\mu}g/L$ and $55.54{\mu}g/L$ by increasing initial chlorine concentration and increasing pH. However, concentration of chloroform is decreased by increasing TDS concentration. This is caused the cation($Na^+$) of the total dissolved solids preferentially reacts with the functional groups of the organic material which influence the trihalomethane formation. But total trihalomethane formation is increased up to $127.46{\mu}g/L$ by $Br^-$ contained in the total dissolved solids. DOC reduction was not influenced by any of the factors.