• 제목/요약/키워드: Inconel alloys

검색결과 51건 처리시간 0.029초

인코넬 합금의 열처리에 따른 입계 탄화물 석출 및 입계응력부식 거동 (The Effects of Heat Treatment on Intergranular Carbide Precipitations and Intergranular Stress Corrosion Cracking of Inconel alloy)

  • 맹완영;남태운
    • 열처리공학회지
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    • 제10권4호
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    • pp.219-231
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    • 1997
  • Inconel alloys used as nuclear power plant components have experienced intergranular stress corrosion cracking problems inspite of their good corrosion characteristics. In order to investigate the effects of heat treatments on carbide precipitation and intergranular stress corrosion cracking(IGSCC) in Inconel alloys, DSC(Differential Scanning Calorimeter), TEM, EDXS and static potential corrosion tests were carried out. Thermal treatment at $750^{\circ}C$ for 15hours in Inconel alloys increased the density of intergranular carbide. The carbides are mainly $Cr_7C_3$ in Inconel 600, and $Cr_{23}C_6$ in Inconel 690. The Cr depletion around grain boundary is not crucial factor on IGSCC. The carbides in grain boundary play an important role as acting dislocation source, and as decreasing stress around growing crack.

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고온 리튬용융염에서 Ni 200 및 Ni-base 합금의 부식거동 (Corrosion Behavior of Ni 200 and Ni-base Alloys in Hot Lithium Molten salt)

  • 조수행;임종호;윤기석;박성원
    • 한국재료학회지
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    • 제14권4호
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    • pp.251-259
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    • 2004
  • In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650~800^{\circ}C$ for 24~312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

인코넬 합금의 미세조직과 기계적 특성에 미치는 냉각속도 영향 (Effect of Cooling Rates on Mechanical Properties and Microstructure of Inconel Alloys)

  • 박노경;이호성;채영석
    • 한국재료학회지
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    • 제17권10호
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    • pp.555-559
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    • 2007
  • The mechanical properties and microstructure of Inconel 690 and 600 alloys with various cooling rates were investigated. Optical microscopy and scanning electron microscopy observations indicated that in case of the cooling rate of $0.5^{\circ}C/min$, discontinuous carbides along the grain boundaries were formed and when the cooling rate was $10^{\circ}C/min$, continuous carbides were formed in Inconel 690 and 600 alloys. For the annealed Inconel 690 alloy with high Cr content, a lot of annealing twins, which led the preferential growth of (111) planes, were observed. However, the annealed Inconel 600 alloy with low Cr content showed a few annealing twins and the preferential growth of (200) planes. Inconel 600 alloy had a larger value of ultimate tensile strength (UTS) than Inconel 690 alloy.

LiCl-Li2O 용융염에서 Inconel 합금 및 Incoloy 800H의 고온 부식거동 (Hot Corrosion Behavior of Inconel Alloys and Incoloy 800H in Molten LiCl-Li2O Salt)

  • 임종호;최정묵
    • 한국재료학회지
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    • 제23권2호
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    • pp.128-134
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    • 2013
  • A study on the corrosion behavior of Inconel alloys and Incoloy 800H in molten salt of LiCl-$Li_2O$ was investigated at $650^{\circ}C$ for 24-312 hours in an oxidation atmosphere. The order of the corrosion rate was Inconel 600 < Inconel 601 < Incoloy 800H < Inconel 690. Inconel 600 showed the best performance suggesting that the content of Fe, Cr and Ni are the important factor for corrosion resistance in hot molten salt oxidation conditions. The corrosion products of Inconel 600 and Inconel 601 were $Cr_2O_3$ and $NiFe_2O_4$, In case of Inconel 690, a single layer of $Cr_2O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2O_4$ and inner layer of $Cr_2O_3$ were formed with an increase of corrosion time. In the case of Incoloy 800H, $Cr_2O_3$ and $FeCr_2O_4$ were observed. Most of the outer scale of the alloys was observed to be spalled from the results of the SEM analysis and the unspalled scale which adhered to the substrate was composed of three layers. The outer layer, the middle one, and the inner one were Fe, Cr, and Ni-rich, respectively. Inconel 600 showed localized corrosion behavior and Inconel 601, 690 and Incoloy 800H showed uniform corrosion behavior. Ni improves the corrosion resistance and too much Cr and/or Fe content deteriorates the corrosion resistance.

고온용융염계 산화분위기에서 초합금의 부식거동 (Corrosion Behavior of Superalloys in Hot Molten Salt under Oxidation Atmosphere)

  • 조수행;임종호;정준호;이원경;오승철;박성원
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.285-291
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    • 2004
  • LiCl-$Li_2O-O_2$ 용융염계에서 용융염 취급장치의 구조재료를 위한 평가의 일환으로 Inconel 718, X-750, Haynes 75, 263 합금의 부식거동을 분위기온도; $650^{\circ}C$, 부식시간: 24~168h, $Li_2O$농도; 3wt%, 혼합가스농도; Ar-10%$O_2$에서 조사하였다. LiCl-$Li_2O-O_2$ 용융염계에서 부식속도는 Haynes 263 < Haynes 75 < Inconel X-750 < Inconel 718 순서로 나타났으며, Haynes 263 합금이 가장 우수한 내부식성을 나타내었다. Haynes 75의 부식생성물은 $Cr_2O_4$, $NiFe_2O_4$, $LiNiO_2$, $Li_2NiFe_2O_4$, Inconel 718의 부식생성물은 $Cr_2O_4$$NiFe_2O_4$ 이며 Haynes 263은 $Li(Ni,Co)O_2$, $NiCr_2O_4$$LiTiO_2$, Inconel X-750은 $Cr_2O_3$, $NiFe_2O_4$,$FeNi_3$, (Al,Nb,Ti)$O_2$의 부식생성물을 나타내었다. Haynes 263은 국부부식의 거동을 보이는 반면, Haynes 75, Inconel 718 및 Inconel X-750은 전면 부식 거동을 나타내었다.

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물분위기에서의 인코넬 합금의 마멸기구 (Wear Mechanism of Inconel Alloys in Room Temperature Water)

  • 이영호;김인섭
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2001년도 제34회 추계학술대회 개최
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    • pp.103-108
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    • 2001
  • Wear test has been performed to evaluate the wear mechanism of Inconel alloys against ferritic stainless steels in room temperature water. By means of scanning electron microscopy (SEM), the worn surface and microstructure of subsurface layer have been examined. The wear at steady state conditions result in the formation of 5∼7${\mu}$m thick layers with fragmented microstructure. The thickness of these layers seems to depend on the ability of work hardening and deformation accommodation at the contact areas during wear. Therefore, in room temperature water, the wear rate is closely related with the wear resistance of these fragment microstructure which are generated after severe subsurface deformation.

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액체 추력기용 내열합금 소재에 대한 용접 특성 연구 (Welding Properties of Heat-resistant Alloys for Liquid Thruster)

  • 유상현;이제훈;김정오;김정훈;이재원
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2005년도 제25회 추계학술대회논문집
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    • pp.177-183
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    • 2005
  • 본 연구에서는 액체 추력기에 적용될 내열합금 소재인 Inconel 600, Inconel 625, Haynes 230에 대해 Nd:YAG 레이저 용접 및 전자빔 비드 온 플레이트 용접을 수행하였다. 레이저 용접과 전자빔 용접 시 각각의 변수가 용접비드 형상에 미치는 영향을 분석하였으며 용접 조건들이 용접성에 미치는 영향을 조사하기 위하여 조직, 미세경도 및 인장강도 등의 실험을 하였다. 또한, 레이저와 전자빔 용접 실험 결과를 분석하여 최적의 용접방법과 조건을 도출하였다.

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고분자 전해질 연료전지 금속 분리판용 금속의 염화물 농도에 따른 전기화학적 특성 연구 (Investigation on Electrochemical Characteristics of Metallic Bipolar Plates with Chloride Concentrations for PEMFC)

  • 신동호;김성종
    • Corrosion Science and Technology
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    • 제20권6호
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    • pp.347-360
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    • 2021
  • Currently, the demand for eco-friendly energy sources is high, which has prompted research on polymer electrolyte membrane fuel cells. Both aluminum alloys and nickel alloys, which are commonly considered as materials of bipolar plates in fuel cells, oxide layers formed on the metal surface have excellent corrosion resistance. In this research, the electrochemical characteristics of 6061-T6 aluminum alloy and Inconel 600 were investigated with chloride concentrations in an acid environment that simulated the cathode condition of the PEMFC. After potentiodynamic polarization experiments, Tafel analysis and surface analysis were performed. Inconel 600 presented remarkably good corrosion resistance under all test conditions. The corrosion current density of 6061-T6 aluminum alloy was significantly higher than that of Inconel 600 under all test conditions. Also, 6061-T6 aluminum alloy and Inconel 600 presented uniform corrosion and intergranular corrosion, respectively. The Ni, Cr, and Fe, which are the main chemical compositions of Inconel 600, are higher than Al in the electromotive force series. And a double oxide film of NiO-Cr2O3, which is more stable than Al2O3, is formed. Thus, the corrosion resistance of Inconel 600 is better.

고온 리튬용융염계 산화분위기에서 Inconel 합금의 부식거동 (Corrosion Behavior of Inconel Alloys in a Hot Lithium Molten Salt under an Oxidizing Atmosphere)

  • 조수행;서중석;윤지섭;박성원
    • 한국재료학회지
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    • 제16권9호
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    • pp.557-563
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    • 2006
  • The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, MA 754, X-750 and 718 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for $72{\sim}216$ hours. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3,\;NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3\;and\;Li_2Ni_8O_{10}$ while $Cr_2O_3,\;NiFe_2O_4\;and\;CrNbO_4$ were produced from Inconel 718. Also, corrosion products of Inconel X-750 were found to be $Cr_2O_3,\;NiFe_2O_4\;and\;(Cr,Nb,Ti)O_2$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, 718, X-750 showed uniform corrosion behavior.

Nd:YAG 레이저를 이용한 초합금 소재의 용접 특성 연구 (Welding Characteristic of Super Alloys for Nd:YAG Laser)

  • 유상현;이제훈;서정;김정오;이영호
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2006년 추계학술발표대회 개요집
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    • pp.158-160
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    • 2006
  • Super alloys are typically used for the liquid thruster in the aerospace industry. In this work, The bead-on-plate welding of Inconel 600, Inconel 625 and Haynes 230 using Nd:YAG laser are studied, in order to examine the effects of experimental parameters on their weldability. The micro-hardness and tensile strength of the specimens are also analyzed, to obtain the optimal welding conditions.

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