• Title/Summary/Keyword: Inclusion-complex

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Metallogenesis and Petrology of the Gwangyang Gold Deposits and Goheung Copper Deposits (광양금광상(光陽金鑛床), 고흥동광상(高興銅鑛床)의 광상생성(鑛床生成)과 암석학적(岩石學的) 연구(硏究))

  • Park, Young Surk;Shin, Byung Woo
    • Economic and Environmental Geology
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    • v.17 no.2
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    • pp.91-100
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    • 1984
  • The Gwangyang gold deposits geologically consist of granitic gneiss, metatectic gneiss and porphyroblastic gneiss which correspond to Jirisan gneiss complex. The formations of Gyeongsang system lies unconformably on these gneisses and are intruded by diorite, porphyritic andesite and Bulgugsa granites. Goheung districts are composed of quartz schist, andesitic rock, tuff and granite. The Gwangyang gold deposits are gold bearing fissure filling veins. The vein thickness varies from 15cm to 40cm and they consist of 7-10 layers in parallel. The Goheung copper deposits are sulphide bearing quartz veln which filled the fracture in andesitic rock and biotite granite. The contact zone of these rocks is partially altered. The mineral paragenesis of the Gwangyang and Goheung districts is pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, galena, sericite, quartz and calcite. The variation trends of FMA and A'KF triangular diagrams and the differentiation index (norm, Q + Or + Ab) versus oxides diagrams is similar to the Gyeonsang basin igneous rocks. From the trace element analysis of 10 samples of country rocks, wall rocks and veins, the distribution of copper and lead contents display a correlative distribution pattern in relation to gold and silver. Homogenization temperature of fluid inclusions range from $200^{\circ}C$ to $270^{\circ}C$ in quartz from the Gwangyang gold vein and the size of fluid inclusion range from 0.01mm to 0.04mm. The fluid inclusions are mainly one or two phase and the filling degree of the inclusions varies from 85 to 95.

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Hydro-structural issues in the design of ultra large container ships

  • Malenica, Sime;Derbanne, Quentin
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.4
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    • pp.983-999
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    • 2014
  • The structural design of the ships includes two main issues which should be checked carefully, namely the extreme structural response (yielding & buckling) and the fatigue structural response. Even if the corresponding failure modes are fundamentally different, the overall methodologies for their evaluation have many common points. Both issues require application of two main steps: deterministic calculations of hydro-structure interactions for given operating conditions on one side and the statistical post-processing in order to take into account the lifetime operational profile, on the other side. In the case of ultra large ships such as the container ships and in addition to the classical quasi-static type of structural responses the hydroelastic structural response becomes important. This is due to several reasons among which the following are the most important: the increase of the flexibility due to their large dimensions (Lpp close to 400 m) which leads to the lower structural natural frequencies, very large operational speed (> 20 knots) and large bow flare (increased slamming loads). The correct modeling of the hydroelastic ship structural response, and its inclusion into the overall design procedure, is significantly more complex than the evaluation of the quasi static structural response. The present paper gives an overview of the different tools and methods which are used in nowadays practice.

Aqueous Solubility Enhancement of Some Flavones by Complexation with Cyclodextrins

  • Kim, Hyun-Myung;Kim, Hyun-Won;Jung, Seun-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.590-594
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    • 2008
  • The inclusion complexes of cyclodextrins (CDs) with flavones in aqueous solution were investigated by phase solubility measurements. The effect of b -cyclodextrin (b -CD), heptakis (2,6-di-O-methyl) b -cyclodextrin (DM-b -CD) and 2-hydroxypropyl-b -cyclodextrin (HP-b -CD) on the aqueous solubility of three flavones, namely, chrysin, apigenin and luteolin was investigated, respectively. Solubility enhancements of all flavones obtained with three CDs followed the rank order: HP-b -CD > DM-b -CD > b -CD, and besides, CDs show higher stability constant on luteolin than that on others flavones. 1H-nuclear magnetic resonance (NMR) spectroscopy and molecular modeling was used to help establish the model of interaction of the CDs with luteolin. NMR spectroscopic analysis suggested that A-C ring, and part of the B ring of luteolin display favorable interaction with the CDs, which was also confirmed by docking studies based on the molecular simulation. The observed augmentation of solubility of luteolin by three CDs was explained by the difference of electrostatic interaction of each complex, especially hydrogen bonding.

Optimization of Spray Drying Process for Manufacturing Dried Vinegar using Response surface methodology (분말식초제조를 위한 분무건조공정의 최적화)

  • 황성희;정용진;윤광섭
    • Food Science and Preservation
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    • v.9 no.2
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    • pp.194-199
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    • 2002
  • This study was conducted to develop processing method for vinegar powder from natural vinegar for encapsulation applications. To optimize the spray drying process, experiment was designed by central composition method to find optimal conditions for manufacturing vinegar powder. The acidity, water absorption, solid content and heat stability of vinegar powder were selected as response variables. The optimal concentration of inclusion complex which was made with vinegar and ${\beta}$-cyclodextrin was determined on 30。bx. On increasing the concentration of ${\beta}$-cyclodextrin as a wall material, the quality of the vinegar was decreased. The optimum conditions of spray drying process for manufacturing vinegar powder were 188∼192$^{\circ}C$ and 500∼600 Lh$\^$ -1/ as inlet temperature and flow rate, respectively.

A Structure Non-Contact and Non-destructive Evaluation Using Laser-Ultrasonics Application (구조물의 비접촉 비파괴 검사를 위한 레이저 초음파법 적용)

  • Kim Jae-Yeal;Song Kyung-Seok;Yang Dong-Jo;Kim You-Hong
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.71-76
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    • 2005
  • The defects evaluation of the interior and the surface would be considered as vital characteristics in predicting the total life span of the steel structure. More importantly, the understandings in the interior composite of welding zone and the notifications in the presence, the formation, and the positioning of the non-metallic inclusion are necessary as well, since there were signs of relatively high defect frequency presented in the welding zone. The ultrasonic testing is a highly recommended technique chosen from among other techniques because of variety of advantages in conducting the non-destructive testing for the welding zone. However, the ultrasonic testing had technical disadvantages referred as followings; the problems due to the couplant between the PZT and the specimen, the formations that were miniature and complex, the moving subject, and the high temperature surrounding the specimen. This research was conducted to resolve the technical disadvantages of the contact ultrasonic testing by studying the non-contact ultrasonic testing where the ultrasonic waves were transferred by the laser, and revealing the specimen defects at its interior part and its surface part. The ultimate goal of this research was to develop a non-destructive evaluation applying the laser manipulated ultrasonic method for the steel structure.

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Molecular Modeling of Enantio-discrimination of α-Methoxy-α-trifluoromethylphenylacetic Acid (MTPA) by Cyclomaltoheptaose (β-Cyclodextrin) and 6-Amino-6-deoxy-cyclomaltoheptaose

  • Jung, Eun-Kyoung;Jeong, Karp-Joo;Lee, Sang-San;Kim, Jee-In;Jung, Seun-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1627-1631
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    • 2003
  • Molecular modeling was performed to comprehend the chiral recognition of ${\alpha}$-methoxy-${\alpha}$-trifluoromethylphenylacetic acid (MTPA) enantiomers by cyclomaltoheptaose (${\beta}$-cyclodextrin,${\beta}$-CD) and 6-amino-6-deoxy-cyclomaltoheptaose (am-${\beta}$-CD). Monte Carlo (MC) docking coupled to constant temperature molecular dynamics (MD) simulations was applied to the investigation for the ${\alpha}$-methoxy-${\alpha}$-trifluoromethylphenylacetic acid complexation with two different CDs in terms of the relative distribution of the interaction energies. The calculated results are finely correlated with the experimental observations in chiral recognition thermodynamics. Am-${\beta}$-CD as a host showed the superior enantio-discrimination ability to the native ${\beta}$-CD where the amino group of am-${\beta}$-CD was critically involved in enhancing the ability of chiral discrimination via the Coulombic interaction with MTPA.

OPTIMIZED NUMERICAL ANNULAR FLOW DRYOUT MODEL USING THE DRIFT-FLUX MODEL IN TUBE GEOMETRY

  • Chun, Ji-Han;Lee, Un-Chul
    • Nuclear Engineering and Technology
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    • v.40 no.5
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    • pp.387-396
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    • 2008
  • Many experimental analyses for annular film dryouts, which is one of the Critical Heat Flux (CHF) mechanisms, have been performed because of their importance. Numerical approaches must also be developed in order to assess the results from experiments and to perform pre-tests before experiments. Various thermal-hydraulic codes, such as RELAP, COBRATF, MARS, etc., have been used in the assessment of the results of dryout experiments and in experimental pre-tests. These thermal-hydraulic codes are general tools intended for the analysis of various phenomena that could appear in nuclear power plants, and many models applying these codes are unnecessarily complex for the focused analysis of dryout phenomena alone. In this study, a numerical model was developed for annular film dryout using the drift-flux model from uniform heated tube geometry. Several candidates of models that strongly affect dryout, such as the entrainment model, deposition model, and the criterion for the dryout point model, were tested as candidates for inclusion in an optimized annular film dryout model. The optimized model was developed by adopting the best combination of these candidate models, as determined through comparison with experimental data. This optimized model showed reasonable results, which were better than those of MARS code.

Three-Dimensional Metal Complex Host with Alternating Arrangement of the Occupied and Vacant Channels. The Crystal Structure of Cd(NH₂CH(CH₃)CH₂NH₂)Ni(CN)₄· 0.25G (G=$CH_3C_6H_5, p-(CH_3)_2C_6H_4$)

  • 박기민;이욱;Toschitake Iwamoto
    • Bulletin of the Korean Chemical Society
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    • v.17 no.10
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    • pp.919-924
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    • 1996
  • Crystal structure of two inclusion compounds Cd(pn)Ni(CN)4·0.25G (G=toluene and p-xylene, pn=1,2-diaminopropane) have been determined from single-crystal X-ray diffraction data; toluene clathrate: monoclinic P21/n, a=13.838(6), b=26.893(5), c= 7.543(5) Å, γ=90.92(3)°, Z=4, R=0.0616; p-xylene clathrate: monoclinic P21/n, a=13.895(2), b=26.900(3), c=7.613(1) Å, γ=91.06(1)°, Z=4, R=0.0486. The host structures determined for toluene- and pxylene-guest clathrates are substantially identical to the U-type structures observed for the straight chain aliphatic-guest clathrates. However, the alternating arrangement of occupied channels with the guest molecules and vacant channels appears in the host structure. The non-centrosymmetric toluene molecules are distributed about the inversion center to give an image like p-xylene molecule. The guests, toluene and p-xylene, prefer the U-type channel, favoring the interaction between the π-electrons of the aromatic ring and the pn-amino groups to hold the aromatic ring vertical to the cyanometallate meshes.

Study on the Improvement of Waterproofing Performance Rating for the Introduction of Residential Apartment Complex Performance Grade Index (공동주택 성능등급 표시제도 강화를 위한 방수성능 등급 도입에 관한 연구)

  • An, Ki-Won;Cho, Il-Kyu;Oh, Sang-Keun
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.12
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    • pp.41-49
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    • 2018
  • The current housing performance rating system displays the performance rating of the houses supplied by the housing construction company, approved by the Housing Law. This system is intended to provide accurate information to the consumers in the announcement of the tenant recruitment, thereby improving the quality of the housing. This system was revised in January 2005 and implemented from January 2006. It is obligatory for companies with a scale of more than 1,000 households (energy performance rating is over 300 households), but there is currently no content on the waterproofing field. Therefore, this study suggests the revision plan proposes the necessity of the inclusion of the performance grade for the waterproofing field which is not currently implemented in the apartment house performance rating system, and to understand how to secure an adequate living environment. As a result, according to survey results, the performance score based on the difficulty of the maintenance method according to future leaks was selected and the revised system was prepared. Based on this, the performance grade for the virtual apartment was evaluated, and the results show that the performance of various grades is presented accordingly.

A systematic review of interventions for family caregivers of the elderly with dementia in Korea (국내 치매노인 가족 부양자 중재에 대한 체계적 고찰)

  • Jeong, Seonghee;Hwang, Jeonghae;Oh, Doonam
    • The Journal of Korean Academic Society of Nursing Education
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    • v.27 no.3
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    • pp.306-320
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    • 2021
  • Purpose: This study was a systematic review to assess the contents and effects of an intervention program for family caregivers of the elderly with dementia in Korea. Methods: A literature search was done using Medline, CINAHL, RISS, KISS, and DBpia to identify studies reported in English or Korean from 2000 to 2021. Results: A total of 1,162 articles were searched; finally, 23 articles were used in the analysis based on the inclusion and exclusion criteria. The most applied intervention contents were knowledge provision and emotional support. Fourteen articles (60.9%) reported on complex interventions, including emotional, social support, relaxation, and various activities. The most frequently measured outcome variable in the reviewed literature was "burden," followed by "depression" and "coping strategy." Conclusion: The review results can provide basic data for establishing evidence and suggesting directions of interventions for family caregivers of the elderly with dementia.