• Analytical Science and Technology
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• v.28 no.4
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• pp.255-259
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• 2015

A technique on the determination of Co(II) in aqueous samples with quinalizarin-β-cyclodextrin inclusion complex was developed. The conditions such as pH of the sample solution, the concentration of quinalizarin and the concentration of β-CD were optimized to 11.3(±0.2), 1.2×10⁻⁶ M and 8.0×10⁻⁶ M, respectively. Under these optimum conditions, the calibration curve of Co(II) was obtained over concentration range of 5.0×10⁻⁹ ~ 1.2×10⁻⁷ M. The detection limit was 4.2×10⁻⁹ M (0.25 ng/mL). For validating this proposed technique, aqueous samples(stream water, reservoir water and tap water) were used. Recovery yields of 95~105% were obtained. The relative standard deviation(%) in aqueous samples were less than 7.0%. Based on experimental results, it is proposed that this technique can be applied to the practical determination of Co(II).

• Journal of Adhesion and Interface
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• v.13 no.4
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• pp.163-170
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• 2012

Although ${\beta}$-cyclodextrin (${\beta}$-CD) has been used as medicine, agrichemical, food, cosmetic, antioxidant, anti-volatile agent, anti-hygroscopic agent, fading-protecting agent, and emulsifier due to its ability to form inclusion complex by enclosing another molecule (guest molecule), it has been restricted in practical application because of its low solubility in water and organic solvent. In this study, ${\beta}$-CD derivative as a new polyol with inclusion characteristics against Bisphenol A and cyclopropane, foaming agent for polyurethane (PU), and with improved solubility was synthesized, characterized and used to formulate rigid PU foam with better thermal conductivity and compressive strength compared to that from commercial polyols.

• English & American cultural studies
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• v.14 no.1
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• pp.219-239
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• 2014

Arjun Appadurai contends that "the new global cultural economy has to be seen as a complex, overlapping, disjunctive order that cannot any longer be understood in terms of existing center-periphery models" (32); though discerning and perhaps becoming more and more apt, Appadurai's observation of the breakdown of the "center-periphery" binary appears as mere "academic jargon" in the lives of new immigrants, tackling the murky waters of identity politics in the transcultural technoscape of modern America in Kunzru's Transmission. Kunzru's antihero is Arjun Mehta, a software technician, who comes to America with high hopes of realizing the "American Dream." To a certain extent, Arjun himself is culpable of resurrecting the "center" as he prioritizes America and its values over all else. Despite his best efforts, Arjun cannot prevail in the perilous politics of exclusion/inclusion, and is relegated into a "high-tech coolie," exploited for his technological savvy. Even as the "center-periphery" binary stays intact in the production of an (Asian) American identity, it becomes undone in the hands of this "would-be" American; ultimately denied inclusion into America, Arjun unleashes a destructive virus that has major global consequences. In a sense, the boundary that separates the center and the periphery comes down as both collectively become victims to Arjun's retributive malfeasance. Arjun seems to rely on the "American" promise that old allegiances (to a national identity) are now defunct and new ones can be easily forged; as Kunzru's Transmission demonstrates with the tragic story of Arjun, the complex politics of identity production in America does not necessarily deliver on this promise. This essay hence aims to examine the politics of (national) belonging in the age of transnationalism.

• Korean Chemical Engineering Research
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• v.43 no.1
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• pp.110-117
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• 2005

In this work, solid-state inclusion complex powders of itraconazole and $2-hydroxypropyl-{\beta}-cyclodextrin(HP-{\beta}-CD)$ were produced by a supercritical anti-solvent (SAS) process. In order to evaluate the degree of complexation, the thermal behavior of the microparticulate complexes was investigated using differential scanning calorimetry. The experimental results obtained for the solubility and dissolution rate of the microparticulate inclusion complexes in a buffer solution of pH 1.2 showed that the complexation of itraconazole with $HP-{\beta}-CD$ results in a significant increase in the solubility and dissolution rate of itraconazole. The particle size of the SAS-produced inclusion complexes was dramatically reduced ($<0.1-0.5{\mu}m$) compared with untreated itraconazole ($30-50{\mu}m$) and $HP-{\beta}-CD$ ($50-100{\mu}m$). The solubility of itraconazole was increased with the increase of pressure at a constant temperature to ca. $758.6{\mu}g/mL$ in an aqueous medium of pH 1.2. The dissolution rate of itraconazole was observed to be significantly improved and about 90% of itraconazole was found to be dissolved within 5-10 min.

• The Journal of the Acoustical Society of Korea
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• v.36 no.6
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• pp.387-393
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• 2017

The dynamic interactions between benzoic acid derivative ($pH{\approx}7.0$)(guest) and ${\beta}$-cyclodextrin (${\beta}$-CD)(host) were investigated in an aqueous solutions in terms of ultrasonic absorption in the frequency range 0.2 MHz ~ 50 MHz with emphasis on the low-frequency range below 1 MHz at $25^{\circ}C$. We show that the interaction of ${\beta}$-CD and benzoic acid derivative complies with a typical spectrum of a single relaxation process around a few MHz. The ultrasonic relaxation observed in these solutions was due to a perturbation of a chemical equilibrium related to a reaction of an inclusion complex formed by the host and guest. The rate constant ($k_b=7.48{\times}10^6M^{-1}s^{-1}$) and equilibrium constant ($K=68.6M^{-1}$) were determined from the concentration dependences of benzoic acid on the relaxation frequency. The standard volume change (${\Delta}V=10.6{\times}10^{-6}m^3mol^{-1}$) of the reaction was also computed from the maximum absorption per wavelength. It was found that the hydrophobicity of guest molecules played an important role in the formation of the inclusion complex.

• Archives of Pharmacal Research
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• v.15 no.2
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• pp.176-183
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• 1992

The stabilizing effects of $\alpha$-$\beta$-$\gamma$- and dimethyl-$\beta$-cyclodextrins $(\alpha$-, $\beta$-, $\gamma$- and DM-$\beta-$-CyDs) on the degradation of hydrocortisone 17-butyrate (HC-17B) in aqueous solution was investigated. Hc-17B underwent a facile hydroxide ion-catalyzed rearrangement to the less active 21-butyrate ester by the apparent first-order kinetics, and maximum stability of HC-17B was obtained at around pH 4.0. The stability of HC-17B was increased by inclusion complexation with $\alpha$-, $\gamma$- and DM-$\beta$-CyD in the pH range of 2.0-8.0 examined, whereas $\beta$-CyD accelerated the degradation of HC-17B at the pH higher than 5.0. The effects of ionic strength, solvent, temperature and CyD concentration were also investigated. Stability constants and apparent degradation rate constants of HC-17B-$\gamma$-CyD and HC-17B-DM-$\beta$-CyD complexes were determined kinetically on the basis of 1:1 complexation. The results suggested that the inclusion complexation with $\gamma$-CyD or DM-$\beta$-CyD was most useful means to enhance the stability of the steroid.

• Progress in Superconductivity and Cryogenics
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• v.25 no.4
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• pp.10-13
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• 2023

To confirm the room-temperature superconductivity at ambient pressure as claimed in recent arXiv preprints by Lee et al., we followed the original authors' systematic solid-state synthesis recipe to reproduce Cu-doped Pb-apatite, known as LK-99. Using X-ray diffraction and Raman spectroscopy, we identified inclusion of various impurities alongside the apatite phase in our sample. While the sample exhibited an overall semiconducting behavior in electrical transport, an intriguing resistivity anomaly at 380 K was observed, possibly originating from a structural phase transition of the Cu_2-δS impurity. Based on the transport and magnetization measurements, we conclude that the sample is a non-magnetic semiconductor, with absence of superconductivity.

• Structural Engineering and Mechanics
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• v.43 no.6
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• pp.795-821
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• 2012

The size and topology of geometrically nonlinear dome structures are optimized thereby minimizing both its entire weight & joint (node) displacements and maximizing load-carrying capacity. Design constraints are implemented from provisions of American Petroleum Institute specification (API RP2A-LRFD). In accordance with the proposed design constraints, the member responses computed by use of arc-length technique as a nonlinear structural analysis method are checked at each load increment. Thus, a penalization process utilized for inclusion of unfeasible designations to genetic search is correspondingly neglected. In order to solve this complex design optimization problem with multiple objective functions, Non-dominated Sorting Genetic Algorithm II (NSGA II) approach is employed as a multi-objective optimization tool. Furthermore, the flexibility of proposed optimization is enhanced thereby integrating an automatic dome generating tool. Thus, it is possible to generate three distinct sphere-shaped dome configurations with varying topologies. It is demonstrated that the inclusion of brace (diagonal) members into the geometrical configuration of dome structure provides a weight-saving dome designation with higher load-carrying capacity. The proposed optimization approach is recommended for the design optimization of geometrically nonlinear dome structures.

• Journal of the Semiconductor & Display Technology
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• v.12 no.3
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• pp.53-57
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• 2013

Human emotions are expressed in various ways. It can be expressed through language, facial expression and gestures. In particular, the facial expression contains many information about human emotion. These vague human emotion appear not in single emotion, but in combination of various emotion. This paper proposes a emotional expression algorithm using Active Appearance Model(AAM) and Fuzz k- Nearest Neighbor which give facial expression in similar with vague human emotion. Applying Mahalanobis distance on the center class, determine inclusion level between center class and each class. Also following inclusion level, appear intensity of emotion. Our emotion recognition system can recognize a complex emotion using Fuzzy k-NN classifier.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.178-179
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• 2003

Mesothermal, tellurium-bearing gold-silver vein mineralization of the Yuryang mine was formed in mineralogically complex quartz-sulfide veins that filled the fault fractures in Precambrian gneiss within Gyeonggi Massif. Ore grades average 179 g/ton gold with a gold/silver ratio of 1.5 : 1. Ore mineralization was deposited in single stage. Major ore mineralization can be divided into two mineralization phases with increasing paragenetic time: Fe-sulfide and base-metal mineralization phase $\rightarrow$ telluride mineralization phase. (omitted)