• Tunnel and Underground Space
• /
• v.2 no.1
• /
• pp.164-176
• /
• 1992

The conical-ended borehole technique and hemispherical-ended borehole technique are proposed, for the accurate stress measurement within a rock mass. Theory of stress tensor determination and in situ measurement system are presented with successful case examples, and the characteristics of stress distribution within rock masses are examined by the multiple times measurement in a single borehole. Subsequently, the problem in relation to the numerical approach for cavern designing is discussed on the basis of the dependency of the stress discontinuity on the geological discontinuities and so on.

• Journal of the Semiconductor & Display Technology
• /
• v.17 no.1
• /
• pp.50-53
• /
• 2018

Cyclic measurement system using relay circuit for organic light emitting diode (OLED) was demonstrated. The OLED characterization such as current-voltage, impedance, and capacitance-voltage is performed in sequence, repetitively and automatically under full control of the personnel computer (PC) without changing the connection of cables. Owing to in situ degradation by cyclic measurement, the time dependence of the data can give good information on the reliability factor of the OLED devices. Therefore, both performance and reliability of the OLEDs can be evaluated, with no manual operation during the entire process.

• Journal of the Optical Society of Korea
• /
• v.15 no.1
• /
• pp.96-102
• /
• 2011

Simultaneous measurements using a scanning spectrograph system and transmissometer were performed for the first time over an urban site in Gwangju, Korea, to derive the ambient $NO_2$ volume mixing ratio. The differential slant column densities retrieved from the scanning spectrograph system were converted to volume mixing ratios using the light traveling distance along the scanning line of sight derived from the transmissometer light extinction coefficients. To assess the performance of this system, we compared the derived $NO_2$ volume mixing ratios with those measured by an in situ chemiluminescence monitor under various atmospheric conditions. For a cloudless atmosphere, the linear correlation coefficient (R) between the two data sets (i.e., data derived from the scanning spectrograph and from the in situ monitor) was 0.81; the value for a cloudy atmosphere was 0.69. The two sets of $NO_2$ volume mixing ratios were also compared for various wind speeds. We also consider the measurement errors, as estimated from an error propagation analysis.

• Korean Chemical Engineering Research
• /
• v.47 no.3
• /
• pp.287-291
• /
• 2009

The heterogeneous decomposition of ammonia on a quartz surface in an inverted, stagnation-point flow reactor was investigated using a measurement reactor and a numerical model of the reactor. In the experiments, 8 mole% of ammonia in nitrogen was used and the temperature of an electric heater was set in the range $300{\sim}900^{\circ}C$ to heat the quartz surface where the decomposition took place. Gas temperatures and ammonia concentrations in the reactor obtained using in situ Raman spectroscopy were analyzed with the numerical model and it was revealed that, depending on the heater temperature, the temperature of the quartz surface was estimated to be in the range $235{\sim}619^{\circ}C$ and the activation energy of the decomposition on the surface was in the range 10.9~15.8 kcal/mol.

• Environmental Engineering Research
• /
• v.25 no.3
• /
• pp.281-289
• /
• 2020

Environmental fate of ionizable organic pollutants such as perfluoroalkyl acids (PFAAs) are of increasing interest but has not been well understood because of uncertain values for parameters related with atmospheric interphase partitioning behavior. In the present study, not only the values for air-water partition coefficient (K_AW) and dissociation constant (pKa) of PFAAs were induced by adjusting to in situ measurements of air-water distribution coefficient between vapor phase and rainwater but also gas-particle partition coefficients were also estimated using three-phase partitioning model of ionizable organic pollutants, in situ measurements of PFAAs in aerosol and air vapor phase, and obtained parameter values. The pKa values of PFAAs we obtained were close to the minimum values suggested in literature except for perfluorooctane sulfonic acids, and COSMOtherm-modeled K_AW values were assessed to more appropriate among suggested values. When applying parameter values we obtained, it was predicted that air particle-associated fate and transport of PFAAs could be negligible and PFAAs could distribute ubiquitously along the transection from urban to rural region by pH-dependent phase transfer in air. Our study is expected to have some implications in prediction of the environmental redistribution of other ionizable organic compounds.

• Earthquakes and Structures
• /
• v.22 no.4
• /
• pp.345-353
• /
• 2022

The configuration of an open ground floor (pilotis) is a common and very critical irregularity observed in multistory reinforced concrete frame structures. The characteristics and the geometrical formation of the beams of the first story proved to be a critical parameter for the overall seismic behavior of this type of Reinforced Concrete (RC) structures. In this work the combination of open ground floor (pilotis) morphology with very strong perimetrical beams at the level of the first story is studied. The observation of the seismic damages and the in situ measurements of the fundamental period of four buildings with this morphology and Π-shaped plan view are presented herein. Further analytical results of a pilotis type Π-shaped RC structure are also included in the study. From the measurements and the analytical results yield that the open ground floor configuration greatly influences the fundamental period whereas this morphology in combination with strong beams can lead to severe local shear damages in the columns of the ground floor. The structural damage was limited in the columns of the ground floor and yet based on the changes of the in situ measured fundamental period the damaged level is assessed as DI=88%. Furthermore, due to the Π-shape of the plan view the tendency of the parts of the building to move independently strongly influences the distribution of the damages over the ground floor vertical elements.

• Corrosion Science and Technology
• /
• v.14 no.3
• /
• pp.113-119
• /
• 2015

Alloy 82/182 weld metals had been extensively used in joining the components of the PWR primary system. Unfortunately, there have been a number of incidents of cracking caused by PWSCC in Alloy 82/182 welds during the operation of PWR worldwide. To mitigate PWSCC, optimization of water-chemistry conditions, especially dissolved hydrogen (DH) and Zn contents, is considered as the most promising and effective remedial method. In this study, the PWSCC behaviours of Alloy 182 weld were investigated in simulated PWR environments with various DH content. Both in-situ and ex-situ oxide characterizations as well as PWSCC initiation tests were performed. The results showed that PWSCC crack initiation time was shortest in PWR water (DH: 30cc/kg). Also, high stress reduced crack initiation time. Oxide layer showed multi-layered structures consisted of the outer needle-like Ni-rich oxide layer, Fe-rich crystalline oxide, and inner Cr-rich inner oxide layers, which was not altered by the level of applied stress. To analyse the multi-layer structure of oxides, EIS measurement were fitted into an equivalent circuit model. Further analyses including TEM and EDS are underway to verify appropriateness of the equivalent circuit model.

• Tunnel and Underground Space
• /
• v.26 no.4
• /
• pp.304-315
• /
• 2016

In this study, the current horizontal stress characteristics of the Tertiary rock formations in the Pohang Basin are investigated on the basis of the in-situ rock stress measurements at depths from 75 m to 716 m of the 3 test boreholes in the Doumsan area, Pohang. The deep hydraulic fracturing stress measurement results indicated that the horizontal stress components in the test site appear far lower than the average ones by the linear fit for the data set measured from the other domestic sites. But, borehole scanning revealed clearly that lots of small and large scale borehole failures occurred due to the low strength characteristics of the existing rocks. To obtain more accurate and overall information on the horizontal stress direction, the integrated analysis combining the hydraulic fracturing stress measurement and borehole scanning data set were additionally carried out. The analysis results showed that in the upper sedimentary and the lower volcanic rock formation, the dominant orientations of the current maximum horizontal stress components were appeared in the range of $80^{\circ}{\sim}100^{\circ}$ (N80E~N80W) and $120^{\circ}{\sim}140^{\circ}$ (N60W~N40W), respectively. From this study result it was found that the maximum horizontal stress directions have a tendency to rotate in a clockwise direction as the rock formation changes with depth in the test site.

• Transactions on Electrical and Electronic Materials
• /
• v.13 no.2
• /
• pp.78-84
• /
• 2012

An in-situ optical monitoring method for real-time process monitoring of electrochemical copper deposition (CED) is presented. Process variables to be controlled in achieving desired process results are numerous in the CED process, and the importance of the chemical bath conditions cannot be overemphasized for a successful process. Conventional monitoring of the chemical solution for CED relies on the pH value of the solution, electrical voltage level for the reduction of metal cations, and gravity measurement by immersing sensors into a plating bath. We propose a nonintrusive optical monitoring technique using three types of optical sensors such as chromatic sensors and UV/VIS spectroscopy sensors as potential candidates as a feasible optical monitoring method. By monitoring the color of the plating solution in the bath, we revealed that optically acquired information is strongly related to the thickness of the deposited copper on the wafers, and that the chromatic information is inversely proportional to the ratio of $Cu$ (111) and {$Cu$ (111)+$Cu$ (200)}, which can used to measure the quality of the chemical solution for electrochemical copper deposition in advanced interconnection technology.

• Proceedings of the KSME Conference
• /
• 2000.04b
• /
• pp.404-409
• /
• 2000

Growth characteristics of silica particles have been studied experimentally using in situ sampling technique from $H_2/O_2TEOS$ diffusion flame with carefully devised sampling probe. Verification of sampling result was done through new method and effects of flame condition and TEOS flow rate on growth characteristics of silica particles were investigated. By comparing particles sampled by thermophoretic sampling in flame with those by collector sampling after probe, particles do not change before and after probe sampling, which was clearly proved from the fact that the result of TEM image analysis makes good agreement with that of SMPS measurement. As flame temperature increases, the effect of coalescence or sintering becomes important mechanism during growth of silica particles, resulting in canceling the effect of coagulation, which makes mean diameter of silica particles increase slowly. With increase in TEOS flow rate, the number concentration of generated silica particle increases but residence time of particles in flame decreases. As a result, there exists upper limit to which the diameter of silica particle increases under same flame condition.