• 대한금속재료학회지
• /
• 제48권1호
• /
• pp.1-7
• /
• 2010

Experiments have demonstrated that the addition of a moderate amount of V to $Fe_{52}Co_{(20-x)}B_{20}Si_4Nb_4V_x$ amorphous alloy enhances the plasticity of the alloy. In particular, $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy withstood a maximum of 8.3% strain prior to fracture along with a strength exceeding 4.7 GPa. Energy dispersive x-ray spectroscopy conducted on the $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy exhibited evidence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by nm-scale phase separation on the plasticity was investigated in terms of structural disordering and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.329-334
• /
• 2019

Sn-Cu alloy powders were prepared via a simple chemical reduction method for the negative electrode materials in lithiumion batteries. The addition of Cu can suppress the growth of Sn particles during synthetic process. Furthermore, the Cu also acts as a matrix phase against the volume change during cycling. With increasing amount of the Cu, a stable $Cu_6Sn_5$ phase formed in the Sn-Cu alloy and its cycle performance greatly enhanced depending on the Cu content. To promote the generation of the $Cu_6Sn_5$ phase, the synthesis temperature is raised to $60-100^{\circ}C$ from the ambient temperature. The Sn-Cu alloy powders prepared at elevated temperatures showed remarkable cycle performances. The Sn-Cu alloy powder obtained at $60^{\circ}C$ exhibited a significantly high volumetric capacity of over 2,000 mAh/cc at the 50th cycle.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.301-302
• /
• 2006

Machinability and machining mechanism were examined in the case where resin impregnation treatment was conducted to the Mo-Co hardening particle dispersed iron-based sintered alloy. As a result, the force required for machining decreased significantly compared with the case where resin impregnation treatment was not conducted. This effect is considered to be attributable to the embrittlement of cutting chips produced by the minimization of the cut material deformation.

• 열처리공학회지
• /
• 제19권5호
• /
• pp.257-261
• /
• 2006

Scandium(Sc) in Al-Zn-Mg-Cu based Al alloy on precipitation phenomenon was compared to a 7001(Al-7.2%Zn-3.2%Mg-1.8%Cu) Al alloy. GP zone and ${\eta}^{\prime}$ phases were the main strengthening phases at low aging temperature under $100^{\circ}C$, but ${\eta}^{\prime}$ and $Al_3Sc$ phases were the main strengthening phases at high aging temperature above $1600^{\circ}C$ in Sc added 7000(Al-7.7%Zn-2.0%Mg-1.9%Cu-0.1%Zr) Al alloy. With the addition of 0.1%Sc in 7000 Al alloy, the activation energy for the GP zone, ${\eta}^{\prime}$ and ${\eta}$ phase decreased compared to the 7001 Al alloy. This result indicates that the Sc accelerated the precipitation for the GP zone, ${\eta}^{\prime}$ and ${\eta}$ phases in 7000 Al alloy. Al-7.7%Zn-2.0%Mg-1.9%Cu-0.1%Zr-0.1 Sc alloy has higher strength than 7001 Al alloy, which has high strength.

• 한국수소및신에너지학회논문집
• /
• 제8권4호
• /
• pp.161-171
• /
• 1997

$AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

• Nuclear Engineering and Technology
• /
• 제44권5호
• /
• pp.491-500
• /
• 2012

The dissimilar metal joints welded between Ni-based alloy, Alloy 690 and low alloy steel, A533 Gr. B with Alloy 152 filler metal were characterized by using optical microscope, scanning electron microscope, transmission electron microscope, secondary ion mass spectrometry and 3-dimensional atom probe tomography. It was found that in the weld root region, the weld was divided into several regions including unmixed zone in Ni-base alloy, fusion boundary, and heat-affected zone in the low alloy steel. The result of nanostructural and nanochemical analyses in this study showed the non-homogeneous distribution of elements with higher Fe but lower Mn, Ni and Cr in A533 Gr. B compared with Alloy 152, and the precipitation of carbides near the fusion boundary.

• Steel and Composite Structures
• /
• 제42권4호
• /
• pp.553-568
• /
• 2022

This paper explored the viability of utilising titanium alloy bolts in the construction industry through an experimental programme, where a total of sixty-six titanium alloy (Ti/6Al/4V) bolts were tested under axial tension, pure shear and combined tension and shear. In addition, a series of Charpy V-notch specimens machined from titanium alloy bolts, conventional high-strength steel bolts, austenitic and duplex stainless steel bolts were tested for impact toughness comparisons. The obtained experimental results demonstrated that the axial tensile and pure shear capacities of titanium alloy bolts can be reasonably estimated by the current design standards for steel structures (Eurocode 3, AS 4100 and AISC 360). However, under the combined tension and shear loading conditions, significant underestimation by Eurocode 3 and unsafe predictions through AS 4100 and AISC 360 indicate that proper modifications are necessary to facilitate the safe and economic use of titanium alloy bolts. In addition, numerical models were developed to calibrate the fracture parameters of the tested titanium alloy bolts. Furthermore, a design-based selection process of titanium alloy bolts in the structural applications was proposed, in which the ultimate strength, ductility performance and corrosion resistance (including galvanic corrosion) of titanium alloy bolts was mainly considered.

• 동력기계공학회지
• /
• 제18권5호
• /
• pp.122-128
• /
• 2014

Generally, the mechanical components and structures are joined by many welding techniques, and therefore the welded joints are inevitable in the construction of structures. The Alloy 617 was initially developed for high temperature applications above $800^{\circ}C$. It is often considered for use in aircraft and gas turbines, chemical manufacturing components, and power generation structures. Especially, the Alloy 617 is the primary candidate for construction of intermediate heat exchanger (IHX) on a very high temperature reactor (VHTR) system. In the present paper, the low cycle fatigue (LCF) life of Alloy 617 base metal (BM) and the gas tungsten arc welded (GTAWed) weld joints (WJ) are evaluated by using the previous experimental results under strain controlled LCF tests. The LCF tests have been performed at room temperature with total strain ranges of 0.6, 0.9, 1.2 and 1.5%. The LCF lives for the BM and WJ have been evaluated from the Coffin-Manson and strain energy based life methods. For both the BM and WJ, the LCF lives predicted by both Coffin-Manson and strain energy based life methods was found to well coincide with the experimental data.

• 한국분말재료학회지
• /
• 제8권1호
• /
• pp.42-49
• /
• 2001

Ti-50Ni(at%) and Ti-40Ni-10Cu(at%) alloy powders have been fabricated by ball milling method, and their microstructure and phase transformation behavior were investigated by means of scanning electron microscopy/energy dispersive spectrometry, differential scanning calorimetry (DSC), X-ray diffractions and transmission electron microscopy. In order to investigate the effect of ball milling conditions on transformation behavior, ball milling speed and time were varied. Ti-50Ni alloy powders fabricated with the milling speed more than 250 rpm were amorphous, while those done with the milling speed of 100rpm were crystalline. In contrast to Ti-50Ni alloy powders, Ti-40Ni-10Cu alloy powders were crystalline, irrespective of ball milling conditions. DSC peaks corresponding to martensitic transformation were almost discernable in alloy powders fabricated with the milling speed more than 250 rpm, while those were seen clearly in alloy powders fabricated with the milling speed of 100 rpm. This was attributed to the fact that a strain energy introduced during ball milling suppressed martensitic transformation.

• Corrosion Science and Technology
• /
• 제18권1호
• /
• pp.8-15
• /
• 2019

A high-temperature gas-cooled reactor (HTGR) is recognized as the best candidate reactor for next generation nuclear reactors. Helium is used to be the coolant in the core of the HTGR with temperature expected to exceed $900^{\circ}C$ at the core outlet. Several iron- and nickel-based superalloys, including Alloy 800H, Hastelloy X, and Alloy 617, are potential structural materials for intermediate heat exchanger (IHX) in an HTGR. Oxidation behaviors of three selected alloys (Hastelloy X, Alloy 800H, and Alloy 617) were investigated at four different temperatures from $650^{\circ}C$ to $950^{\circ}C$ under helium environments with various concentrations of $O_2$ and $H_2O$. Preliminary results showed that chromium oxide as the primary protective layer was observed on surfaces of the three tested alloys. Based on results of mass gain and SEM analyses, Hastelloy X alloy exhibited the best corrosion resistance in all corrosion tests. Further details on the oxidation mechanism of these alloys are presented in this study.