• 제목/요약/키워드: In situ Mass

검색결과 377건 처리시간 0.029초

In Situ NMR 진단용 원통형 직접 메탄올 연료전지 (Tubular Type Direct Methanol Fuel Cell for in situ NMR Diagnosis)

  • 조한익;엄명섭;한기성;한옥희;하흥용;김수길
    • 전기화학회지
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    • 제12권4호
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    • pp.329-334
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    • 2009
  • 본 연구는 연료전지 운전시 전극 촉매 및 전해질막 내에서 발생하는 연료 및 산화제의 산화/환원 반응 메커니즘, 이동현상, 구성품 열화현상 등을 핵자기 공명 (NMR, Nuclear Magnetic Resonance)을 이용하여 연료전지의 분해나 시료 채취 없이 제자리 (in situ) 분석할 수 있는 진단장치용 연료전지 개발에 관한 것이다. NMR에 사용되는 연료전지는 특수하게 제작된 TCD (Toroid Cavity Detector) 탐침 내부에서 작동하여야 하며, TCD 탐침이 가지는 기하학적 제한 요소들로 인해 일반적인 평판형 연료전지와 달리 원통형으로 제작된다. 이로 인해 반응물의 공급이나 생성물의 제거가 어려우며 누수 현상 및 불균일한 압력 분배가 발생하여 성능이 낮다. 따라서, in situ NMR 분석용 연료전지가 가지는 구조상의 특징인 원통형에 적합한 유로를 설계하고 제작하여 물질 전달 특성을 개선해야 할 필요성이 있다. 본 연구에서는 NMR 장비 내의 자기장에 영향을 미치지 않는 비자성 물질을 이용해 원 통형 공기극 유로를 개발하여, 산소의 공급 및 반응물의 제거를 원활하게 하였다. 또한, 체결 압력을막-전극 접합체에 균일하게 분배하여 누수 및 누액을 차단하였다. 이를 통해, 상온에서 약 $36mW/cm^2$의 우수한 성능을 나타내는 in situ NMR 진단용 직접 메탄올연료전지 시스템을 개발하였다.

물리검층에 의한 파쇄대 인식과 동적 지반정수의 산출 (Application of geophysical well logging to fracture identification and determination of in-situ dynamic elastic constants.)

  • 황세호;이상규
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 1999년도 제2회 학술발표회
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    • pp.156-175
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    • 1999
  • 물리검층은 최근에 토목지반조사분야에 대한 활용성이 증가하고 있다. 이것은 물리 검층이 시추공 내에서 분해능 높은 다양한 원위치 물성정보를 제공할 수 있는 장점이 있기 때문이다. 현재 토목지반조사분야에서 적용되고 있는 것은 주로 암상구분, 파쇄대 인식과 동탄성계수의 산출, 지하수흐름검층 등이다. 이와 관련하여 최근에 활용성이 증가하는 물리검층법에 대한 소개와 지반조사와 관련한 물리검층 사례, 그리고 완전파형음파검층에 의한 탄성파 속도와 암반분류와 관계에 대한 사례를 소개한다.

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난류 용탕 In-Situ 합성법을 위한 스태틱 믹서의 형상에 따른 혼합 효과 (Mixing Effect by the Geometry of Static Mixer with Turbulent In-Situ Mixing Process)

  • 이대성;김효근;하만영;박용호;박익민
    • 대한기계학회논문집B
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    • 제29권12호
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    • pp.1307-1312
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    • 2005
  • Turbulent in-situ mixing process is a new material process technology to get dispersed phase in nanometer size by controlling reaction of liquid/liquid, liquid/solid and liquid/gas, flow and solidification speed simultaneously. In this study mixing, the key technology to this synthesis method will be studied by computational fluid dynamics. For the simulation of mixing of liquid metal, static mixers will be investigated. Two inlets for different liquid metal meet and merge like 'Y' shape tube. The tube has various shapes such as straight and curved. Also, the radius of curve will be varied. The performance of mixer will be evaluated with quantitative analysis with coefficient of variance of mass fraction. Also, detailed plots of intersection will be presented to understand effect of mixer shape on mixing.

Geophysical and mechanical investigation of different environmental effects on a red-bed soft rock dam foundation

  • Liming Zhou;Yujie Li;Fagang Wang;Yang Liu
    • Geomechanics and Engineering
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    • 제34권2호
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    • pp.139-154
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    • 2023
  • Red-bed soft rock is a common stratum and it is necessary to evaluate the mechanical properties and bearing capacity of red-bed soft rock mass affected by different environmental effects. This paper presents a complete procedure for evaluating the bearing capacity of red-bed soft rock by means of geophysical exploration and in-situ rock mechanics tests. Firstly, the thickness of surface loosened rock mass of red-bed soft rock was determined using geophysical prospecting method. Then, three environmental effects, including natural weathering effect, dry-wet cycling effect and concrete sealing effect, were considered. After each effect lasted for three months, in-situ rock mass mechanical tests were conducted. The test results show that the mechanical properties of rock mass considering the sealing effect of concrete were maintained. After considering the natural weathering effect, the mechanical parameters decrease to a certain extent. After considering the effect of dry-wet cycling, the decreases of mechanical parameters are the most significant. The test results confirm that the red-bed soft rock dam foundation rock mass will be significantly affected by various environmental effects. Therefore, combined with the mechanical test results, some useful implementations are proposed for the construction of a red-bed soft rock dam foundation.

단양 석회석 광산터널의 암반 평가 및 안정성 연구 (Study on the stability of tunnel and rock mass classification in Danyang limestone quarry)

  • 신희순
    • 터널과지하공간
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    • 제6권2호
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    • pp.131-143
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    • 1996
  • In-situ survey and laboratory rock test were carried out for rating rock mass around the tunnel that some failures had been occurred in Danyang limestone quarry. For rating rock mass, several methods such as RMR, Q-system, rock strength etc. were applied. The stability analysis on tunnel was evaluated by numerical method FLAC. And The block theory using streographic projection was also applied for stability analysis. The 3-4 major discontinuity sets are distributed in rock mass around tunnel.

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지반정수산정을 위한 경험적 암반평가기법과 상관성 (Empirical Equations for Rock Mass Classifications and Rock Property Evaluations)

  • 신중호;신희순
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.79-86
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    • 2002
  • Rock mass classifications form the back bone of the empirical design approach and are widely employed in rock engineering. In this paper the inter-relations were discussed among RMR, Q-system, RCR, N, M-RMR, RMi, and L-RMR. Several relationships for the assessment of the modulus of deformation of rock mass, Poisson's ratio, uniaxial compressive strength, tensile strength, cohesion and internal friction angle were also analysed and suggested.

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Enhanced Production of Digoxin by Digitoxin Biotransformation Using In Situ Adsorption in Digitalis lanata Cell Cultures

  • Hong, Hee-Jeon;Lee, Jong-Eun;Ahn, Ji-Eun;Kim, Dong-Il
    • Journal of Microbiology and Biotechnology
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    • 제8권5호
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    • pp.478-483
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    • 1998
  • For the enhanced production of a cardiac glycoside, digoxin, using in situ adsorption by biotransformation from digitoxin in plant cell suspension cultures, selection of proper resins was attempted and the culture conditions were optimized. Among various kinds of resins tested, Amberlite XAD-8 was found to be the best for digoxin production in considering adsorption characteristics as well as the effect on cell growth. Adequate time for resin addition was determined to be 36 h from the beginning of biotransformation and the presence of resins should be as short as possible to increase the productivity. In addition, to prevent the cells from direct contact with resin particles, immobilized systems were designed and examined. Immobilization further improved the advantages of in situ adsorption. It was confirmed that the increase of the contact area for mass transfer was an important factor in utilizing an immobilized system to enhance digoxin production.

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자연 산화물 분산 촉진에 의한 실 시간 인 도핑 실리콘의 고품질 에피택셜 저온 성장 (High-Quality Epitaxial Low Temperature Growth of In Situ Phosphorus-Doped Si Films by Promotion Dispersion of Native Oxides)

  • 김홍승;심규환;이승윤;이정용;강진영
    • 한국전기전자재료학회논문지
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    • 제13권2호
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    • pp.125-130
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    • 2000
  • Two step growth of reduced pressure chemical vapor eposition has been successfully developed to achieve in-situ phosphorus-doped silicon epilayers, and the characteristic evolution on their microstructures has been investigated using scanning electron microscopy, transmission electron microscopy, and secondary ion mass spectroscopy. The two step growth, which employs heavily in-situ P doped silicon buffer layer grown at low temperature, proposes crucial advantages in manipulating crystal structures of in-situ phosphorus doped silicon. In particular, our experimental results showed that with annealing of the heavily P doped silicon buffer layers, high-quality epitaxial silicon layers grew on it. the heavily doped phosphorus in buffer layers introduces into native oxide and plays an important role in promoting the dispersion of native oxides. Furthermore, the phosphorus doping concentration remains uniform depth distribution in high quality single crystalline Si films obtained by the two step growth.

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Spatio-Temporal Variation of Cold Water Masses along the Eastern Coast of Korea in 2013 and 2014

  • Han, In-Seong;Park, Myung-Hee;Min, Seung-Hwan;Kim, Ju-Yeon
    • 해양환경안전학회지
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    • 제22권3호
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    • pp.286-295
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    • 2016
  • With the results of observations in 2013 and 2014 including ocean buoys, in-situ investigations and wind data, we examined the spatio-temporal variation of cold water masses along the eastern coast of Korea. Usually, a cold water mass first appears along the northern part of the eastern coast from May to July, and then along the southern part of the eastern coast from late June to mid-August. Cold water masses appear 3~5 times a year and remain for 5~20 days in the southwestern part of the East Sea. A distinctive cold water mass appeared usually in mid-July in this area, the surface temperature of which was below $10^{\circ}C$ in some cases. During the appearance of a cold water mass in the southwestern part of the East Sea, the horizontal temperature gradient was large at the surface and a significant low water temperature below $8^{\circ}C$ appeared at the bottom level. This appearance of cold water masses clearly corresponded to southwesterly winds, which generated coastal upwelling.

감압상태에서의 In-Situ Particle Monitor의 성능특성 (Performance Characteristics of In-Situ Particle Monitors at Sub-Atmospheric Pressure)

  • 배귀남
    • 대한기계학회논문집B
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    • 제22권11호
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    • pp.1564-1570
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    • 1998
  • In-situ particle monitors(ISPMs) are widely used for monitoring contaminant particles in vacuum-based semiconductor manufacturing equipment. In the present research, the performance of a Particle Measuring Systems(PMS) Vaculaz-2 ISPM at subatmospheric pressures has been studied. We created uniform upstream conditions of particle concentration and measured the detection efficiency, the lower detection limit, and the size response of the ISPM using uniform sized methylene blue aerosol particles. The effect of particle size, particle velocity, particle concentration, and system pressure on the detection efficiency was examined. Results show that the detection efficiency of the ISPM decreases with decreasing chamber pressure, and with increasing mass flow rate. The lower detection limit of the ISPM, determined at 50 % of the measured maximum detection efficiency, was found to be about $0.15{\sim}0.2{\mu}m$, which is similar to the minimum detectable size of $0.17{\mu}$ given by the manufacturer.