• 제목/요약/키워드: Ignition catalyst

검색결과 75건 처리시간 0.027초

은을 촉매로 사용하는 과산화수소 추력기 개발 (Development of Hydrogen Peroxide Thruster adopted Silver Catalyst)

  • 이수림;이충원
    • 한국추진공학회지
    • /
    • 제11권4호
    • /
    • pp.67-73
    • /
    • 2007
  • 최근에 친환경 로켓 추진제로 과산화수소가 새로운 관심을 받게 됨에 따라 이에 대한 연구를 수행하기 위해 은을 촉매로 사용한 과산화수소 단일추진제 추력기와 시험설비를 개발하였다. 본 논문에서는 설계 제작된 추력기와 시험설비를 소개하고, 점화시험을 통해 연소실 압력 및 온도, 점화지연 시간, 특성 배기속도 등의 추력기 성능을 분석하였다. 점화시험 결과 정상상태 운전조건에서 95%까지의 높은 특성배기속도 효율을 확인하였다.

DPF 재생을 위한 버너-산화촉매 복합 적용 (Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration)

  • 심성훈;정상현
    • 한국연소학회지
    • /
    • 제15권3호
    • /
    • pp.25-31
    • /
    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

다공성 매질 접근법을 적용한 하이브리드 로켓 N2O 촉매 점화기의 열적 현상 (Thermal Phenomena of an N2O Catalyst Bed for Hybrid Rockets Using a Porous Medium Approach)

  • 유우준;김수종;김진곤;장석필
    • 한국항공우주학회지
    • /
    • 제34권9호
    • /
    • pp.89-96
    • /
    • 2006
  • 본 연구에서는 소형 위성용 하이브리드 로켓 점화장치에 적용되는 N2O 촉매 베드의 유동 및 열적 현상에 대한 이론적인 고찰을 하였다. 허니콤 형상을 가지는 촉매 베드 내의 열적 현상을 분석하기 위해서 다공성 매질 접근법을 사용하였다. 유동장은 Brinkman- extended Darcy 모델을 사용하였고, 온도장은 One-equation 모델을 사용하여 촉매 베드 내에서 유동장 및 온도장에 대한 해석해들을 구하였다. 다공성 매질 접근법을 적용한 모델의 해석해와 기존 실험결과를 비교하여 본 모델의 정확성을 검증하였다. 해석해에 근거하여 N2O 촉매 베드에 영향을 미치는 중요한 변수들이 촉매 베드의 기공률, 유효 체적비, 촉매 베드와 기공의 직경비, 공급열, 그리고 펌핑파워임을 확인하였으며 촉매 베드 내에서의 열적현상에 대한 중요 변수들의 효과를 연구하였다.

밀리미터 스케일 촉매 연소기에서의 수소-공기 예혼합 가스의 촉매 연소 특성 (Catalytic Combustion Characteristics of Hydrogen-Air Premixture in a Millimeter Scale Monolith Coated with Platinum)

  • 최원영;권세진
    • 한국연소학회지
    • /
    • 제10권1호
    • /
    • pp.20-26
    • /
    • 2005
  • In the present study, catalytic combustion of hydrogen-air premixture in a millimeter scale monolith coated with Pt catalyst was investigated. As the combustor size decreases, the heat loss increases in proportion with the inverse of the scale of combustion chamber and combustion efficiency decreases in a conventional type of combustor. Combustion reaction assisted by catalyst can reduce the heat loss by decreasing the reaction temperature at which catalytic conversion takes place. Another advantage of catalytic combustion is that ignition is not required. Platinum was coated by incipient wetness method on a millimeter scale monolith with cell size of $1{\times}1mm$. Using this monolith as the core of the reaction chamber, temperatures were recorded at various locations along the flow direction. Burnt gas was passed to a gas chromatography system to measure the hydrogen content after the reaction. The measurements were made at various volume flow rate of the fuel-air premixture. The gas chromatography results showed the reaction was complete at all the test conditions and the reacting species penetrated the laminar boundary layer at the honeycomb and made contact with the catalyst coated surface. At all the measuring locations, the record showed monotonous increase of temperature during the measurement duration. And the temperature profile showed that the peak temperature is reached at the point nearest to the gas inlet and decreasing temperature along the flow direction.

  • PDF

용액연소합성법을 이용한 LaFeO3 분말 합성 및 탄소 연소 특성 (Solution Combustion Synthesis of LaFeO3 Powders and Their Carbon Ignition Property)

  • 강대식;이태근;황연;배광현;조성백
    • 한국재료학회지
    • /
    • 제17권7호
    • /
    • pp.382-385
    • /
    • 2007
  • [ $LaFeO_3$ ] powders were prepared as the oxidation catalyst materials to reduce the emission of particulate matters from diesel engine and their catalytic effects on the oxidation of carbon were investigated. Solution combustion method was employed for the powder synthesis, which uses highly exothermic and selfsustaining reactions. In this study $LaFeO_3$ powders were synthesized at $400^{\circ}C$ as varying the ratio ($\Phi$) of fuel (citric acid) and oxidizer (metal nitrate), and their phase and carbon ignition property were examined. As $\Phi$ decreases, the crystallinity of synthesized $LaFeO_3$ powders enhanced. By calcining at $700^{\circ}C$, all the powders synthesized at various $\Phi$ fully crystallized. The calcined $LaFeO_3$ powders showed carbon ignition temperature as low as $501{\sim}530^{\circ}C$, which implied the decrease of the ignition temperature by $120{\sim}150^{\circ}C$.

하이브리드 로켓 자동점화를 위한 다단촉매점화기에 관한 연구 (A Study on Multi-Stage Catalytic Ignitor for Hybrid Rocket Auto Ignition)

  • 최우주;김진철;권민찬;유영준;김태규
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
    • /
    • pp.117-119
    • /
    • 2017
  • 본 논문에서는 하이브리드 로켓의 자동점화를 위한 다단 방식의 촉매점화시스템에 관한 연구를 수행하였다. 다단 촉매점화기의 열분해 성능을 평가하기 위해 1단 점화기에 촉매를 충전하여 예열 후, 1단 점화기와 2단 점화기에 각각 저유량과 고유량을 공급하여 실험을 진행하였다. 이때 저유량의 $N_2O$가스를 분해하여 생성된 고온의 가스로 고유량의 $N_2O$가스를 분해하였다. 실험 결과 기존 점화기보다 점화 시간이 감소되었다. 또한 1단 점화기에서 분해된 가스를 이용하여 2단 점화기에 공급된 고유량 $N_2O$가스의 분해 가능성을 확인하였다.

  • PDF

BTX(Benzene, Toluene, Xylenes)의 자연발화온도와 발화지연시간의 측정 (Measurements of Autoigniton Temperature(AIT) and Time Lag of BTX(Benzene, Toluene, Xylenes))

  • 하동명
    • 한국안전학회지
    • /
    • 제21권3호
    • /
    • pp.45-52
    • /
    • 2006
  • The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

고압축비 전기점화 천연가스 발전용 엔진에서 앳킨슨 사이클 적용을 통한 열효율 향상 (Improvement of Thermal Efficiency using Atkinson Cycle in a High-Compression Ratio, Spark-Ignition, Natural Gas Engine for Power Generation)

  • 이준순;박현욱;오승묵;김창업;이용규;강건용
    • 한국분무공학회지
    • /
    • 제28권2호
    • /
    • pp.55-61
    • /
    • 2023
  • Natural gas is a high-octane fuel that is effective in controlling knocking combustion. In addition, as a low-carbon fuel with a high hydrogen-carbon ratio, it emits less carbon dioxide and almost no particulate matter compared to conventional fossil fuels. Stoichiometric combustion engines equipped with a three-way catalyst are useful in various fields such as transportation and power generation because of their excellent exhaust emission reduction performance. However, stoichiometric combustion engines have a disadvantage of lower thermal efficiency compared to lean combustion engines. In this study, a combination of high compression ratio and Atkinson cycle was implemented in a 11 liter, 6-cylinder, spark-ignition engine to improve the thermal efficiency of the stoichiometric engine. As a result, pumping and friction losses were reduced and the operating range was extended with optimized Atkinson camshaft. Based on the exhaust gas limit temperature of 730℃, the maximum load and thermal efficiency were improved to BMEP 0.66 MPa and BTE 35.7% respectively.

2차 공기 분사에 의한 스파크 점화 가솔린 엔진의 배기 Hydrocarbon 저감에 관한 실험적 연구 (An Experimental Study for Reducing the Exhaust Hydrocarbon Emission at SI Engine Using Timed Secondary Air Injection)

  • 심현성;김세준;정석호
    • 한국자동차공학회논문집
    • /
    • 제7권7호
    • /
    • pp.104-112
    • /
    • 1999
  • An experimental study for reducing the exhaust hydrocarbon emission at spark ignition engine using timed secondary air injection is carried out . In this study, secondary air injection timings and durations are controlled to decrease the hydrocarbon emission and to increase exhaust gas temperature at cold and warm-up engine conditions. The hydrocarbon reduction rate and exhaust gas temperature are compared between timed secondary air injection and continuous air injection. The optimum secondary air injection timing for reducing the hydrocarbon emission is at the exhaust valve open timing. At some engine conditions , the hydrocarbon emissions are decreased to 10% of engine raw values and exhaust gas temperatures increase by 20$0^{\circ}C$ with times secondary air injection . Timed secondary air injection has more hydrocarbon reduction rate that continuous secondary air injection except some engine conditions.

  • PDF

모노리스를 이용한 과산화수소 단일추진제 추력기 개발 (Development of $H_2O_2$ Monopropellant Thruster with Monolith Support)

  • 안성용;진정근;권세진
    • 한국추진공학회지
    • /
    • 제11권1호
    • /
    • pp.18-26
    • /
    • 2007
  • 마이크로위성의 임무능력 향상을 위한 과산화수소 단일추진제 마이크로 추력기를 개발하였다. 단일 추진제 추력기의 핵심 요소인 촉매를 모노리스 지지체에 담지/제작하였으며 특성속도 효율, 반응지연 시간 측정을 통해 추력기 성능평가를 수행하였다. 실험결과 정상상태 설계 유량에서 96.0%의 높은 특성속도 효율을 확인하였다.