• Korean Journal of Hazardous Materials
• /
• v.6 no.2
• /
• pp.23-29
• /
• 2018

The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.19 no.11
• /
• pp.58-63
• /
• 2020

The fuel injection amount and timing along with the ignition timing for the gasoline engine of a racing car were adjusted using an electronic control unit (ECU), and the engine performance was evaluated through an acceleration test. The fuel map for the fuel injection amount and ignition map for the ignition timing were derived. Using the transient throttle control, the air-fuel ratio could be maintained at a constant value even in the case of a sudden throttle operation. In the flat shift, ignition blocking was more effective than fuel blocking. In a 75 m acceleration test, the required duration without and with ECU control was 4.47 s and 3.99 s, respectively. Notably, the acceleration could be improved by approximately 10.7% when the ECU control was implemented.

• Journal of the Korean Society of Visualization
• /
• v.14 no.3
• /
• pp.51-58
• /
• 2016

New concept spark plug was developed to study its influence on the combustion characteristics of SI engine. It has pre-ignition chamber at the lower end of spark plug and flame hole, in which fresh mixture gas can be put in through the flame hole without any fuel supply system. This spark plug was tested in a single cylinder engine dynamometer for different air fuel ratio to measure the fuel consumption rate, emission gases, and MBT timing. And constant volume combustion chamber was made to understand flame characteristics of spark plug. New spark plug induced fast burn compared to the conventional spark plug and its effects were increased in lean air fuel ratio. Pre-ignition chamber spark plug with 5 holes which had adjusted size was more stable and effective in combustion performance than pre-ignition chamber spark plug with 1 hole. And its effects showed larger differences in lean air fuel ratio than stoichiometric condition. Flame kernel and flame growth process of conventional spark plug and pre-ignition chamber spark plug studied by flame visualization of schlieren method.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.04a
• /
• pp.91-94
• /
• 2007

The fabrication and firing test of the ignition system for a micro solid propellant thruster are described in the present paper. Pt igniter coil was patterned on the glass membrane that was fabricated by the wet etching process. The thickness of Pt layer was $2000{\AA}$ and the width of igniter pattern was $40{\mu}m$. The thickness and diameter of glass membrane were $15{\mu}m$ and 1 mm, respectively. Ignition test was performed. Successful ignition of HTPB/AP propellant was obtained with an ignition delay of 1.6 s at an input voltage of 12 V. The ignition energy was estimated to be 1.4 J.

• Journal of the Korean Society of Safety
• /
• v.33 no.4
• /
• pp.8-14
• /
• 2018

In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

• International Journal of Automotive Technology
• /
• v.8 no.2
• /
• pp.137-147
• /
• 2007

Homogenous Charge Compression Ignition (HCCI) combustion systems can be broadly divided for the process applied to 4-stroke and 2-stroke engines. The former process is often referred to as simply HCCI combustion and the latter process as Active Thermo-Atmosphere Combustion (ATAC). The region of stable engine operation tends to differ greatly between the two processes. In this study, it was shown that the HCCI combustion process of a 4-stroke engine, characterized by the occurrence of autoignition under a high compression ratio, a lean mixture and wide open throttle operation, could be simulated by operating a 2-stroke engine at a higher compression ratio. On that basis, a comparison was made of the combustion characteristics of high-compression-ratio HCCI combustion and ATAC, characterized as autoignited combustion in the presence of a large quantity of residual gas at a low compression ratio and part throttle. The results showed that one major difference between these two combustion processes was their different degrees of susceptibility to the occurrence of cool flame reactions. Compared with high-compression-ratio HCCI combustion, the ignition timing of ATAC tended not to change in relation to different fuel octane numbers. Furthermore, when internal EGR was applied to high-compression-ratio HCCI combustion, it resulted in combustion characteristics resembling ATAC. Specifically, as the internal EGR rate was increased, the ignition timing showed less change in relation to changes in the octane number and the region of stable engine operation also approached that of ATAC.

• Journal of the Korean Society of Safety
• /
• v.7 no.4
• /
• pp.105-114
• /
• 1992

This paper presents an study on the knowledge based system for diagnosing the fire causes using the Fuzzy Possibility Measure( FPM ) about the electric-fire ignition. The Ignition values needed for causes diagnosis is computed as FPM for electric-fire ignition based on the internal scale technique that assigns numerically the characteristic difference of facts to the-tin-ear scale. For the convinience of inference, ignition sources are classified into seven types : short, ground fault, leakge of electricity, overcurrent, cord junction overheating, bad Insulation and spark. The system for causes diagnosis of electric-fire is composed of Knowledge Acquisition System, Inference Engine and Man-Machine Interface, The diagnosis system is wrritten in an artificial intelligence langusge “PROLOG” which uses depth-first search and backward chaining schemes in reasoning process.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.19 no.8
• /
• pp.1989-1998
• /
• 1995

Characteristics of the flame propagation for normal and abnormal combustion in hydrogen premixture in a cylindrical constant-volume combustion chamber are studied numerically. A detailed hydrogen oxidation kinetic mechanism, mixture transport properties and a model describing spark ignition process are used. The calculated pressure-time history of the stable deflagration wave propagation agrees well with the experiment. The ignition of the premixture in the unburned gas, initiated by the hot spot, causes a transition from deflagration to detonation under some initial temperature and pressure. Under the initial conditions with high temperature and pressure, excessive ignition energy initiates a strong blast wave and a detonation wave that follows. The chemical reaction in the detonation wave is much more vigorous than that in the deflagration wave and the peak pressure in the detonation wave is much higher than the equilibrium value.

• 한국연소학회:학술대회논문집
• /
• 2015.12a
• /
• pp.215-218
• /
• 2015

Simultaneous laser ignition and spectroscopy is a scheme that enables rapid determination of the local equivalence ratio and condensed fuel concentration during a reaction in a two phase spray flame. We have conducted quantitative analysis of the LIBS signals according to the equivalence ratio, droplet size, droplet number density and droplet concentration as a part of novel feedback control strategy proposed for flame ignition and stabilization with simultaneous in situ combustion flow diagnostics. This is a desirable scheme since such real time information onboard an engine for instance can be constantly monitored and fed back to the control loop to enhance the mixing process and minimize emissions of unwanted species and potential combustion instability.

• International Journal of Automotive Technology
• /
• v.7 no.3
• /
• pp.251-259
• /
• 2006

For practical application on the HCCI engine, the solution of subjects, such as control of auto-ignition timing and avoidance of knocking, is indispensable. This study focused on the technique of controlling HCCI combustion appropriately, changing the mixture ratio of two kinds of fuel. Methane and DME/n-Butane were selected as fuels. The influences, which the mixing ratio of two fuels does to ignition timing, ignition temperature, rate of heat release and oxidation reaction process, were investigated by experiment with 4-stroke HCCI engine and numerical calculation with elementary reactions.