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Profiling of Volatile Components Using Gas Chromatography-Mass Spectrometry in Commercial Pine Needle (Pinus densiflora S. and Z.) Powder

  • Kim, Joo-Shin;Chung, Hau-Yin
    • Preventive Nutrition and Food Science
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    • v.16 no.1
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    • pp.45-54
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    • 2011
  • Volatile components in commercial pine needle (Pinus densiflora S. and Z.) powder were extracted using simultaneous steam distillation and a solvent extraction (SDE) apparatus, and were analyzed by gas chromatography-mass spectrometry (GC-MS). A total of 230 compounds divided into 13 groups were identified, which included alcohols (42), ketones (39), aldehydes (32), terpenes (30), alkenes (17), esters (14), furans (14), benzenes (10), alkanes (8), napthalenes (7), acids (6), miscellaneous compounds (6), and phenols (5). Among the 230 compounds identified, 96 compounds were positively confirmed and quantified, and the rest of the compounds were tentatively identified. The major volatile components identified at relatively high levels were dodecanoic acid, hexadecanoic acid, hexanal, benzaldehyde, (Z)-3-hexen-1-ol, 1-penten-3-one, limonene, and $\beta$-caryophyllene oxide. Among the groups, terpenes accounted for 60.18% of the total concentration of all the volatile components. Some volatile components might account for the unique aroma and the biological activity of the sample.

Wolsong 3&4 Steam Generator Tube Inspection (월성 3,4호기 증기발생기 전열관 검사)

  • Jang, Kyoung-Sik;Kwon, Dong-Ki;Choi, Jin-Hyuk;Son, Tai-Bong
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.859-866
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    • 2001
  • During the Pre-service Inspection for Wolsong Unit 3&4 in 1997/1998 respectively, 17 Distorted Roll Transition indications(over expanded beyond tubesheet secondary face) were identified at the Unit 4 (S/G B, D). Six(6) tubes out of these tubes were plugged in 1998. However the first Periodic Inspection identified additional 110 indications in 1999 and 2000. The additionally identified 110 indication call, not reported at the Pre-service Inspection, are; 2 Not-Finally-Expanded-Tubes and 108 Distorted Roll Transition tubes. Design limit of each Steam Generator tube Plugging is 6.4%. Plugging was performed by the Steam Generator manufacturer under the warranty. When Distorted Roll Transition indications were first identified on the Unit 4 in 1998 the degree of Over-expansion was measured using an inner dial-gage to make the disposition of Nonconformance report. 2 Not-Finally-Expanded-Tubes were plugged and 10 tubes out of 108 Distorted Roll Transition Tubes were also plugged as a preventive measure.

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AN INTERNAL STRUCTURE OF INFORMATION SYSTEMS FAILURE; What really constitutes IS failure\ulcorner

  • Kim, Jong-Uk
    • Journal of Korea Society of Industrial Information Systems
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    • v.5 no.4
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    • pp.1-15
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    • 2000
  • Information systems (IS) failures still continue and are prevalent everywhere. When considering an enormous amount of budget currently invested on IS technology in many organizations, these continuing failures can be critical culprits to failures of the organizations themselves. However, the meaning and definition of IS failures are not unified among IS researchers as well as IS practitioners although there have been a lot of conceptual research regarding the concept of IS failures. Previous empirical studies are not enough yet and thus we anticipate further empirical studies to be performed which will validate previous conceptual research. In this regards, by analyzing IS practitioners perception toward IS failures in a more detailed manner, this research extends conceptual and empirical research in the past which previously identified the structure of information systems (IS) failures. Further, this current study identified the interrelationships among the categories. The data was analyzed using a multidimensional scaling program and fourteen categories of problems were identified as to constitute the IS failure structure. It was found that about a half of categories identified were related to technical failures such as network and system infrastructure, costs, data/information, and program errors. The other remaining categories were related with organizational or social problems such as business success, human resources, relationships, communication, and user skills.

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Mode identifiability of a cable-stayed bridge using modal contribution index

  • Huang, Tian-Li;Chen, Hua-Peng
    • Smart Structures and Systems
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    • v.20 no.2
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    • pp.115-126
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    • 2017
  • The modal identification of large civil structures such as bridges under the ambient vibrational conditions has been widely investigated during the past decade. Many operational modal analysis methods have been proposed and successfully used for identifying the dynamic characteristics of the constructed bridges in service. However, there is very limited research available on reliable criteria for the robustness of these identified modal parameters of the bridge structures. In this study, two time-domain operational modal analysis methods, the data-driven stochastic subspace identification (SSI-DATA) method and the covariance-driven stochastic subspace identification (SSI-COV) method, are employed to identify the modal parameters from field recorded ambient acceleration data. On the basis of the SSI-DATA method, the modal contribution indexes of all identified modes to the measured acceleration data are computed by using the Kalman filter, and their applicability to evaluate the robustness of identified modes is also investigated. Here, the benchmark problem, developed by Hong Kong Polytechnic University with field acceleration measurements under different excitation conditions of a cable-stayed bridge, is adopted to show the effectiveness of the proposed method. The results from the benchmark study show that the robustness of identified modes can be judged by using their modal contributions to the measured vibration data. A critical value of modal contribution index of 2% for a reliable identifiability of modal parameters is roughly suggested for the benchmark problem.

Relationship Between Image Quality and Changes in Spation Resolution for the Gamma Camera (감마카메라의 공간분해능 변화와 화질과의 관계)

  • Lee, Man-Koo;Park, Soung-Ock
    • Journal of radiological science and technology
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    • v.25 no.1
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    • pp.77-81
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    • 2002
  • The purpose of this study is to examine quantitatively the relationship between visual image quality and degradation In spatial resolution for a gamma camera by the increase in distance from collimator. The relationship between the portion(p) of images identified the difference of image quality and the difference(${\Delta}FWHM$) in FWHM between paired images was showed in a sigmoid curve. Using Dendy's method, minimum level to be correctly identified the difference of Image duality on three out of four occasion(p=0.75) was corresponded to 0.4 mm in ${\Delta}FWHM$. Using fuzzy theory, the level to be identified the difference of image quality was examined under various conditions. The truth-value of fuzzy sets-degraded or slightly degraded and not-degraded in image quality between palled Images-was gained the peak at 0.5 mm of ${\Delta}FWHM$. It was founded that changes of $0.4{\sim}0.5\;mm$ in FWHM-corresponding about 2 cm distance from collimator could be sufficiently identified in the difference of image quality.

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Full-scale measurements of wind effects and modal parameter identification of Yingxian wooden tower

  • Chen, Bo;Yang, Qingshan;Wang, Ke;Wang, Linan
    • Wind and Structures
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    • v.17 no.6
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    • pp.609-627
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    • 2013
  • The Yingxian wooden tower in China is currently the tallest wooden tower in the world. It was built in 1056 AD and is 65.86 m high. Field measurements of wind speed and wind-induced response of this tower are conducted. The wind characteristics, including the average wind speed, wind direction, turbulence intensity, gust factor, turbulence integral length scale and velocity spectrum are investigated. The power spectral density and the root-mean-square wind-induced acceleration are analyzed. The structural modal parameters of this tower are identified with two different methods, including the Empirical Mode Decomposition (EMD) combined with the Random Decrement Technique (RDT) and Hilbert transform technique, and the stochastic subspace identification (SSI) method. Results show that strong wind is coming predominantly from the West-South of the tower which is in the same direction as the inclination of the structure. The Von Karman spectrum can describe the spectrum of wind speed well. Wind-induced torsional vibration obviously occurs in this tower. The natural frequencies identified by EMD, RDT and Hilbert Transform are close to those identified by SSI method, but there is obvious difference between the identified damping ratios for the first two modes.

System identification of the suspension tower of Runyang Bridge based on ambient vibration tests

  • Li, Zhijun;Feng, Dongming;Feng, Maria Q.;Xu, Xiuli
    • Smart Structures and Systems
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    • v.19 no.5
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    • pp.523-538
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    • 2017
  • A series of field vibration tests are conducted on the Runyang Suspension Bridge during both the construction and operational stages. The purpose of this study is devoted to the analysis of the dynamic characteristics of the suspension tower. After the tower was erected, an array of accelerometers was deployed to study the evolution of its modal parameters during the construction process. Dynamic tests were first performed under the freestanding tower condition and then under the tower-cable condition after the superstructure was installed. Based on the identified modal parameters, the effect of the pile-soil-structure interaction on dynamic characteristics of the suspension tower is investigated. Moreover, the stiffness of the pile foundation is successfully identified using a probabilistic finite model updating method. Furthermore, challenges of identifying the dynamic properties of the tower from the coupled responses of the tower-cable system are discussed in detail. It's found that compared with the identified results from the freestanding tower, the longitudinal and torsional natural frequencies of the tower in the tower-cable system have changed significantly, while the lateral mode frequencies change slightly. The identified modal results from measurements by the structural health monitoring system further confirmed that the vibrations of the bridge subsystems (i.e., the tower, the suspended deck and the main cable) are strongly coupled with one another.

Molecular Biological Species Identification of Imported Groupers(Epinephelus moara ♀×E. lanceolatus ♂) (수입산 바리과(Family Serranidae) 잡종 어류(Epinephelus moara ♀×E. lanceolatus ♂)의 분자생물학적 판별)

  • Kim, Yong Hwi;Park, Jong Yeon;Kim, Jae Hoon;Bang, In-Chul
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.4
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    • pp.566-571
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    • 2020
  • To classify a presumed hybrid of imported grouper species acquired from the National Fishery Products Quality Management Service, maternal and paternal lines were identified based on partial sequencing of mitochondrial cytochrome c oxidase 1 (co1) and nuclear recombination activation gene 1 (rag1) genes. The matrilineal species was identified as Epinephleus moara by a partial (760 bp) co1 sequence. Ambiguous sequences with base pairs belonging to E. moara or E. lanceolatus were found in a total of 15 different base pairs in the partial 1,159 bp of the rag1 gene, and the patrilineal species was found to be E. lanceolatus. Therefore, all of the groupers examined in the study were identified to be hybrids of E. moara and E. lanceolatus. In addition, a fast and convenient method using random amplification of polymorphic DNA (RAPD) was established for hybrid discrimination. Hybrids between E. moara ♀ and E. lanceolatus ♂ were identified through specific bands of 387 bp and 433 bp in PRIMER 6.

Isolation and Identification of Bioactive Organosulfur Phytochemicals from Solvent Extract of Broccoli (브로콜리 용매추출물의 Bioactive Organosulfur 화합물의 분리 및 동정)

  • 석대은;김진희;김미리
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.3
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    • pp.315-319
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    • 2003
  • Bioactive organosulfur phytochemicals were isolated from fresh broccoli using methlylene chloride as an extract solvent and identified by GC/MSD analyses. Major organosulfur phytochemicals of broccoli extract were found to be isothiocyanates, which constitute 40.42% of total phytochemicals. The isothiocyanates from broccoli extract were identified to be 3-butenyl, 4-methyl thiobutyl, 4-methylthio-3-butenyl, 5-methylthiopentyl, 2-phenylethyl, 3-methyl sulfinyl propyl, and 4-methylsulfinylbutyl isothiocyanates, of which major isothio cyanates were 3 butenyl isothiocyanate and 4-methylsulfinylbutyl isothiocyanate, constituting about 38.55% of total isothiocyanates present in the solvent extract. Also, nitrites, corresponding to products from enzymatic hydrolysis of glucosinolates were identified as 4-methylthiobutyl, 5-methyl thiopentyl, 2-phenylethyl and 4-methylsulfinylbutyl nitrile. In addition, three sulfides were identified as dimethyl disulfide, dimethyl trisulfide and dimethyl tetrasulfide.

Analysis of Volatiles in Sesame Oil Collected by Simultaneous Distillation/Extraction(SDE) and Dynamic Headspace Sampling (DHS) (연속수증기증류법(SDE)과 동적헤드스페이스법(DHS)에 의한 참기름 중의 향기성분의 분석)

  • Ha, Jaeho
    • Analytical Science and Technology
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    • v.9 no.4
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    • pp.399-405
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    • 1996
  • The flavor compounds of the oil from roasted sesame seeds were collected by simultaneous steam distillation/ extraction(SDE) and dynamic headspace sampling(DHS) and were analyzed using a gas chromatograph equipped with a flame ionization detector and connected into a mass spectrometer. Among the flavor compounds collected by the SDE method, 46 compounds were identified. They consisted of 6 alcohols, 6 aldehydes, 5 ketones or acids, 4 furans or phenols, 12 pyrazines, 4 pyridines or thiazoles, and others. Thirty six compounds were identified by DHS and many of them were the same as those identified by the SDE method. However, some compounds such as 1-hexanol, pentanal, and dimethylsulfide were identified only by the DHS method.

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