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Effect of Anodizing Current Density on Anti-Corrosion Characteristics for Al2O3 Oxide Film (Al2O3 산화 피막의 내식성에 미치는 양극산화 전류밀도의 영향)

  • Lee, Seung-Jun;Jang, Seok-Gi;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.153-153
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    • 2016
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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Case of Developing Analysis Model for Recoil System for Automatic Gun (자동포용 주퇴복좌장치의 해석모델 개발 사례)

  • Noh, Dae-Kyung;Kang, Young-Ky;Ji, Jae-Do;Park, Jin-Saeng;Jang, Joo-Sup
    • Journal of the Korea Society for Simulation
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    • v.24 no.4
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    • pp.35-41
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    • 2015
  • Recoil system for 40mm automatic gun is a device developed to absorb the shock of explosion. It is impossible to conduct pinpoint strike due to recoil if very high explosive shock, which is generated when an automatic gun fires shells, can't be absorbed. This study covers development and verification of analysis model for recoil system by utilizing a multi-domain software. The research process is as in the following. First, an analysis model is developed to verify damping characteristics through understanding of design intention. Second, environment which is identical to a field test is set up on analysis tool after putting explosive force that is measured through the test into the analysis model. Finally, the analysis model for recoil system using the multi-domain software is verified if it has effectiveness with a comparison between internal pressure of the recoil system along with displacement of gun barrel and the field test result.

Surface-Tension Effects on the Flow Caused by a Two-Dimensional Pulsating Source Moving with a Constant Speed beneath the Free Surface (전진하며 동요하는 2차원 특이점에 의하여 발생되는 자유표면파에 미치는 표면장력의 영향)

  • Hang-S.,Choi;Jae-S.,Choi
    • Bulletin of the Society of Naval Architects of Korea
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    • v.27 no.1
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    • pp.57-62
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    • 1990
  • This paper deals with the flow caused by a two-dimensional pulsating source, which moves with a constant horizontal speed beneath the free surface. The analysis is based on lincar potential theory including surface tension effects. In the case of subcritical reduced frequencies $\tau<1/4(\tau=U_{\omega}/g$, U=constant speed, $\omega$=circular frequency, g=gravitational acceleration), six wave components arc found. Two of them are largely affected by surface tension, which propagate ahead of the source in the direction of and opposite to the steady translation, respectively. The rest are almost identical with those found by Haskind(1954), i.e. for which the surface tension effect is negligible. For low oscillation frequencies, the resonant frequency still exists at $\tau$ only slightly greater than 1/4. For oscillation frequencies greater than $\nu(={\omega}^2/g)>20$, the surface tension effect is so significant that it disperses generated waves and consequently the singular phenomenon is removed. However, in addition to the gravity breaking, capillary breakings occur when the translation speed coincides with the minimum capillary celerity.

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DEVELOPMENT AND TESTS OF THE ALGORITHM FOR DIRECT DATA TRANSMISSION BETWEEN RVDB AND HUGE CAPACITY DATA SERVER (RVDB와 대용량 서버 간의 직접 데이터 전송 알고리즘 개발과 시험에 관한 연구)

  • Roh, Duk-Gyoo;Oh, Se-Jin;Yeom, Jae-Hwan;Jung, Dong-Kyu;Oh, Chung-Sik;Yun, Young-Joo;Kim, Hyo-Ryoung;Ozeki, Kensuke
    • Publications of The Korean Astronomical Society
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    • v.29 no.3
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    • pp.45-52
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    • 2014
  • This paper describes the development of algorithm for direct data transmission between Raw VLBI Data Buffer (RVDB) and Huge Capacity Data Server (HCDS) operated in Korea-Japan Correlation Center (KJCC). The transmitted data is the VLBI observation data, which is recorded at each radio telescope site, and the data transmitting rate is varying from 1 Gbps, in usual case, upto 8 Gbps. The developed algorithm for data transmission enables the direct data transmission between RVDB and HCDS through 10 Gbps optical network using VLBI Data Interchange Format (VDIF). Proposed method adopts the conventional UDP/IP protocol, but in order to prevent the loss of data during data transmission, the packet error monitoring and data re-transmission functions are newly designed. The VDIF specification and VDIFCP (VDIF Control Protocol) are used for the direct data transmission between RVDB and HCDS. To validate the developed algorithm for data transmission, we conducted the data transmission from RVDB to HCDS, and compared to the transmitted data with the original data bit by bit. We confirmed that the transmitted data is identical to the original data without any loss and it has been recovered well even if there were some packet losses.

The Carboxyl Terminal Amino Acid Residues Glutamine276-Threonine277 Are Important for Actin Affinity of the Unacetylated Smooth ${\alpha}$-Tropomyosin

  • Cho, Young-Joon
    • BMB Reports
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    • v.33 no.6
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    • pp.531-536
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    • 2000
  • Tropomyosin (TM) is an important actin binding protein involved in regulation of muscle contraction. Unacetylated striated tropomyosin failed to bind to actin whereas unacetylated smooth tropomyosin bound well to actin. It has been demonstrated that high actin affinity of unacetylated ${\alpha}-tropomyosin$ was ascribed to the carboxyl terminal amino acid residues. In order to define the role of the carboxyl terminal residues of tropomyosin molecule on actin binding, two mutant tropomyosins were constructed. TM11 is identical to the striated tropomyosin except that the carboxyl terminal last three amino acids was replaced with $^{282}NNM^{284}$ whereas in TM14 $^{276}HA^{277}$ was substituted with smooth specific $^{276}QT^{277}$. TM11 and TM14 were overproduced in Escherichia coli and analyzed for actin affinity. The apparent binding constants (Kapp) of unacetylated tropomyosins were $2.2{\times}10^6M^{-1}$ for sm9, $1.03{\times}10^6M^{-1}$ for TM14, $0.19{\times}10^6M^{-1}$ for TM11, $>0.1{\times}10^6M^{-1}$ for striated, respectively. This result indicated that higher actin affinity of the unacetylated smooth tropomyosin was primarily attributed to the presence of QT residues in the smooth sequence. In case of the Ala-Ser (AS) dipeptide extension of the amino terminus of tropomyosin, Kapp were $21.1{\times}10^6M^{-1}$ for AS-sm9, $8.0{\times}10^6M^{-1}$ for AS-11, $4.7{\times}10^6M^{-1}$ for AS-14, $3.8{\times}10^6M^{-1}$ for AS-striated. AS-TM11 showed considerably higher actin affinity than AS-TM14, implying that interaction of Ala-Ser of the amino terminus with the carboxyl terminal residues. Since Kapp of AS-TM11 was significantly lower than that of AS-sm9, the presence of QT might be required for restoration of high actin affinity of the smooth ${\alpha}-tropomyosin$. These results suggested that the carboxyl terminal amino acid residues Glutamine275-Threonine276 are important for actin affinity of the recombinant smooth ${\alpha}-tropomyosin$, particularly of unacetylated smooth ${\alpha}-tropomyosin$.

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Development of Hybrid/Dual Swirl Jet Combustor for a MGT (Part II: Numerical Study on Isothermal Flow) (마이크로 가스터빈용 하이브리드/이중 선회제트 연소기 개발 (Part II: 비반응 유동에 관한 수치해석))

  • Mun, Sun-Yeo;Hwang, Cheol-Hong;Lee, Kee-Man
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.70-79
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    • 2013
  • The isothermal flow structure and mixing characteristics of a hybrid/dual swirl jet combustor for micro-gas turbine (MGT) were numerically investigated. Location of pilot burner, swirl angle and direction were varied as main parameters with the identical thermal load. As a result, the variations in location of pilot nozzle, swirl angle and direction resulted in the significant change in turbulent flow field near burner exit, in particular, center toroidal recirculation zone (CTRZ) as well as turbulent intensity, and thus the flame stability and emission performance might be significantly changed. With the comparison of experimental results, the case of swirl angle $45^{\circ}$ and co-swirl flow including optimum location of pilot burner were chosen in terms of the flame stability and emissions for the development of hybrid/dual swirl jet combustor.

Effects of Light and Photosynthetic Electron Transport System on the Generation of Singlet Oxygen ($^1$O$_2$) in Ginseng Thylakoid Membrane (인삼 틸라코이드에서 Singlet Oxygen($^1$O$_2$) 생성에 미치는 전자전달계의 영향)

  • Yang, Deok-Cho;Chae, Quae;Lee, Sung-Jong;Kim, Yong-Hae;Kang, Young-Hee
    • Journal of Ginseng Research
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    • v.14 no.1
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    • pp.57-62
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    • 1990
  • In order to Investigate the mechanism of the leaf-burning disease of ginseng (Panax ginseng C.A. Meyer), studies on the generation of singlet oxygen (1O2) and the photooxidation of the pigments were carried out in comparison with the ones of soybean (G1ycine max L). The studies were mainly focalized on the effects of light intensity, light intensity, inhibitor and electron donor/acceptor of the Photosynthetic electron transport system. When we measured the amounts of 1O2 generated in the thylakoids of ginseng and soybean by the irradiation of light (300 w/m2) as a function its time. It was identified that a higher amount of 1O2 was formed in the ginseng thylakoid than the case of soybean. A generation ratio of lO2 between ginseng and soybean sltbstantially identical in the range of light intensities 50∼150w/m2 However much higher amount of 1O2 was generated in ginseng by irradiation of strong intensity of light (200 500w/m2). Wave length dependency on the generation of 1O2 and the pigment photooxidation was observed on ginseng thylakoids; red light (600-700 nm) gave a maximum effect in the contrast with blur green light (400-60 nm). When the ginseng thylalioid was treated with the electron donor (Mn2+) and acceptors (DCPIP, FeCy) of the photosynthetic electron transport system. a drastic inhibition of 1O2 generation was observed. However, treatment with its inhibitors (DCMU, KCW) activated 1O2 generation. An interesting fact that an electron donor or acceptor of the photosystem II(P680) Inhibited 1O2 generation, suggests an intimate relationship between 1O2 generation and photosystem II.

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The Analysis of Acoustic Waves generated by a TA(ThermoAcoustic) Laser Pair (열음향(Thermoacoustic) 레이저의 음향파 특성 분석)

  • Oh, Seung-Jin;Chen, Kuan;Lee, Yoon-Joon;Shin, Sang-Woong;Lim, Sang-Hoon;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.31 no.6
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    • pp.1-7
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    • 2011
  • Sound waves and acoustic energy generated by two identical TA (ThermoAcoustic) lasers were analyzed and studied. One end of the ceramic stack was heated by a thin NiCr wire wound around that end. The other end of the stack was cooled by natural convection of atmospheric air. The wavelength of the sound waves generated by a single TA laser was four times the tube length and the amplitude of the waves increased with the heating rate. SPL (SoundPressure Level) meters and microphones were employed to measure and study the sound waves at different distances from the glass tube opening and at the focusing point of the TA laser pair for different laser position arrangements. The sound waves of the two TA lasers at the focusing point were found to be almost 180 degrees out of phase when the openings of the two lasers were very close to each other and the angle between the laser axes was small. When the two TA lasers were placed far apart, the sound wave amplitudes and the phase difference between the two laser outputs varied periodically with time. The frequencies of the sound waves changed when the openings of the two TA lasers were in close vicinity and the angle between the laser axes exceeded a certain value. In this case, the glass tube opening was no longer a pressure anti-node and the wavelength of the fundamental mode was not equal to four times the tube length.

A Structural Complexity Metric for Web Application based on Similarity (유사도 기반의 웹 어플리케이션 구조 복잡도)

  • Jung, Woo-Sung;Lee, Eun-Joo
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.8
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    • pp.117-126
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    • 2010
  • Software complexity is used to evaluate a target system's maintainability. The existing complexity metrics on web applications are count-based, so it is hard to incorporate the understandability of developers or maintainers. To make up for this shortcomings, entropy-theory can be applied to define complexity, however, it is assumed that information quantity of each paper is identical. In this paper, structural complexity of a web application is defined based on information theory and similarity. In detail, the proposed complexity is defined using entropy as the previous approach, but the information quantity of individual pages is defined using similarity. That is, a page which are similar with many pages has smaller information quantity than a page which are dissimilar to others. Furthermore, various similarity measures can be used for various views, which results in many-sided complexity measures. Finally, several complexity properties are applied to verify the proposed metric and case studies shows the applicability of the metric.

Studies on Isoindoline Derivatives. III. Studies on the Anhydrides and Imides of Dibasic Acids for the Organic Acids in the Gabriel Condensation (Isoindoline 유도체의 합성연구 III 이염기산무수물 또는 Imjde에 대한 유기산의 Gabriel 축합반응에 관한 연구)

  • 이남순;임중기;조태순;원정희;문도원;박인석;김무곤;민윤식;정진수
    • YAKHAK HOEJI
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    • v.18 no.1
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    • pp.59-73
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    • 1974
  • Fifteen derivatives of phthalide were synthesized from m-hemipinic, hydrastic and 4,5-benzophthalic anhydride with acetic, phenylacetic, p-methoxyphenylacetic, p-nitrophenylacetic, ${\alpha}$-nephthylacetic and succinic acid by the Gabriel condensation. In the same way, 13 derivatives of phthalimidine and 4 derivatives of ${\alpha,\beta}$ -benzisothiazoline-1, 1-dioxide were synthesized from diphenylmaleimide, phthalimide, saccharine and 4,5-benzo-phthalimide with previous 6 acids. 3-Substituted derivatives of m-hemipinic anhydride, hydrastic anhydride and 4,5-benzophthalic anhydride were treated with formamide and seven 3-substituted imidines could be synthesized. In case of 4,5-benzophtha lide, two isomers,4,5-benzophthalidene-3-acetic acid and 4,5-benzophthalidene-1-acetic acid, can be obtained theoretically, but only one product we got, and the chemical structure of it was identified by the following way. It was hydrolyzed and then decarboxylated, and this decomposed product was identical with 1-acetyl-2-naphthoic acid which was synthesized from .betha.-naphthylamine. This indicates that by the Gabriel condensatioin 4,5-benzophthalide only produces 4,5-benzophthlidene-3-acetic acid, that is ${\alpha}$-carbonyl substitute.

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