• Title/Summary/Keyword: Ideal gas equation

Search Result 52, Processing Time 0.022 seconds

Bondline Strength Evaluation of Honeycomb Sandwich Panel For Cure Process and Moisture Absorption (경화공정 및 수분흡수에 따른 복합재료 하니콤 샌드위치 판넬의 접합강도특성 연구)

  • Choe, Heung-Seop;Jeon, Heung-Jae;Nam, Jae-Do
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.25 no.1
    • /
    • pp.115-126
    • /
    • 2001
  • In this paper, through a series of comparative experiments, effects of two different cure processing methods, cocure and precure, on the mechanical properties of honeycomb core materials for aircraft applications are considered. Mass of moisture accumulated into the closed cells of the sandwich panel specimen from the measured mass of moisture diffused to the full saturation state into the elements(skin, adhesive layer, Nomex honeycomb), consisting the honeycomb sandwich specimen has been calculated. Water reservoir of 70$\^{C}$ was used to have specimens absorb moisture to see the influence of moisture absorbed into sandwich panel on its mechanical properties. For the repair condition holding for 2 hours at 177$\^{C}$(350℉) temperature, a pressure due to the vapor expansion in each cell of the sandwich panel, which may result in the local separation of the interface between laminated skin and the surface of the honeycomb, has been estimated by vapor pressure-temperature relation from the thermodynamic steam table and compared to the pressure from the ideal gas state equation. The bonding strengths of the laminated skins on the flat surface of the Nomex honeycomb have been compared by the flatwise tension test and climbing drum peel test performed at room temperature for dry, wet and wet-repair specimens, respectively.

Oxygen detection of sensor cells based on YSZ (Yttria-Stabilized Zirconia) thin films (YSZ(yttria-stabilized zirconia) 박막을 이용한 센서 셀의 산소 감응)

  • 박준용;배정운;황순원;김기동;조영아;전진석;최동수;염근영
    • Journal of the Korean Vacuum Society
    • /
    • v.8 no.4B
    • /
    • pp.507-513
    • /
    • 1999
  • 8mol%-yttria-stabilized zirconia(YSZ) thin films as oxygen ion conductor were deposited by rf-magnetron sputtering, and the oxygen gas sensors with the structure of $SiO_2$ substrate/Ni-NiO mixed reference layer/Pt/YSZ/Pt were fabricated and their oxygen sensing properties were investigated. The steady-state electro-motive force (EMF) values were measured as a function of oxygen partial pressure ($PO_2;form 1.013\times10^3 \textrm{Pa \;to}\; 1.013\times10^5$Pa) and operating temperature ($300^{\circ}C$ to $700^{\circ}C$). The fabricated YSZ oxygen sensor showed the best oxygen sensing properties at 50$0^{\circ}C$. However, oxygen sensing properties were very low at the temperature lower than 30$0^{\circ}C$ due to the lack of oxygen ion mobility and at the temperature higher than $700^{\circ}C$ due 새 intermixing of materials between the layers. Especially, the YSZ sensor operating at $500^{\circ}C$ and oxygen partial pressure above $1.565\times10^4$Pa showed the oxygen sensing properties close to the values predicted by ideal Nernst equation.

  • PDF

Analysis of Characteristics of Spent Fuels on Long-Term Dry Storage Condition

  • Yoon, Suji;Park, Kwangheon;Yun, Hyungju
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.19 no.2
    • /
    • pp.205-214
    • /
    • 2021
  • Currently, the interim storage pools of spent fuels in South Korea are expected to become saturated from 2024. It is required to prepare an operation plan of a domestic dry storage facility during a long-term period, with the researches on safety evaluation methods. This study modified the FRAPCON code to predict the spent fuel integrity evaluation such as the axial cladding temperature, the hoop stress and hydrogen distribution in dry storage. The cladding temperature in dry storage was calculated using the COBRA-SFS code with the burnup information which was calculated using the FRAPCON code. The hoop stress was calculated using the ideal gas equation with spent fuel information such as rod internal pressure. Numerical analysis method was used to calculate the degree of hydrogen diffusion according to the hydrogen concentration and temperature distribution during a dry storage period. Before 50 years of dry storage, the cladding temperature and hoop stress decreased rapidly. However, after 50 years, they decreased gradually and the cladding temperature was below 400 K. The initial temperature distribution and hydrogen concentration showed a parabolic line, but hydrogen was transferred by the hydrogen concentration and temperature gradient over time.

Process Design of Carbon Dioxide Storage in the Marine Geological Structure: I. Comparative Analysis of Thermodynamic Equations of State using Numerical Calculation (이산화탄소 해양지중저장 처리를 위한 공정 설계: I. 수치계산을 통한 열역학 상태방정식의 비교 분석)

  • Huh, Cheol;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.11 no.4
    • /
    • pp.181-190
    • /
    • 2008
  • To response climate change and Kyoto protocol and to reduce greenhouse gas emissions, marine geological storage of $CO_2$ is regarded as one of the most promising option. Marine geological storage of $CO_2$ is to capture $CO_2$ from major point sources(eg. power plant), to transport to the storage sites and to store $CO_2$ into the marine geological structure such as deep sea saline aquifer. To design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. The purpose of this paper is to compare and analyse the relevant equations of state including ideal, BWRS, PR, PRBM and SRK equation of state. To evaluate the predictive accuracy of the equation of the state, we compared numerical calculation results with reference experimental data. Ideal and SRK equation of state did not predict the density behavior above $29.85^{\circ}C$, 60 bar. Especially, they showed maximum 100% error in supercritical state. BWRS equation of state did not predict the density behavior between $60{\sim}80\;bar$ and near critical temperature. On the other hand, PR and PRBM equation of state showed good predictive capability in supercritical state. Since the thermodynamic conditions of $CO_2$ reservoir sites correspond to supercritical state(above $31.1^{\circ}C$ and 73.9 bar), we conclude that it is recommended to use PR and PRBM equation of state in designing of $CO_2$ marine geological storage process.

  • PDF

A Study on the Safety Improvement in a Venting System from the HCl Release Accident of a Petrochemical Company (석유화학공장의 염화수소 누출사고를 통한 대기벤트 시스템의 안전성 향상 방안)

  • Ma, Byung-Chol;Lee, Keun-Won;Im, Ji-Pyo;Kim, Young-Chul
    • Journal of the Korean Institute of Gas
    • /
    • v.16 no.4
    • /
    • pp.38-43
    • /
    • 2012
  • The purpose of this study is to carry out the consequence analysis of an accident related to the release of Hydrogen chloride occurred in a petrochemical company in Korea and suggest the measures to prevent similar accidents from happening again. The total amount released through the safety valve of HCl Column was calculated based on the rated capacity of the safety valve, the ideal gas equation and mechanical energy balance, respectively. As a result of the calculation, we found that the amount of HCl released through the safety valve was at least 76.8 kg. Also, we predicted the dispersion concentration at the position of the injured workers(more than 350 m away from the accident location) using simulation programs such as PHAST. The results of ALOHA and K-CARM are 304 ppm and 1,700 ppm respectively. However, PHAST calculation indicated that the concentration is less than l ppm. From these results, we can understand that workers were injured by HCl gas released from the safe valve and the concentration of gas might be less than 1 ppm. Also, it is important for toxic gases such as HCl to be vented safely to the atmosphere after scrubbing.

A study on the development of simulation program for the small naturally aspirated four-stroke diesel engine (소형 4행정사이클 무과급 디이젤 기관의 성능 시뮤레이션 전산프로그램의 개발에 관한 연구)

  • 백태주;전효중
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.8 no.1
    • /
    • pp.17-36
    • /
    • 1984
  • Since 1973, the competition on the development of fuel saving type internal combustion engines has become severe by the two times oil shock, and new type engines are reported every several months. Whenever these new type engines are developed, new designs are required and they will be offered in the market after performing the endurance test for a long time. But the engine market is faced with a heavy burden of finance, as the developing of a new engine requires tremendous expenses. For this reason, the computer simulation method has been lately developed to cope with it. The computer simulation method can be available to perform the reasonable research works by the theoretical analysis before carrying out practical experiments. With these processes, the developing expenses are cut down and the period of development is curtailed. The object of this study is the development of simulation computer program for the small naturally aspirated four-stroke diesel engine which is intended to product by the original design of our country. The process of simulation is firstly investigated for the ideal engine cycle, and secondly for the real engine cycle. In the ideal engine cycle, each step of the cycle is simulated by the energy balance according to the first law of thermodynamics, and then the engine performance is calculated. In the real cycle imulation program, the injection rate, the preparation rate and the combustion rate of fuel and the heat transfer through the wall of combustion chamber are considered. In this case, the injection rate is supposed as constant through the crank angle interval of injection and the combustion rate is calculated by the Whitehouse-Way equation and the heat transfer is calculated by the Annand's equation. The simulated values are compared with measured values of the YANMAR NS90(C) engine and Mitsubishi 4D30 engine, and the following conclusions are drawn. 1. The heat loss by the exhaust gas is well agree with each other in the lower load, but the measured value is greater than the calculated value in the higher load. The maximum error rate is about 15% in the full load. 2. The calculated quantity of heat transfer to the cooling water is greater than the measured value. The maximum error rate is about 11.8%. 3. The mean effective pressure, the fuel consumption, the power and the torque are well agree with each other. The maximum error is occurred in the fuel consumption, and its error rate is about 7%. From the above remarks, it may be concluded that the prediction of the engine performance is possibly by using the developed program, although the program needs to reform by adding the simulation of intake and exhaust process and assumping more reliable mechanical efficiency, volumetric efficiency, preparation rate and combustion rate.

  • PDF

Study of spatial temperature distribution during combustion process in a high temperature and pressure constant volume chamber (고온 고압 정적 연소실에서 연소과정에 따른 온도 분포 측정)

  • Kim, Ki-hyun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.1
    • /
    • pp.345-350
    • /
    • 2017
  • Downsizing is widely applied to diesel engines in order to improve fuel efficiency and reduce exhaust emissions. Engine sizes are becoming smaller but pressure and temperature inside combustion chambers are increasing. Therefore, research for fuel spray under high pressure and temperature conditions is important. A constant volume chamber which simulates high temperature and pressure likely to be found in diesel engines was developed in this study. Pressure and temperature were increased abruptly because of ignition of the pre-mixture in the constant volume chamber. Then pressure and temperature were gradually decreased due to the heat loss through the chamber wall. Fuel spray occurred when temperature and pressure were reached at the target condition. In this experiment, the temperature condition should be exactly defined to understand the relation between fuel evaporation and ambient temperature. A fast response thermocouple was developed and used to measure the temporal and spatial temperature distribution during the combustion process inside the combustion chamber. In the results, the core temperature was slightly higher than the bulk temperature calculated by the gas equation. Ed-note: do you want to say 'ideal gas equation'? This was attributed to the heat transfer loss through the chamber wall. The vertical temperature deviation was higher than the horizontal temperature deviation by 5% which resulted from the buoyancy effect.

Comparative Analysis of Chemistry Curriculum between Korea and New Zealand (한국과 뉴질랜드의 화학 교육과정 비교)

  • Kim, Hyun Jung
    • Journal of the Korean Chemical Society
    • /
    • v.62 no.3
    • /
    • pp.235-242
    • /
    • 2018
  • The purpose of this study is to analyze the chemistry curriculum between Korea and New Zealand. Both countries state that they want to cultivate their key competencies through the curriculum, and Korea' key competencies are similar to New Zealand'. Also, we find a strong correlation between key competencies of Korea science and achievement aims of the nature of science in New Zealand. Specially, the achievement standards that cultivate the key competencies are presented separately in New Zealand curriculum and NCEA, and confirms the achievement level through internal evaluation. By comparison, the curriculum content for chemistry is a good fit because of the overlap in the content. The Chemistry I is in the 7th level of New Zealand curriculum and the Chemistry II is in the 7th and 8th levels of New Zealand. However, there are some differences in hydrocarbon, ideal gas equation, colligative property and understanding of spectroscopic data.

Evaluation of the Effect of Riser Support System on Global Spar Motion by Time-domain Nonlinear Hull/Mooring/Riser Coupled Analysis

  • KOO BON-JUN;KIM MOO-HYUN
    • Journal of Ocean Engineering and Technology
    • /
    • v.19 no.5 s.66
    • /
    • pp.16-25
    • /
    • 2005
  • The effect of vertical riser support system on the dynamic behaviour of a classical spar platform is investigated. Spar platform generally uses buoyancy-can riser support system, but as water depth gets deeper the alternative riser support system is required due to safety and cost issues. The alternative riser support system is to hang risers off the spar platform using pneumatic cylinders rather than the buoyancy-can. The existing numerical model for hull/mooring/riser coupled dynamics analysis treats riser as an elastic rod truncated at the keel (truncated riser model), thus, in this model, the effect of riser support system can not be modeled correctly. Due to this reason, the truncated riser model tends to overestimate the spar pitch and heave motion. To evaluate more realistic global spar motion, mechanical coupling among risers, guide frames and support cylinders inside of spar moon-pool should be modeled. In the newly developed model, the risers are extended through the moon-pool by using nonlinear finite element methods with realistic boundary condition at multiple guide frames. In the simulation, the vertical tension from pneumatic cylinders is modeled by using ideal-gas equation and the vertical tension from buoyancy-cans is modeled as constant top tension. The different dynamic characteristics between buoyancy-can riser support system and pneumatic riser support system are extensively studied. The alternative riser support system tends to increase spar heave motion and needs damper system to reduce the spar heave motion.

Evaluations of the Equations of State and Thermodynamic Quantities of Fluid Metal at High Temperatures and Densities

  • Shin, Hyun-Joon;Hong, Jong-Ha;Oh, Byung-Wan
    • Nuclear Engineering and Technology
    • /
    • v.10 no.3
    • /
    • pp.127-136
    • /
    • 1978
  • We have applied the temperature dependent Thomas-Fermi theory to evaluate the equations of state, chemical potentials, entropies, % ionizations, total energies and kinetic energies of an atom, and seveal thermodynamic quantifies of one of metallic substance, Na, for a density range of 0.1$\rho$$_{0}$ ~ 10$\rho$$_{0}$, where $\rho$$_{0}$ is the normal density of Na at its melting point, and for a temperature range of 60.88Ryd. ~0.0216 Ryd., where the system is expected to be in a gaseous or liquid state. The main interest of present work lies in physical quantities at high temperatures and high densities, however, we have included those quantities of Na at sufficiently low temperatures and low densities to show that the approximation is not so crude as one might expect. Particularly, at high temperatures, the calculated equations of state, kinetic energies of an atom, chemical potentials and entropies are compared with those, of an ideal Fermi gas. The results show that, at high temperatures, the agreement seems good for chemical Potentials. However, the differences in, entropy, kinetic energy of an atom, and equation of state are not negligible even at such high temperature as $textsc{k}$T=60.88Ryd.

  • PDF