• Title/Summary/Keyword: Ice thickness

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Study of Frozen Molecular Surfaces by $Cs^{+}$ Reactive ion Scattering and tow-Energy Secondary ton Mass Spectrometry

  • Park, S.-C.;Kang, H.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.1
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    • pp.30-35
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    • 2002
  • We show that a combined technique of Cs$^{+}$ reactive ion scattering (Cs$^{+}$ RIS) and low-energy secondary ion mass spectrometry (LESIMS) provides a powerful means for probing molecular films and their surface reactions. Simple molecules, including HCI, NH$_3$, D$_2$O, and their mixtures, were deposited into a thin film of several monolayer thickness on Ru(001) at low temperature in vacuum, and the surface was characterized by Cs$^{+}$ RIS and LESIMS. On pure films, D$_2$O, HCI, and NH$_3$ existed in the corresponding molecular states. When HCI and NH$_3$ were co-deposited, ammonium ion(NH$_4$$^{+}$) was readily formed by proton transfer from HCI to NH$_3$. In the presence of water molecules, HCI ionized first to hydronium ion(H$_3$O$^{+}$), which subsequently transferred proton to NH$_3$ to form NH$_4$$^{+}$. The proton transfer, however, did not occur to a completion on ice, in contrast to the complete reaction in aqueous solutions.s solutions.

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Economic Valuation of the Biodiversity-Related Changes in Ecosystem Services of the Arctic Caused by Climate Change (북극의 기후변화로 인한 생태계변화의 경제적 가치추정)

  • Kang, Heechan;Kim, Hyo-Sun
    • Environmental and Resource Economics Review
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    • v.25 no.2
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    • pp.321-349
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    • 2016
  • According to the recent observation by NOAA(US National Oceanic and Atmospheric Administration), 2015 is the warmest year based on global average temperature since 1880. The air temperatures in the Arctic have been rising at almost twice the global average and the extent and thickness of sea ice in the Arctic have declined. And the warming process in the Arctic is accelerating rapidly. These impacts of drastic change in sea ice caused by climate change in the Arctic threaten the eco-system service and biodiversity in the Arctic. This study intends to estimate the economic value on changes in eco-system services and biodiversity of the Arctic caused by climate change. The result of the valuation indicates that the total benefit from improvement of ecosystem in the Arctic ranges from 318.6 billion won to 715.9 billion won per annum. Replication scenarios can be explored into two broad categories in future studies: scenarios in consideration of conflicts of different stakeholders and scenarios based on wider or narrower definition of biodiversity in the Arctic.

Determination of Boil-Off gas Ratio for the Design of Underground LNG Storage System in Rock Cavern (암반동굴식 지하 LNG 저장 시스템 설계를 위한 기화율의 산정)

  • Chung, So-Keul;Lee, Hee-Suk;Jeong, Woo-Cheol;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.17 no.1 s.66
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    • pp.56-65
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    • 2007
  • A new underground LNG storage concept in the rock mass has been developed by combining underground cavern construction and new ice-ring harrier technologies with the conventional cryogenic insulation system. Technical feasibility of the storage system has been verified through construction and operation of the pilot storage cavern and a full-scale project is expected to start in the near future. One of the most important issues in the LNG storage system is the operational efficiency of the storage to minimize heat loss during a long period of operation due to the cryogenic heat transfer. This paper presents several important results of heat transfer and coupled hydro-thermal analyses by a finite element code Temp/W and Seep/W. A series of heat transfer analyses for full-scale caverns were performed to determine design parameters such as boil-off gas ratio (BOR), insulation thickness and pillar width. The result of the coupled hydro-mechanical analysis showed that BOR for underground storage system remains at about 0.04 %/day during the early stage of the operation. This value could be even much lower when the discontinuities in the rock masses are taken into consideration.

Study on Characteristics of Snowfall and Snow Crystal Habits in the ESSAY (Experiment on Snow Storms At Yeongdong) Campaign in 2014 (2014년 대설관측실험(Experiment on Snow Storms At Yeongdong: ESSAY)기간 강설 및 눈결정 특성분석)

  • Seo, Won-Seok;Eun, Seung-Hee;Kim, Byung-Gon;Ko, A-Reum;Seong, Dae-Kyeong;Lee, Gyu-Min;Jeon, Hye-Rim;Han, Sang-Ok;Park, Young-San
    • Atmosphere
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    • v.25 no.2
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    • pp.261-270
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    • 2015
  • Characteristics of snowfall and snow crystal habits have been investigated in the campaign of Experiment on Snow Storms At Yeongdong (ESSAY) using radiosonde soundings, Global Navigation Satellite System (GNSS), and a digital camera with a magnifier for taking a photograph of snowfall crystals. The analysis period is 6 to 14 February 2014, when the accumulated snowfall amount is 192.8 cm with the longest snowfall duration of 9 days. The synoptic situations are similar to those of the previous studies such as the Low pressure system passing by the far South of the Korean peninsula along with the Siberian High extending to northern Japan, which eventually results in the northeasterly or easterly flows and the long-lasting snowfall episodes in the Yeongdong region. In general, the ice clouds tended to exist below around 2~3 km with the consistent easterly flows, and the winds shifted to northerly~northwesterly above the clouds layer. The snow crystal habits observed in the ESSAY campaign were mainly dendrite, consisting of 70% of the entire habits. The rimed habits were frequently captured when two-layered clouds were observed, probably through the process of freezing of super-cooled droplets on the ice particles. The homogeneous habit such as dendrite was shown in case of shallow clouds with its thickness of below 500 m whereas various habits were captured such as dendrites, rimed dendrites, aggregates of dendrites, plates, rimed plates, etc in the thick cloud with its thickness greater than 1.5 km. The dendrites appeared to be dominant in the condition of cloud top temperature specifically ranging $-12{\sim}-16^{\circ}C$. However, the association of snow crystal habits with temperature and super-saturation in the cloud could not be examined in the current study. Better understandings of characteristics of snow crystal habits would contribute to preventing breakdown accidents such as a greenhouse destruction and collapse of a temporary building due to heavy snowfall, and traffic accidents due to snow-slippery road condition, providing a higher-level weather information of snow quality for skiers participating in the winter sports, and estimating more accurate snowfall amount, location, and duration with the fallspeed of solid precipitation.

The Frost Heaving Characteristics of Subgrade Soils Using Laboratory Freezing System (실내동결시스템을 이용한 노상토의 동상 특성)

  • Shin, Eun-Chul;Ryu, Byung-Hyun;Park, Jeong-Jun
    • International Journal of Highway Engineering
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    • v.12 no.2
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    • pp.71-79
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    • 2010
  • The influence of fines of the frost susceptibility of subgrade soils were established by laboratory freezing system test simulating closely the thermal conditions in the field. During the winter season, the climate is heavily influenced by the cold and dry continental high pressure. Because of siberian air mass, the temperature of January is $-6{\sim}-7^{\circ}C$ on average. This chilly weather generate the frost heaving by freezing the moisture of soil and damage potential of the road structure. In the freezing soil, the ice lenses increase the freeze portion of soil by absorbing the ground water with capillary action. However, the capillary characteristics differ from the sort of soil on the state of freezing condition. In the current design codes for anti-freezing layer, the thickness of anti freezing layer is calculated by freezing depth against the temperature condition. Therefore, they have a tendency of over-design and uniform thickness without the considerations of thermal stability, bearing capacity and frost susceptibility of materials. So, it is essential for studying the appropriateness and bearing capacity besides the seasonal and mechanical properties of pavement materials to take a appropriate and reasonable design of the road structure. In this Paper, the evaluation of frost susceptibility was conducted by means of the mechanical property test and laboratory freezing system apparatus. The temperature, heaving amount, heaving pressure and unfrozen water contents of soil samples, the subgrade soils of highway construction site, were measured to determine the frost susceptibility.

Evaluation of Active Layer Depth using Dynamic Cone Penetrometer (동적 콘 관입기를 이용한 활동층 심도평가)

  • Hong, Won-Taek;Kang, Seonghun;Park, Keunbo;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.1
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    • pp.49-54
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    • 2016
  • An active layer distributed on surface of an extreme cold region causes a frost heave by repeating the freezing and thawing according to the seasonal temperature change. Since the height of frost heave is greatly affected by the thickness of active layer, an accurate evaluation of the thickness of active layer is necessary for the safe design and construction of the infrastructure in the extreme cold region. In this study, dynamic cone penetrometer, which is miniaturized in-situ penetration device, is applied for the evaluation of active layer depth distribution. As the application tests, two dynamic cone penetration tests were conducted on the study sites located in Solomon and Alaska. In addition, ground temperature variations were obtained. As the results of the application tests, the depth of interface between the active layer and the permafrost was evaluated from the difference in dynamic cone penetration indexes of the active layer and the permafrost, and a layer was detected around the interface considered as an ice lens layer. Also, the interface depths between the above zero and the below zero temperature determined from the ground temperature variations correspond with the interface depths evaluated from the dynamic cone penetration tests. This study demonstrates that the dynamic cone penetrometer may be a useful tool for the evaluation of the active layer in the extreme cold region.

The Effect of Cold-rolling on Microstructure and Transformation Behavior of Cu-Zn-Al shape Memory Alloy (냉간가공에 의한 CuZnAl계 현상기억합급의 결정립미세화와 특성평가)

  • Lee, Sang-Bong;Park, No-Jin
    • Korean Journal of Materials Research
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    • v.9 no.3
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    • pp.322-326
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    • 1999
  • In this study, cold-rolling and appropriate annealing was adopted for the grain refining of Cu-26.65Zn-4. 05Al-0.31Ti(wt%) shape memory alloy. For the cold deformation of this alloy the ducti1e $\alpha$-phase must be contained. After heat treatment at $550^{\circ}C$ the $(\alpha+$\beta)$-dual phase with 40vol.% $\alpha$-phase was obtained which could be rolled at room temperature. This alloy was cold rolled into a final thickness of 1.0mm with total reduction degrees of 70% and 90%. The rolled sheets were betanized at $800^{\circ}C$ for various times, then quenched into ice water. The grain size of co]d rolled samples were $60~80\mu\textrm{m}$ which is much smaller comparing with the hot-rolled samples. And the 90% rolled sample showed smaller grain size than the case of the 70% rolled one. The small grain size had influence on the phase transformation temperatures and stabilization of the austenitic phases.

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Numerical analysis for deformation characteristics under the freezing and bursting of Al pipe (알루미늄 관의 동파 거동특성에 관한 수치적 연구)

  • Choi, Seung-Hyun;Lee, Dong-Won;Ko, Young-Bae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4763-4768
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    • 2014
  • Recently, aluminum pipes have been used instead of steel pipes for open and shut machines in vinyl housing because of its corrosion-resistance and light weight. In particular, the light weight is very useful for fitting and removal by human resources. On the other hand, an aluminum pipe is weak in winter because aluminum has a larger thermal expansion coefficient than steel. This study examined the freezing and bursting of aluminum pipes by numerical analysis. The mechanical-thermal deformation characteristics were analyzed under the condition of ice volumetric expansion in aluminum pipes reaching 50%. From numerical analysis, large stresses above the yield stress occurred in aluminum pipe after ice expanded in the net diameter immediately. In addition, the freezing and bursting of aluminum pipes was predicted around an ice volumetric expansion of 6 - 7% because the thickness of the aluminum pipe reached an aluminum elongation ratio of 17%. Therefore, it is recommended that aluminum pipes be sealed perfectly to prevent water flow in the pipe. These results suggest that it is very difficult to prevent freezing and bursting of aluminum pipes by water freezing in the pipe.

Controlled Partial Skin Thickness Burns: Rabbit Ear as a 2nd Degree Burn Wound Model for Studies of Topical Therapy

  • Cho, Lee Ae-Ri;Moon, Hee-Kyung
    • Journal of Pharmaceutical Investigation
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    • v.36 no.5
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    • pp.339-342
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    • 2006
  • This study was designed to prepare an animal model for partial thickness bum wound which can be employed for testing topical therapy. We first evaluated whether rabbit ear and mouse back skin wound model could differentiate the wound healing process in terms of degree of re epithelialization, required days for complete wound closure, presence of scarring. $2^{nd}$ degree wet bum were prepared on mouse back skin and rabbit ear by applying 5 mL hot water($85{\pm}0.1^{\circ}C$) for 7 see followed by 5 mL ice-cold 0.5% acrynol solution for cooling and disinfecting the inflicted area. After removing the dead epidermis layer at 24 hr, tested dressings were applied for specified time and wound progression was investigated. In mouse model, wound contraction was the primary wound closing mechanism, which is quite different from human wound healing process. In rabbit ear model, epidermal regeneration was the major wound healing process rather than wound contraction and the difference in wound healing property among tested dressings could be clearly demonstrated. A rabbit ear model could differentiate the wound progression among open, occluded and epidermal growth factor(EGF) treated wound. Four sites of circular wound(diameter: 1 cm) on the anterior part of rabbit ear could be employed for the comparative wound healing study. For obtaining reproducible bum wound, degree of bum depth and bum sites should be carefully controlled in addition, employing rabbits of same strain and weight. The result suggests that rabbit ear could be employed as a reliable and human-resembled wound model.

The study on the shade color change that depends on the kind of zirconia core and the porcelain thickness (지르코니아 코어의 종류와 도재 두께에 따른 색상의 변화)

  • Yeom, Mi-Ok;Lee, Jong-Hyuk;Shin, Soo-Yeon;Sin, Seung-Chul;Cho, Ja-Won
    • Journal of Technologic Dentistry
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    • v.32 no.4
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    • pp.341-350
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    • 2010
  • Purpose: This study focused on achieving desired shades by combining zirconia core with different thickness porcelain in order to make dental prostheses effectively. Methods: White and colored $LAVA^{TM}$ All Ceramic (3M-ESPE, Seefeld, Germany), and Zirkonzahn (Bruneck, Italy) Trans and prettau were used to have Zirconia. LAVATM Ceram (3M-ESPE, Germany) and ICE (Zirkonzahn, Italy) powder were used to have the porcelain. We made quadrilateral specimen of thickness 0.3mm, 0.5mm, 0.7mm and diameter 10 to use zirconia ceramics system of 2 kinds that color tone reappearance way is different and produced total 120 specimens to 4 experimental groups. We used Spectrophotometer to analyze color tone. Data's value getting by dispersal colorimetry period found L*, a*, b* value using Excel program. We used one-way ANOVA to use SPSS WIN 12.0 program. Results: All L*, a*, b* indexes of zirconia core and porcelain veneer in LAVA group and Zirkonzahn group were different. When you combine the white zirconia core of LAVA group with a porcelain veneer, the thickness of the porcelain must be more than 0.5mm to meet the standard target. When all the colored zirconia cores of LAVA group were combined with porcelain veneers, there was no significant difference from the standard target. When the zirconia cores of Zirkonzahn group are combined with porcelain veneers, the thinner thicknesses were closer to the standard tab than thicker thicknesses; however, there was a significant difference in all combinations, with Delta E* value indicating more than 3. Conclusion: When it comes to colored zirconia, which is the most popular, the thicknesses of both a core and a dentin veneer must be more than 0.3mm to get an appropriate shade. There is more possibility to get desirable shades when the thicknesses of a white core are thinner; however, they would be vulnerable to the environment and lose their color. When combine a zirconia core with a dentin veneer, using Zirkonzahn group needs more considerations in order to meet the standard target.