• Title/Summary/Keyword: IR absorption

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$CO_2$ Laser Absorption Measurement of $CH_3CH_2Br$ using Photoacoustic Method

  • Jang Soo Shin;Kyung Hoon Jung;Cheol Jung Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.553-556
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    • 1992
  • The ${CO}_2$ laser absorption measurement of ${CH}_3{CH}_2Br$ utilizing photoacoustic (PA) technique was performed using a cw and a pulsed ${CO}_2$ lasers. The absorption profile in the ${CO}_2$ laser wavelength region (9-10 ${\mu}$m) and the macroscopic small signal absorption cross section at 10P(20) (10.59 ${\mu}$m, 944 $cm^{-1}$) laser line were measured using a cw ${CO}_2$ laser. The laser fluence dependence on infrared multiphoton absorption (IRMPA) was also studied with a pulsed TEA ${CO}_2$ laser at 10P(20) laser line. In view of monotonic increase of PA signal with the rise of laser fluence, it was suggested that the anharmonicity in pumped vibration mode did not restrict ir multiphoton absorption in ${CH}_3{CH}_2Br$ system as found in large molecular system.

Characteristics of Surface Micromachined Pyroelectric Infrared Ray Focal Plane Array

  • Ryu, Sang-Ouk;Cho, Seong-Mok;Choi, Kyu-Jeong;Yoon, Sung-Min;Lee, Nam-Yeal;Yu, Byoung-Gon
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.1
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    • pp.45-51
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    • 2005
  • We have developed surface micromachined Infrared ray (IR) focal plane array (FPA), in which single $SiO_{2}$ layer works as an IR absorbing plate and $Pb(Zr_{0.3}Ti_{0.7})O_{2}$ thin film served as a thermally sensitive material. There are some advantages of applying $SiO_{2}$ layer as an IR absorbing layer. First of all, the $SiO_{2}$ has good IR absorbance within $8{\sim}12{\mu}m$ spectrum range. Measured value showed about 60% absorbance of incident IR spectrum in the range. $SiO_{2}$ layer has another important merit when applied to the top of Pt/PZT/Pt stack because it works also as a supporting membrane. Consequently, the IR absorbing layer forms one body with membrane structure, which simplifies the whole MEMS process and gives robustness Ito the structure.

Differential Absorption and Translocation of Bensulfuron-methyl Between Selected Rice Cultivars (Bensulfuron-methyl 처리(處理)에 따른 내성선발(耐性選拔) 수도품종(水稻品種)의 흡수(吸收) 및 이행차이(移行差異))

  • Guh, J.O.;Pyon, J.Y.;Ishizuka, K.
    • Korean Journal of Weed Science
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    • v.8 no.1
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    • pp.45-52
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    • 1988
  • A serial study on differential response in absorption and translocation of $^{14}C$-bensulfuron-methyl was conducted by use of a group of selected rice cultivars as the tolerant or the susceptible to bensulfuron-methly. Trial 1. Differential Response in Absorption and Translocation of Selected Cultivar Group. The susceptible cultivar group has reached as higher rate as 102%, 113%, 115%, 127% and 113% of the tolerant cultivar group in root absorption per seedling, per unit dry weight, and the rate of translocation from bottom to shoot, respectively. Trial 2. Differential Response in Absorption and Translocation of Selected Rice Cultivar as Affected by Exposed Time of Root Portion upto 48 hrs. ${\bullet}$ Regardless of leaf stage of experimented plants, the amount of absorption per seedling and per unit dry weight has reached rather higher in the susceptible(cv. IR 1846) than the tolerant (cv. Chinsurah Boro II). However, separating by portions, the tolerant was realized higher rate of aborption in root but the susceptible in shoot, respectively. ${\bullet}$ Translocation rate from root to shoot, namely the individual seedling based rate of radioactivity in shoot to total radioactivity, was significantly higher in the susceptile than the tolerant. ${\bullet}$ Depending on higher rate of seedling growth at the time of chemical treatment, the susceptible (cv. IR 1846) was seemed more sensitive even at equivalent rate of absorption and translocation.

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The Dose Characteristics of Designed Ir-192 Micro-source for Brachytherapy (근접조사용 Ir-192 마이크로선원의 디자인과 선량 특성)

  • 최태진;김진희
    • Progress in Medical Physics
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    • v.14 no.2
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    • pp.81-89
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    • 2003
  • The dose distributions of designed Ir-192 micro-source were investigated by dose computations which were accomplished by employing shape of encapsule material and thickness of the source for self-absorption. The computation dose derived from air-kerma rate (S$_{k}$ ) and dose rate constant (Λ) includes the anisotropy of dose distribution around the source. We got the dose rate constants in a water medium is 1.154 cGy h$^{-1}$ U$^{-1}$ . The size of the source was 0.5 mm in diameter and 3.5 mm in length and it was encapsuled in 1.1 mm$\Phi$${\times}$5.5 mm of stainless steel sealed with 0.3 mm of filter thickness. The tissue dose of reference point at 1.0 cm radial distance of the source axis was delivered 1.154 Uh$^{-1}$ (1.3167${\times}$10$^{-3}$ cGy/mCi-sec) from the S$_{k}$ 4.108U/mCi of Ir-192 source. The filtration effect contributed to air-kerma strength as exponential filtering effect of 86.2% in total attenuation, but self-absorption was 88.4% from radial dose distributions. In particular, the dose attenuations showed a rapid anisotropic distributions as 56% of reference dose along to $\pm$10 degrees from the tip of source axis and 50% for of that to source-cable direction. We persist in use the large diameter of applicator will avoid the dose anisotropy by the filtered attenuation effects along the axis of Ir-192 micro-source.

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Comparative Analysis on Insulation Performance of Traction Motors for Hybrid Vehicles (하이브리드 차량용 견인전동기의 절연성능 비교분석)

  • Choi, Su-Yeon;Park, Chan-Yong;Kim, Sung-Wook;Park, Dae-Won;Kil, Gyung-Suk;Lee, Kang-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1124-1129
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    • 2008
  • The object of this paper is to acquire the data related to insulation evaluation of hybrid vehicle traction motors. We made a comparative analysis on Insulation Resistance (IR), Dielectric Absorption Ratio (DAR), and Polarization Index (PI) of the motor stators. The experiment was carried out according to IEEE Std. 43 and IEC 60085-1 for insulation resistance test standard of rotating machinery. Test voltage of 500 V was applied between a phase and the enclosure. The IR and the DAR of used motors were lower than those of new ones. The DAR and the PI were $0.92{\sim}1.02$ and $0.74{\sim}1.1$, respectively and the result did not meet the recommendation basis 2 for insulation level H. From the experimental results, we could prepare parameters and basis for insulation evaluation of the traction motor stator by the comparative analysis of short-time insulation resistance changes, DAR and PI.

Near-IR Radiative Transfer Process for the Hazy Atmosphere of Titan

  • Kim, Sang-Joon
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.44.2-44.2
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    • 2015
  • Radiative transfer programs have been developed to simulate near-IR spectra of Titan. The formalism of the radiative transfer calculations includes the absorption and emission lines of $CH_4$, $C_2H_2$, $C_2H_6$, and HCN, and continua produced by Titanian haze particles. Absorption and scattering of sunlight by haze particles are considered by employing a two-stream approximation and a spherical-shell model for the atmospheric layers of Titan. Various constraints on the radiative transfer calculations for generating synthetic spectra will be discussed and presented. Several examples of comparisons between the synthetic spectra and recent spectral observations of Titan will also be presented.

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Studies on Structure and Color of the White Antheraea pernyi, Silkworm Cocoon

  • Tao, Ji;Hongde, Liu
    • Natural Product Sciences
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    • v.1 no.1
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    • pp.66-69
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    • 1995
  • Traditional Antheraea pernyi silkworm cocoon is tawny color. The white Antheraea pernyi silkworm cocoons studied here by IR and UV are new breeds of recent breeding. We discovered that the main body of the first grade structure of silk protein in the new white is as same as the one in the traditional tawny Antheraea pernyi silkworm cocoon, yet there are small quantities of cross-linked polymer of gentisic acid and silk protein in the white silkworm cocoons. In spite of the least surviving quantity of the polymer, the white silkworm cocoons are most white and its white color is similar to white Bombyx mori silkworm cocoon.

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The preparation of Ultra-thin films of Hexyltriphenyl-phosphonium-TCNQ complex by using Langmuir-Blogett method (Langmuir-Blodgett법을 이용한 Hexyltriphenyl-phosphonium-TCNQ착체의 초박막 제조)

  • Kang, Woo-Hyeang;Kim, Young-Kwan;Sohn, Byoung-Chung;Hwang, Kyo-Hyun;Han, Jong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.131-136
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    • 1995
  • Ultra-thin films of hexyltriphenylphosphonium-TCNQ(1:1) complex were formed on various substrates by Langmuir-Blodgett technique, where hexyltriphenylphosphonium-TCNQ(1:1) complex was synthesized by attaching hexyltriphenylphosphonium group to TCNQ. The reaction product was identified with FT-IR, and UV-Vis absorption spectroscopies. The formation of ultra-thin films of hexyltriphenylphosphonium-TCNQ(1:1) complex was confirmed also by FT-IR, and UV/Vis absorption spectroscopies.

Effects of Oxygen on the Photochemical Behaviors of Methacrylic Homopolymer Containing Anthracene Groups

  • Kim, Yong-Woon;Chae, Kyu-Ho
    • Journal of Photoscience
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    • v.9 no.3
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    • pp.57-63
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    • 2002
  • A homopolymer containing anthracene groups, poly[6-(9-anthryloxy)hexyl methacrylate] (PAn) was prepared and the effect of oxygen on its photochemical reaction was studied by UV and IR absorption spectroscopy in order to understand its photochemical behavior. Photochemical reaction of the PAn in THF solution under an atmosphere of air resulted in the formation of endoperoxide at the beginning stage of reaction followed by photodimerization reaction after all the oxygen was consumed, whereas photodimerization and endoperoxide formation took place concomitantly in the film state. The photoreversible reaction of the anthracene photodimer groups in the polymer by photolysis with 254 nm UV light was not efficient. The IR absorption spectral changes of the PAn film upon irradiation indicate that various photooxidation products were produced in the atmosphere of air.

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Synthesis, Crystal Structure, Spectra Characterization and DFT Studies on a Di-Cycle Pyrazoline Derivative

  • Song, Jie;Zhao, Pu Su;Zhang, Wei Guang
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1875-1880
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    • 2010
  • A dicycle pyrazoline derivative, 1-phenyl-5-(p-fluorophenyl)-3,4-($\alpha$-p-fluoro-tolylenecyclohexano) pyrazoline, was synthesized and characterized by elemental analysis, IR, UV-vis, fluorescence spectra and X-ray single crystal diffraction. Density function theory (DFT) calculations were performed by using B3LYP method with 6-$311G^{**}$ basis set. The optimized geometry can well simulate the molecular structure. Vibrational frequencies were predicted, assigned and compared with the experimental values, which suggest that B3LYP/6-$311G^{**}$ method can well predict the IR spectra. Both the experimental electronic absorption spectra and the predicted ones by B3LYP/6-$311G^{**}$ method reveal three electron-transition bands, with the theoretical ones having some red shifts compared with the experimental data. Natural bond orbital analyses indicate that the absorption bands are mainly derived from the contribution of n $\rightarrow\pi^*$ and $\pi\rightarrow\pi^*$ transitions. Fluorescence spectra determination shows that the title compound can emit blue-light at about 478 nm. On the basis of vibrational analysis, the thermodynamic properties of title compound at different temperature have been calculated, revealing the correlations between $C^0_{p,m}$, $S^0_m$, $H^0_m$ and temperature.