• 제목/요약/키워드: IPPD

검색결과 15건 처리시간 0.029초

고분자(高分子) 강성체(彈性體)의 노화방지제(老化防止劑) 효과(效果)에 관(關)한 연구(硏究) (A Study on the Effect of Rubber-Bound Antioxidant and Ordinary Antioxidant in Elastomer.)

  • 최세영;백남철
    • Elastomers and Composites
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    • 제17권1호
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    • pp.13-21
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    • 1982
  • The purpose of this dissertation is to compare bound andtioxidant, MHPPD with the ordinary one, IPPD, when high polymers are used like NR and SBR. The effect of rubber bound antioxidant and ordinary antioxidant on the Mooney scorch time has been studied by means of the Mooney viscometer. The ageing properties of vulcanizates containing rubber-bound antioxidant and ordinary antioxidant have been studied in terms of hardness, tensile strength and elongation. The results of the Mooney scorch time and ageing properties are as follows: When MHPPD was mixed with NR or SBR compounds, the Mooney scorch time was faster than the IPPD compounds. Also the ageing properties of the vulcanizates containing MHPPD were much superior to the IPPD compounds. Furthermore, the vulcanizates comporised of MHPPD have taken andvantage of and resistance in the ozone test.

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NR 및 SBR의 노화방지제(老化防止劑) 병용효과(倂用效果)에 의(依)한 가황특성(加黃特性) 연구(硏究) (A study on the vulcaniz러on characteristic of combined antioxidants in NR and SBR compounds)

  • 최재원;이기종
    • Elastomers and Composites
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    • 제17권2호
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    • pp.77-90
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    • 1982
  • The purpose of this study is to get comparative results on the combined antioxidant systems comprised of MHPPD with IPPD, MHPPD with PBN and MHIPPD with MB when they are individually added to NR and SBR compound. Vulcanization characterstics and physical properties of the combined antioxidants have been studied by means of the Mooney viscometer, the Monsanto disc rheometer and so on. According to the test results, MHPPD with IPPD system has shown faster cure rate, better optimum cure time and shorter scorch time than other systems. The vulcanizate comprised of the MHPPD with IPPD antioxidant system has taken advantage of heat resistance, fluid resistance and antiozone resistance.

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Migration of Antidegradants to the Surface in NR Vulcanizates: Influence of Content of Carbon Black

  • 최성신
    • Bulletin of the Korean Chemical Society
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    • 제19권2호
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    • pp.170-174
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    • 1998
  • Migration properties of antidegradants to the surface in NR vulcanizates containing carbon black of 30, 50, and 70 phr were studied using the migration-generating equipment with a vacuum technique. The migration was carried out at 60, 80, and 100 ℃ for 20 h. BHT, IPPD, HPPD, and wax were used as migrants. IPPD migrates faster than the other migrants. Amounts of BHT, IPPD, and HPPD that migrated at 60 and 80 ℃ decrease as the content of carbon black in the vulcanizate increases. Migrations of antidegradants in the NR vulcanizate containing carbon black of 50 phr are faster than those containing carbon black of 30 and 70 phr at 100 ℃. Although n-C23H48 is heavier than HPPD, it migrates faster than HPPD and even faster than BHT at 100 ℃. Influencing factors of carbon black on the migrations are its porous structure and polar functional groups on the surface.

천연고무 가류물에서 왁스막이 오존노화방지제의 이동에 미치는 영향 (Wax Barrier Effect on Migration Behaviors of Antiozonants in NR Vulcanizates)

  • 최성신
    • Elastomers and Composites
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    • 제34권2호
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    • pp.147-155
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    • 1999
  • 고무와 혼합된 왁스는 고무 표면으로 이동하여 방어막을 형성한다. 일반적으로 고무의 오존화를 방지하기 위해 오존노화방지제를 왁스와 함께 사용하고 있다. 다양한 종류의 왁스가 첨가된 천연고무 가류물을 이용하여 왁스막이 오존노화방지제의 이동에 미치는 영향을 연구하였다 오존노화방지제로 IPPD (N-isopropyl-N'-phenyl-p-phenylenediamine), HPPD (N-l,3-dimethylbutyl-N'-phenyl-p-phenylenediamine), SBPPD (N,N'-di(sec-butyl)-p-phenylenediamine), 그리고 DMPPD (N,N'-di(1,4-dimethylpentyl)-p-phenylenediamine)를 사용하였다. 노화방지제 이동 실험은 $60^{\circ}C$$80^{\circ}C$에서 10, 20, 30일간 실시하였다. 노화방지제의 이동속도는 고무가류물에 왁스가 없을 때가 있을 때보다 빨랐으며 분자량이 큰 왁스가 혼합되었을 때가 분자량이 작은 왁스가 혼합되었을 때보다 느렸다. DMPPD와 SBPPD의 이동속도가 HPPD와 IPPD의 이동속도보다 빨랐다.

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함정 수명주기관리시스템(PLM) 구축을 위한 통합 자료환경(IPDE) 구현 방안 (IPDE(Integrated Product Data Environment) Implementation Method for the Application of Naval Ship PLM(Product Lifecycle Management))

  • 정연환;유재문
    • 대한조선학회논문집
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    • 제42권6호
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    • pp.698-709
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    • 2005
  • This research analyzes the design work and construction work, which might be arising out of or during the procurement process of naval ships of the Korean Navy. This research also suggests the applicable information methodology driven out by utilizing PLM/POM tool, which could be one of practical solutions to the problems arising from the outcome of this analysis. As to the procedure and methodology of information technology of design and construction work of the ship, IPPD was adopted. Before its actual application, main contents of the IPPD were introduced in this research. And it's real application and subsequent concrete surroundings of IPDE were defined. In addition, addition, several detailed and necessary works to be fulfilled were defined, mainly focused on the application of IPDD for the design and construction stages of the ships suitable for the Korean Navy, And also, this analysis defines the main functions to be secured by adopting the PLM/POM tool and obtained the relevant functions partially herewith.

Improved Pre-prepared Power Demand Table and Muller's Method to Solve the Profit Based Unit Commitment Problem

  • Chandram, K.;Subrahmanyam, N.;Sydulu, M.
    • Journal of Electrical Engineering and Technology
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    • 제4권2호
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    • pp.159-167
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    • 2009
  • This paper presents the Improved Pre-prepared Power Demand (IPPD) table and Muller's method as a means of solving the Profit Based Unit Commitment (PBUC) problem. In a deregulated environment, generation companies (GENCOs) schedule their generators to maximize profits rather than to satisfy power demand. The PBUC problem is solved by the proposed approach in two stages. Initially, information concerning committed units is obtained by the IPPD table and then the subprob-lem of Economic Dispatch (ED) is solved using Muller's method. The proposed approach has been tested on a power system with 3 and 10 generating units. Simulation results of the proposed approach have been compared with existing methods and also with traditional unit commitment. It is observed from the simulation results that the proposed algorithm provides maximum profit with less computational time compared to existing methods.