• Title/Summary/Keyword: INTERPHASE

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Modern State of Models for Fundamental Adhesion - A Review Extended Abstract

  • Possart, Wulff
    • Journal of Adhesion and Interface
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    • v.3 no.1
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    • pp.43-51
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    • 2002
  • Advanced adhesive technologies and demanding applications of adhesive joints can no longer be developed successfully by the traditional "trial and error" approach. Appropriate technical solutions require reference to a reliable basis of well-established scientific knowledge about the elementary mechanisms of adhesion (i.e. the 'fundamental adhesion') as they are responsible for the capability of the compound w transmit mechanical force between the adhesive and the substrate surface (i.e. the 'practical adhesion'). Adhesion mechanisms also influence the formation of polymer structure in the adhesive and the resulting macromolecular dynamics in the interphase that is formed in the adhesive near to the substrate. These manifold molecular factors rule the macroscopic behaviour of an adhesive bond line in terms of mechanical and other physical properties as well as in terms of durability. This paper reviews the level of refinement that understanding of fundamental adhesion has achieved up to now.

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Two-phase flow and heat transfer characteristics in a submerged gas injection system (잠겨진 가스분사장치에서의 2상 유동 및 열전달 특성)

  • 최청렬;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.824-834
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    • 1999
  • Characteristics of two-phase flow and heat transfer were numerically investigated in a submerged gas injection system when temperature of the injected gas was different from that of the liquid. The Eulerian approach was used for both the continuous and dispersed phases. The turbulence in the liquid phase was modeled using the standard $k-\varepsilon$$\varepsilon$ turbulence model. The interphase friction and heat transfer coefficient were calculated from the correlations available in the literature. The turbulent dispersion of the phases was modeled by a "dispersion Prandtl number". In the case with heat transfer where the temperature of the injected gas is higher than the mean liquid temperature, the axial and the radial velocities are lower in comparison with the case of homogeneous temperatures. The results in the present research are of interest in the design and operation of a wide variety of material and chemical processes.

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Approximate Solutions for Laminar Film Condensation on a Flat Plate (평판에서 층류 막응축의 근사해)

  • Lee, S.H.;Kweon, J.Y.;Lee, E.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.4
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    • pp.215-221
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    • 1991
  • Laminar film condensation of a saturated vapor in forced flow over a flat plate is analyzed by using integral method. Laminar condensate film is so thin that the inertia and thermal convection terms in liquid flow can be neglected. Approximate solutions for water are presented and well agreed with the similarity solutions over the wide range of physical parameter, Cp1(Ts-Tw)/Pr.hfg. For the strong condensation case, it is found that magnitude of the interfacial shear stress at the liquid-vapor interphase boundary is approximately equal to the momentum transferred by condensation, i.e., ${\tau}_i{\simeq}\dot{m}(U_O-U_i)$.

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SW-VVVF System for High Efficiency Drive of Induction Motor (삼상 유도전동기의 고효율 운전을 위한 SW-VVVF 시스템에 관한 연구)

  • 유철로;이공희;이성룡
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.38 no.2
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    • pp.93-99
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    • 1989
  • This paper describes Sinusoidal Wave-Variable Voltage Variable Fequency (SW-VVVF) system for the high efficiency drive of a 3-phase induction motor. SW-VVVF system consists of a 3-phase 24-pulse converter and a SPWM inverter. The converter with additional 2 tap diode circuits in interphase reactor reduces harmonics in input current. The SPWM inverter consists of an improved PLL system and a V/F controller, which reduces harmonics in output current and performs a high efficiency algorithm by maintaining a constant slip frequency and compensating for the velocity variation of the induction motor with the change of load. Therefore, this system reduces harmonics in input and output currents, and also can drive an induction motor with high efficiency in an economical way. We have proved its utility through experiment.

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Local nanofiller volume concentration effect on elastic properties of polymer nanocomposites

  • Shin, Hyunseong;Han, Jin-Gyu;Chang, Seongmin;Cho, Maenghyo
    • Multiscale and Multiphysics Mechanics
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    • v.1 no.1
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    • pp.65-76
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    • 2016
  • In this study, an influence of local variation of nanoparticulate volume fraction on the homogenized elastic properties is investigated. It is well known that interface effect is dependent on the radius and volume fraction of reinforced nanofillers. However, there is no study on the multiscale modeling and analysis of polymer nanocomposites including polydispersed nanoparticles with consideration of interphase zone, which is dependent on the volume fraction of corresponding nanoparticles. As results of numerical examples, it is confirmed that an influence of local variation of nanoparticulate volume fraction should be considered for non-dilute system such as cluster of nanoparticles. Therefore representative volume element analysis is conducted by considering local variation of nanoparticle volume fraction in order to analyze the practical size of cell including hundreds of nanoparticles. It is expected that this study could be extended to the multiparticulate nanocomposite systems including polydispersed nanoparticles.

Actin-related protein BAF53 is essential for the formation of replication foci

  • Kwon, Su-Jin;Kwon, Hyock-Man
    • Animal cells and systems
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    • v.16 no.3
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    • pp.183-189
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    • 2012
  • It has been suggested that chromatin is organized into the stable structures that provide fundamental units of chromosome architecture in interphase mammalian cells. The stable structures of chromatin can be visualized as replication foci when replicating DNA is labeled with thymidine analogs. Previously, we showed that the chromosome territory expanded after BAF53 knockdown. In this study, we found that BAF53 is required for the formation of replication foci. DNA replication was not impaired in BAF53 knockdown cells, suggesting that the decrease in the number of replication foci is due to disintegration of replication foci, but not suppression of DNA replication. The attractive forces that maintain structural integrity of replication foci could be disrupted by BAF53 knockdown, and it may be responsible, at least in part, for the expansion of chromosome territories after BAF53 knockdown.

Isolation of Luteolin 7-O-rutinoside and Esculetin with Potential Antioxidant Activity from the Aerial Parts of Artemisia montana

  • Kim, Na-Mee;Kim, Jong;Chung, Hae-Young;Chol, Jae-Sue
    • Archives of Pharmacal Research
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    • v.23 no.3
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    • pp.237-239
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    • 2000
  • The antioxidant activity of Artemisia montana was determined by measuring the radical scavenging effect on 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical and inhibitory activity against free radical generation of hepatocytes ($AC_2$F). The methanol extract of A. montana showed strong radical scavenging activity at a concentration of $10.1{\mu}g/m{\ell}$, and thus fractionated by solvent extraction. Esculetin and luteolin 7-O-rutinoside (scolymoside) were isolated as the active principles from the EtOAc and interphase fractions, respectively. The antioxidant activity of these compounds were comparable to that of L-ascorbic acid.

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A micromechanics-based time-domain viscoelastic constitutive model for particulate composites: Theory and experimental validation

  • You, Hangil;Lim, Hyoung Jun;Yun, Gun Jin
    • Advances in aircraft and spacecraft science
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    • v.9 no.3
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    • pp.217-242
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    • 2022
  • This paper proposes a novel time-domain homogenization model combining the viscoelastic constitutive law with Eshelby's inclusion theory-based micromechanics model to predict the mechanical behavior of the particle reinforced composite material. The proposed model is intuitive and straightforward capable of predicting composites' viscoelastic behavior in the time domain. The isotropization technique for non-uniform stress-strain fields and incremental Mori-Tanaka schemes for high volume fraction are adopted in this study. Effects of the imperfectly bonded interphase layer on the viscoelastic behavior on the dynamic mechanical behavior are also investigated. The proposed model is verified by the direct numerical simulation and DMA (dynamic mechanical analysis) experimental results. The proposed model is useful for multiscale analysis of viscoelastic composite materials, and it can also be extended to predict the nonlinear viscoelastic response of composite materials.

Properties of Capacity on Carbon Electrode in EC:MA Electrolytes - I. Effect of Mixing Ratio on the Electrochemical Properties - (EC:MA 혼합전해질에서 카본 전극의 용량 특성 - I. 전기화학적 특성에 대한 혼합비의 영향 -)

  • Park, Dong-Won;Kim, Woo-Seong;Son, Dong-Un;Kim, Sung-Phil;Choi, Yong-Kook
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.183-187
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    • 2006
  • The choice of solvents for electrolytes solutions is very important to improve the characteristics of charge/discharge in the Li-ion battery system. Such solvent systems have been widely investigated as electrolytes for Li-ion batteries. In this paper, the electrochemical properties of the solid electrolyte interphase film formed on carbon anode surface and the solvent decomposition voltage in 1 M LiPF6/EC:MA(x:y) electrolyte solutions prepared from the various mixing volume ratios are investigated by chronopotentiometry, cyclic voltammetry, and impedance spectroscopy. As a result, the solvent decomposition voltages are varied with the ionic conductivity of the electrolyte. Electrochemical properties of the passivation film were different, which are dependent on the mixture ratio of the solvents. Therefore, the most appropriate mixing ratio of EC and MA as a solvent in 1 M $LiPF_6/(EC+MA)$ system for Li-ion battery is approximately 1:3 (EC:MA, volume ratio).

Effects of Lithium Bis(Oxalate) Borate as an Electrolyte Additive on High-Temperature Performance of Li(Ni1/3Co1/3Mn1/3)O2/Graphite Cells (LiBOB 전해액 첨가제 도입에 따른 Li(Ni1/3Co1/3Mn1/3)O2/graphite 전지의 고온특성)

  • Jeong, Jiseon;Lee, Hyewon;Lee, Hoogil;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.58-67
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    • 2015
  • The effects of electrolyte additives, lithium bis(oxalate)borate (LiBOB), fluoroethylene carbonate (FEC), vinylene carbonate (VC), 2-(triphenylphosphoranylidene) succinic anhydride (TPSA), on high-temperature storage properties of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite are investigated with coin-type full cells. The 1 wt.% LiBOB-containing electrolyte showed the highest capacity retention after high temperature ($60^{\circ}C$) storage for 20 days, 86.7%, which is about 5% higher than the reference electrolyte, 1.15M lithium hexafluorophosphate ($LiPF_6$) in ethylene carbonate/ethyl methyl carbonate (EC/EMC, 3/7 by volume). This enhancement is closely related to the formation of semi-carbonate compounds originated from $BOB^-$ anions, thereby resulting in lower SEI thickness and interfacial resistance after storage. In addition, the 1 wt.% LiBOB-containing electrolyte also exhibited better cycle performance at 25 and $60^{\circ}C$ than the reference electrolyte, which indicates that LiBOB is an effective additive for high-temperature performance of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite chemistry.