• Title/Summary/Keyword: II-VI

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Effect of Saliva Contamination Stage and Different Decontamination Procedures on Bonding Strength of Resin-Modified Glass Ionomer (레진강화형 글라스아이오노머의 초기 결합력과 타액오염 제거의 상관관계)

  • Go, Hanho;Park, Howon;Lee, Juhyun;Seo, Hyunwoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.46 no.2
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    • pp.158-164
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    • 2019
  • The purpose of this study was to compare the bond strength of resin-modified glass ionomer (RMGI) to dentin with saliva contamination at different stages and using different decontamination procedures. Extracted human permanent molars were embedded onto acrylic resin with the dentin surface exposed. Group I was a control group that was conditioned with polyacrylic acid (PAA). Groups II and III were contaminated with saliva before PAA conditioning and Groups IV, V, and VI were contaminated with saliva after PAA conditioning. After saliva contamination, Groups II and IV were dried, Groups III and V were rinsed and dried, and Group VI was additionally conditioned with PAA. After surface treatment, the dentin specimens were filled with RMGI. Group I showed significantly higher bond strength than the other groups. Group VI showed a significantly higher bond strength than the other saliva contaminated groups. However, there were no significant differences in the failure mode between the different groups. Saliva contamination impaired the bond strength of RMGI to dentin, regardless of when the saliva contamination occurred. Decontamination with washing and drying could not improve the shear bond strength of RMGIC. When saliva contamination occurred after PAA conditioning, additional PAA conditioning improved the shear bond strength.

Adsorption of Co(II), Ni(II), Pb(II) and U(VI) from Aqueous Solutions using Polyaniline/Graphene Oxide Composites

  • Liu, Zhengjie;Yang, Jianwei;Li, Changzhen;Li, Jiaxing;Jiang, Yajuan;Dong, Yunhui;Li, Yueyun
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.781-788
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    • 2014
  • Polyaniline modified graphene oxide (PANI/GO) composites were synthesized by dilute polymerization technique and were characterized by Fourier transformed infrared spectroscopy (FTIR), Raman spectroscopy, and scanning electron microscopy (SEM). The characterization results indicated that polyaniline molecules were successfully grafted on GO surfaces. The application of PANI/GO composites to the adsorption of heavy metals from aqueous solutions was investigated under ambient conditions. The maximum adsorption capacities of Co(II), Ni(II), Pb(II) and U(VI) ions on PANI/GO composites calculated from Langmuir models are 22.28, 25.67, 65.40 and 1552.31 mg/g, respectively. The excellent adsorption capacity suggests that PANI/GO composites can be applied as a promising adsorbent in heavy metal pollution cleanup in environmental pollution management.

Adsorption of Hg(I), Pb(II), and U(VI) ions using from Fruits of Schizandra Chinensis (오미자를 이용한 Hg(I), Pb(II), U(VI) 이온들의 흡착)

  • Kim, Kwan-Chun;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.29-35
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    • 2007
  • This study was examined adsorption ability of heavy metal Hg(I), Pb(II), and U(Vl) ion use of fruit from schizandra chinensis, The fruits of schizandra chinensis sample used breaking into fragments $50{\sim}100$ mesh. The sample solution was mixed fruits of schizandra chinensis and heavy metal ion. Each heavy metal ion of into solution was quantum analysis with ICP-AES. As the result, each condition of maxium adsorption ability of heavy metal ion was high in the range of pH 5-7, adsorption time was about 15 minutes, and the optimum temperature was $100^{\circ}C$. The heavy metal ion was increased adsorption in order of increasing concentration and in ethanol solution better than in aqueous solution.

복합오염물질 처리를 위한 Hybrid PRB System

  • 김상태;강완협;문희선;민지은;조종수;박주양;김재영;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.129-132
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    • 2004
  • A hybrid permeable reactive barriers(hybrid PRBs) composed of Fe(II) PRB, biological PRB and sorptive PRB was investigated to treat groundwater with multiple contaminations. We performed batch, column and pilot tests to determine removal rates and design parameters of each PRB media, and operated two hybrid PRB systems with pilot-scale barriers in series. The pilot test of the hybrid PRB system with the combination of Fe(II), biological media and black shale showed multiple contaminations could be removed in ground water. Nitrate could be treated below 20 mg/L and Cr(VI) was treated down to 0.05 mg/L. TCE was degraded below 0.001 mg/L in system. The hybrid PRB system with a proper combination of PRBs could remediate ground water with multiple contaminations.

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Metal-Organic Vapor Phase Epitaxy : A Review II. Process and charactristics (MOVPE 단결정층 성장법 II. MOVPE공정 및 특징)

  • 정원국
    • Journal of Surface Science and Engineering
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    • v.23 no.2
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    • pp.1-10
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    • 1990
  • Metal-Organic Vapor Phase Epitaxy (MOVPE) is an epitaxial process utilizaing ane or more of organometallice as reactnte to grow compound semicond semiconductror layers. MOVPE is basically a cold wall process in which reactants are delivered without reacting with each other to the heated substrate where reactants are thermally decomposed to from compound semiconductors through chemical reaction. Since reactants are delivered as gas phase and the formation of the single crystal compunds depends on the thermal decomposition of the reactants, details of MOVPE relies on the hydrodynamics and pyroltsis and chemical reation of reactants inside on reaction chamber. It has been demonstrated that MOVPE is capable of growing virtually all of the III-V, II-VI and IV-VI compound semiconductrs, fabricating ultrathin epilayers, for ming abrupt hetrointerfaces with monolayer transition width, and is suitable for multi-wafer operation yilding a high throghtput. Overiew of reactror componts and layer, characteristics, and status of MOVPE are discussed.

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Silver Ores and Fluid Inclusions of the Cheolam Silver Deposits (철암은광상(鐵岩銀鑛床)의 광석(鑛石)과 유체포유물(流體包有物))

  • Park, Hee-In;Woo, Young-Kyun;Bae, Young Boo
    • Economic and Environmental Geology
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    • v.20 no.1
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    • pp.1-18
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    • 1987
  • The Cheolam silver deposits are emplaced along the fractures in breccia dike and the Hongjesa granite. Breccia dike contains fragments of late Cretaceous acidic volcanic rocks and other fragments of various rocks distributed in the mine area. Therefore it is presumed that the mineralization was taken place in later than late Cretaceous time. Mineral paragenesis is complicated by multiple episodes of fracturing. Six distinct depositional stages can be recognized: stage I, deposition of base metal sulfides; stage II, deposition of base metal sulfides and silver minerals; stage III, deposition of carbonates; stage IV, deposition of silver minerals and base metal sulfides; stage V, deposition of silver minerals; stage VI, deposition of barren quartz. Silver minerals from the deposits are native silver, acanthite, pyrargyrite, argentian tetrahedrite, stephanite, polybasite, pearceite, allargentum, antimonial silver and electrum. Fluid inclusion studies ware carried out for stage I, II, IV and VI quartz and stage III calcite. Homogenization temperatures for each stage are as follows: stage I, from $225^{\circ}$ to $360^{\circ}C$; stage II, from $145^{\circ}$ to $220^{\circ}C$; stage III, from $175^{\circ}$ to $240^{\circ}C$; stage IV, from $130^{\circ}$ to $185^{\circ}C$; stage VI, from $120^{\circ}$ to $145^{\circ}C$. Salinities of ore fluids were in the range of 4 and 10 wt.% equivalent NaCl over stage I and stage VI. Ore mineralogical data of each stage indicate that temperatures are within the range of homogenization temperature of fluid inclusions and sulfur fugacities declined steadily from $10^{-9.7}atm$. to $10^{-18.7}atm$. through stage I into stage V.

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Influence of Iron Phases on Microbial U(VI) Reduction

  • Lee, Seung-Yeop;Baik, Min-Hoon;Lee, Min-Hee;Lee, Young-Boo;Lee, Yong-Jae
    • Journal of Soil and Groundwater Environment
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    • v.16 no.6
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    • pp.58-65
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    • 2011
  • The bacterial uranium(VI) reduction and its resultant low solubility make this process an attractive option for removing U from groundwater. An impact of aqueous suspending iron phase, which is redox sensitive and ubiquitous in subsurface groundwater, on the U(VI) bioreduction by Shewanella putrefaciens CN32 was investigated. In our batch experiment, the U(VI) concentration ($5{\times}10^5M$) gradually decreased to a non-detectable level during the microbial respiration. However, when Fe(III) phase was suspended in solution, bioreduction of U(VI) was significantly suppressed due to a preferred reduction of Fe(III) instead of U(VI). This shows that the suspending amorphous Fe(III) phase can be a strong inhibitor to the U(VI) bioreduction. On the contrary, when iron was present as a soluble Fe(II) in the solution, the U(VI) removal was largely enhanced. The microbially-catalyzed U(VI) reduction resulted in an accumulation of solid-type U particles in and around the cells. Electron elemental investigations for the precipitates show that some background cations such as Ca and P were favorably coprecipitated with U. This implies that aqueous U tends to be stabilized by complexing with Ca or P ions, which easily diffuse and coprecipitate with U in and around the microbial cell.

Separation and Purification of Soybean $\beta$-amylase Isozymes (대두 $\beta$-amylase Isozyme의 분리 및 정제)

  • 지의상
    • The Korean Journal of Food And Nutrition
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    • v.3 no.2
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    • pp.149-160
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    • 1990
  • The soybean $\beta$-amylase ($\alpha$-1, 4-glucan maltohydrolase, EC 3.2.1.2) is composed of seven isozymes(I', I, II, III, IV, V and VI), and isozyme II and IV are the main components among these. The Purification of $\beta$-amylase isozymes from soybean whey were performed by ammonium sulfate fractionation, CM-Sephadex C-50 column chromatography, DEAE-Sephadex chromatography and Gel filtration. The resulted purity of $\beta$-amylase was throughly confirmed by electrophoresis, and then determined its isoelectric point and molecular weight. The results obtained were as follows, 1. Five active fractions of soybean p-amylase were derived on CM-Sephadex C-50 column chromatography. 2. Seven active bands of p-amylase isozymes were detected by isoelectric focusing gel electrophoresis, and their isoelectric points(I' to VI) were 5.07, 5.15, 5.25, 5.40, 5.55, 5.70 and 5.93, respectively. 3. Isozyme II and IV were main components of soybean $\beta$-amylase. 4. The molecular weights of both isozyme II and IV were determined to be 56,000 daltons by the result of SDS polyacrylamide gel electrophoresis. 5. Km values of main isozyme II & IV for amylopectin were determined to be 2.25 mg/ml, which suggest the same function of each isozyme.

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A Study on Court Dress and Its Ornaments of the Armed Vassals [I] - In Koryo Dynasty, when they attend the "Bopka", King while he is conducting his business - (위장종관(衛仗從官)의 복식(服飾)에 관한 연구(硏究)[I] - 고려대(高麗代) "법가(法駕)" 위장(衛仗)을 중심(中心)으로 -)

  • Im, Myung-Mi
    • Journal of the Korean Society of Costume
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    • v.5
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    • pp.103-112
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    • 1981
  • In Koryo Dynasty, during the reign of uijong, Choe Yun-ui and others countries collected the royal orders of the Koryo kings and adopted the Tang institutions, and compiled 50 volumes of a book, called "Detailed Ceremonies of Old and New." Recording about clothing, with a special focus on dress and its ornaments of armed vassals, when they attend the king while he is conducting his business. 1) As for the headgear's were the Pokdu, Moja, Kwan, Tumo (official hat to be worn with armors) and Malye (for protection against the cold). There were II kinds of headgear's name in all. 2) As for the clothes, (1) Kongbok (formal costume) (2) Dress, there were 34 kinds of clothes name differented by (i) flowerage on clothes (ii) size of sleeves (iii) color of clothes (iv) fabrics (v) the belt used with the dress. Others were; (3) Baeja (4) Hansam, (5) Poto, and (6) Armor. 3) As for colors of clothes, there were (i) Purple, (ii) Red(Scarlet), (iii) Green, (iv) Blue, (v) Yellow, (vi) Black and (vii) White. 4) As for materials, there were (i) Kum, Ra, Sa (all kinds of silk), (ii) Iron and (iii) Leather. 5) For belts, there were (i) Sockdae, (ii) Hongjung, (iii) Kayeundae, (iv) Dongdokum-dae, (v) Jojung and (vi) Dongshimsokdae.

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Adsorption Properties of Uranium on Acrylic Fibers Treated with Hydroxylamine (하이드록실 아민으로 처리한 아크릴 섬유의 우라늄 흡착특성)

  • Chin Young Gil;Lee Jung Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.2
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    • pp.98-103
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    • 1990
  • Fibrous adsorbents containing amidoxime group which make chelate complexes with uranyl ions are studied for the recovery of uranium from sea water. Acrylic fibers are used as base Polymer. The adsorption properties of uranium are carried out to examine pH effect, concen-tration dependence, adsorption rate, separation, and chelate complex. The results obtained are as follows; 1. Metal capacity of U (VI) ion is in the range of pH $2\~10.2$. Amidoxime group-containing fiber recover U (VI) ions existed in sea water or waste water in extremely small quantities. 3. Using amidoxime group-containing fiber Cu (II) and U (VI) are separated with each other in dilute nitric acid solution (pH 2.3). 4. U (VI) chelate complexes are conformed by tridendate ligands, which are coordinated with one nitrogen and two oxygens onto amidoxime group-containing fiber.

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