• Title/Summary/Keyword: II-VI

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Synthesis of InP Nanocrystal Quantum Dots Using P(SiMe2tbu)3

  • Jeong, So-Myeong;Kim, Yeong-Jo;Jeong, So-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.533-534
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    • 2012
  • Colloidal III-V semiconductor nanocrystal quantum dots (NQDs) have attracted attention as they can be applied in various areas such as LED, solar cell, biological imaging, and so on because they have decreased ionic lattices, lager exciton diameter, and reduced toxicity compared with II-VI compounds. However, the study and application of III-V semiconductor nanocrystals is limited by difficulties in control nucleation because the molecular bonds in III-V semiconductors are highly covalent compared to II-VI compounds. There is a need for a method that provides rapid and scalable production of highly quality nanoparticles. We present a new synthetic scheme for the preparation of InP nanocrystal quantum dots using new phosphorus precursor, P(SiMe2tbu)3. InP nanocrystals from 530nm to 600nm have been synthesized via the reaction of In(Ac)3 and new phosphorus precursor in noncoordinating solvent, ODE. This opens the way for the large-scale production of high quality Cd-free nanocrystal quantum dots.

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A Study on the Classification of the Somatotype of Korean Females (실루엣에 의한 한국여성의 체형분석)

  • Nam Yun Ja;Lee Soon Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.8 no.1
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    • pp.47-56
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    • 1984
  • The purpose of this study was to classify somatotype and to investigate the 15 measurements for the clothing construction. The size of sample was 467 females between age 6 and 60. Analysis of Variance (ANOVA) was employed to analyze the 15 measurements by group and somatotype. The results of the study were as follows; 1) All the measurements were significantly different among the groups except the Vertebralis angle. 2) Concerning the upper part of the body, Standard somatotype was found more frequently in group IV. V compared with the other, Turning over somatotype in group I. II, Bending somatotype in group VI. VII. VIII. Concerning the under part of the body Standard somatotype was found more frequently in group IV. V. VI. VII. VIII. compared with the other, Forward-turning over somatotype of the lower help body and Turning over somatotype in group I. II. III. when the upper part of the body was turning over somatotype, the under part of the body was generally Turning over somatotype or Forward-turning over somatotype. When the upper part of the body was Bending somatotype, the under part of the body was commonly Forward somatotype.

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Neutronics analysis of TRIGA Mark II research reactor

  • Rehman, Haseebur;Ahmad, Siraj-ul-Islam
    • Nuclear Engineering and Technology
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    • v.50 no.1
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    • pp.35-42
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    • 2018
  • This article presents clean core criticality calculations and control rod worth calculations for TRIGA (Training, Research, Isotope production-General Atomics) Mark II research reactor benchmark cores using Winfrith Improved Multi-group Scheme-D/4 (WIMS-D/4) and Program for Reactor In-core Analysis using Diffusion Equation (PRIDE) codes. Cores 133 and 134 were analyzed in 2-D (r, ${\theta}$) and 3-D (r, ${\theta}$, z), using WIMS-D/4 and PRIDE codes. Moreover, the influence of cross-section data was also studied using various libraries based on Evaluated Nuclear Data File (ENDF/B-VI.8 and VII.0), Joint Evaluated Fission and Fusion File (JEFF-3.1), Japanese Evaluated Nuclear Data Library (JENDL-3.2), and Joint Evaluated File (JEF-2.2) nuclear data. The simulation results showed that the multiplication factor calculated for all these data libraries is within 1% of the experimental results. The reactivity worth of the control rods of core 134 was also calculated with different homogenization approaches. A comparison was made with experimental and reported Monte Carlo results, and it was found that, using proper homogenization of absorber regions and surrounding fuel regions, the results obtained with PRIDE code are significantly improved.

Fabrication and Physical Properties of Heterojunction Solar Cell (II-VI) of $n-Cd_{1-x}Zn_xS/p-Si$ (이종접합 태양전지 (II-VI)의 제작과 물성에 대한 연구($n-Cd_{1-x}Zn_xS/p-Si$ 태양전지를 중심으로))

  • Lee, Soo-Il;Kim, Byung-Chul;Seo, Dong-Joo;Choi, Seong-Hyu;Hong, Kwang-Joon;You, Sang-Ha
    • Solar Energy
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    • v.8 no.1
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    • pp.41-48
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    • 1988
  • Heterojunction solar cells of $n-Cd_{1-x}Zn_xS/p-Si$ were fabricated by solution growth technique. The crystal structure, spectral response, surface morphology, and I-V characteristics of the $n-Cd_{1-x}Zn_xS/p-Si$ heterojunction solar cells were studied. The $Cd_{1-x}Zn_xS$ layer deposited on a silicon substrate (111) were found to be a cubic structure with the crystal orientation (111), (220) of the CdS and to be a hexagonal structure with crystal orientation (100) of the ZnS. The open-circuit voltage, short-circuit current, fill factor, and conversion efficiency of $n-Cd_{1-x}Zn_xS/p-Si$ heterojunction solar cell under $100mW/cm^2$ illumination were found to be 0.43V, 38mA. 0.76, and 12.4%, respectively.

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Antimicrobial Activities of the Lignans from Abies koreana Wilson (구상나무 리그난류의 항균활성)

  • Kim, Yun-Geun;Jo, Jong-Soo;Moon, Chang-Kuck
    • Korean Journal of Food Science and Technology
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    • v.31 no.1
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    • pp.260-262
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    • 1999
  • Abies koreana Wilson is a proper tree to Korea. We tested the antimicrobial activity of the lignans isolated from it. The lignans inhibited the growth of Klebsiella pneumoniae and Vibrio parahaemolyticus at the concentration of $10^3\;ppm\;and\;10^4\;ppm$. Especially, the compound V showed higher inhibition activity to Vibrio parahaemolyticus by 1.7 times compared with the control. The compound III showed activity of 36% of the control to Klebsiella pneumoniae. The compounds II and VI had the high growth inhibition activity of 48, 66% respectively to Vibrio parahaemolyticus.

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Multivariate Analysis of Variation of Growth and Quality Characteristics in Colored Rice Germplasm (유색미 도입 유전자원의 생육 및 품질특성 변이 다변량 분석)

  • Park, Jong-Hyun;Lee, Ji-Yoon;Chun, Jae-Buhm;You, Oh-Jong;Son, Eun-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.63 no.3
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    • pp.175-185
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    • 2018
  • The aim of this study was to evaluate the variation of growth and quality characteristics in colored rice from 178 accessions and to develop useful, basic rice breeding data by classifying these germplasm characteristics via principal component (PC) analysis. The coefficient of variation of the 178colored rice accessions were the highest for panicle length (PL) and protein contents, followed by length-width ratio (LWR), 1000-grain weight (TGW), culm length (CL), and amylose contents, whereas the lowest was for the number of panicles per hill (NP), which is a yield component. The results from the PC analysis exhibited eigenvalues and contributions respective to each PC as follows: PC1, 2.06 and 29.49%; PC2, 1.31 and 18.75%; PC3, 1.21 and 17.36%; PC4, 1.01 and 14.38%. The eigenvalues of four PCs were over 1.0, and their cumulative contributions were 79.98%, which completes the necessary condition for evaluation of the 178 colored rice accessions. Cluster analysis showed cluster I as the largest, which included 79 accessions, while clusters II, III, IV, V, VI, and VII comprised 46, 19, 13, 4, 8, and 9 accessions, respectively. Moreover, dark brown accessions were dispersed in clusters I and II, and many resources of purple seed coat color were found in clusters V, VI, and VII. Particularly, cluster V had resources of only black and purple seed coat colors. Resources of cluster VII were found to have a relatively small average CL, PL, and LWR; notably, cluster V had the smallest average TGW, and cluster IV the lowest NP but the highest TGW. Finally, considering the yield potential, growth characteristics, heading stage, and color during breeding of colored rice, we obtained the following conclusions: cluster VII is suitable for breeding of colored rice; cross breeding among clusters I, II, and VII has a high yield potential; and it is possible to produce a superior color by cross breeding plants from cluster V and VI.

ZnTe 완충층 두께에 따른 CdTe/ZnTe 양자점의 운반자 동역학

  • Kim, Su-Hwan;Lee, Ju-Hyeong;Choe, Jin-Cheol;Lee, Hong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.305-305
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    • 2014
  • 양자점(Quantum dots)은 3차원적 운반자 구속과 낮은 전류와 높은 온도에서 작동하는 나노 크기의 전기적, 광학적 소자로 응용이 적합하기 때문에 그 특성을 이용한 단전자 트랜지스터, 적외선 검출기, 레이저, LED, 태양전지 등 반도체 소자로의 응용연구가 활발히 진행되고 있다. 특히 양자점의 낮은 임계전류밀도와 높은 차동 이득(differential gain), 그리고 고온에서 작동이 용이하여 양자점 레이저로 활용되고 있다. 이러한 분야에 양자점을 응용하기 위해서는 양자점의 운반자 동역학을 이해하고 양자점의 모양, 크기, 크기 분포와 같은 특성 조절이 필요하다. 또한 기존의 연구들은 III-V족 화합물 반도체 양자점에 대한 연구가 대부분이며, II-VI족으로 구성된 연구가 미흡한 상황이기 때문에 II-VI족 화합물 반도체 양자점에 대한 많은 연구가 필요한 상황이다. II-VI 족 화합물 반도체 양자점은 기존의 III-V 족 양자점보다 더 큰 엑시톤 결합에너지(exciton binding energy)를 가지고 있으며, 이러한 특성을 가지는 II-VI 족 화합물 반도체 양자점 중에서도 CdTe 양자점은 높은 엑시톤 결합에너지와 녹색 스펙트럼 영역을 필요로 하는 광학적 장치들에 응용 가능성이 높기 때문에 더욱 주목받고 있다. 본 연구에서는 분자 선속 에피 성장법(Molecular Beam Epitaxy; MBE)과 원자 층 교대 성장법(Atomic Layer Epitaxy; ALE)으로 CdTe/ZnTe 나노구조에서 ZnTe 완충층의 두께에 따른 운반자 동역학 및 광학적 특성을 연구 하였다. 저온 광루미네센스 측정(Photoluminescence; PL) 을 통하여 ZnTe 완충층 두께가 증가할수록 양자점의 광루미네센스 피크가 낮은 에너지로 이동함을 알 수 있었는데, 이는 ZnTe 완충층의 두께가 증가할수록 ZnTe 완충층과 CdTe 양자점의 격자 불일치(lattice mismatch)로 인한 구조 변형력이 감소하고 이에 따라 CdTe 양자점으로 가해지는 변형(Strain)이 감소하여 CdTe 양자점의 크기가 증가했기 때문이다. 그리고 ZnTe 완충층의 두께가 증가할수록 PL 세기가 증가함을 알 수 있었는데, 이는 ZnTe 완충층의 두께가 증가할수록 양자 구속 효과로부터 electronic state와 conduction band edge 사이의 에너지 차이의 증가 때문이다. 또한 시분해 광루미네센스 측정 결과 ZnTe의 두께가 증가할수록 양자점의 소멸 시간이 더 길게 측정되었는데, 이는 더 큰 양자점 일수록 엑시톤 오실레이터 강도가 감소하기 때문에 더 긴 소멸 시간을 나타내는 것을 확인할 수 있었다. 결과적으로 본 연구는 ZnTe 두께 변화를 통해 양자점의 에너지 밴드를 제어할 수 있으며, 양자점의 효율 향상을 할 수 있는 좋은 방법임을 제시하고 있다.

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Antimicrobial Activities of Hydroxybiphenyl Derivatives (II) - Synthesis and Antibacterial Activities of Allylhydroxybiphenyl Compounds against a Cariogenic Bacterium Streptococcus mutans ATTCC OMZ176

  • Seo, Won-Jun;Koo, Sung-Hyen;Bae, Ki-Hwan
    • Archives of Pharmacal Research
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    • v.9 no.3
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    • pp.127-130
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    • 1986
  • Naturally occurring diallyldihydroxybiphenyl compounds, magnolol and honokiol were reported to have potent antibacterial activities against most of Gram positive bacteria (1-4). To developmore potent antibacterial agents, some allyhydroxybiphenyl derivatives were synthesized from the starting compounds, p-phenyl-phenol (I) p-phenylphenol (IV), o, o-biphenol (VII) and p. p'-biphenol (XII). Among the newly synthesized compounds (III, VI, IX, XI, XIV and XVI), the antibacterial activities of 2-allyl-p-phenylphenol (VI), 6-ally-o, 0'-biphenol (IX), 2, 2'-diallyl-o, o'-biphenol (XIV) and 2, 2', 6-triallyl-p, p'-biphenol (XIV) were more potent than those of magnolol and bonokiol against a cariogenic bacterium, Stroptococcus matans ATCC OMZ 176.

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Synthesis of Higenamine, A Cardiotonic Principle of Aconite Root

  • Chang, Ki-Churl;Choi, Sook-Yun;Lim, Jung-Kyoo;Park, Chan-Woong
    • Archives of Pharmacal Research
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    • v.7 no.2
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    • pp.133-136
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    • 1984
  • Higenamine (I), cardiotonic principle of Aconite root, was synthesized from 4-methoxy-phenylacetic acid (II) and .betha.-(3, 4-dimethoxyphenyl)-ethylamine (IV). Condensation of IV with 4-mehoxyphenylacetyl chloride (III) was followed by cyclodehydration yielding 1-(4'-methoxybenzyl)-6, 7- dimethoxy-3, 4-dihydroisoquinoline (VI). Reduction of VI to 1, 2, 3, 4-tetrahydroisoquinoline (VII) and subsequent demethylation provided desired product higenamine, 1-(4'-hydroxybenzyl)-6, 7- dihydroxy-1, 2, 3, 4, -tetrahydroisoquinoline.

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Adsorption of Uranium Ion Utilizing OenNtn-Styrene-DVB Resin (OenNtn-스틸렌-DVB 수지를 이용한 우라늄(VI) 이온의 흡착)

  • 김준태;노기환;강영식
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.9-15
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    • 2003
  • Resins have been synthesized from chlormethyl styrene 1,4- divinylbenzene(DVB) with 1%, 4%, and 20%-crosslinked and macrocyclic ligand of cryptand type by copolymerization method and the adsorption of uranium(VI), nickel(II) and lutetium(III) ions have been investigated in various experimental conditions. The correlation between the adsorption characteristics of rare earths and transition metal on the resins and stability constants of complexes with macrocyclic ligand have been examined. The uranium ion was not adsorbed on the resins below pH 2.0, but the power of adsorption of uranium ion increased rapidly above pH 3.0. The adsorption power was in the order of 1%, 4% and 20%-crosslinked resin, but adsorptive characteristics of resins decreased in proportion to the order of dielectric constants of solvents.