• 제목/요약/키워드: I-V polarization

검색결과 120건 처리시간 0.029초

이상계 스테인레스 강 용접부의 인성과 내식성 거동 (Property differences between GTAW and SMAW duplex stainless steel weld metal)

  • 백광기;김희진;안상곤
    • Journal of Welding and Joining
    • /
    • 제4권3호
    • /
    • pp.58-71
    • /
    • 1986
  • Mechanical and corrosion property of duplex stainless steel weldments made by the GTAW and SMAW process were studied. Fracture toughness, general and local corrosion resistance of GTAW and SMAW weldments were evaluated in terms of Charpy V notch impact test, anodic polarization diagram, pitting corrosion rate, respectively. SMA weld metal showed much lower impact toughness and higher ductile-brittle transition temperature than GTA weld metal. Fractographic and EDX analysis on fracture surface of SMA weld metal demonstrated the existence of (Si, Ti), oxide in large amounts. Potentiodynamic anodic polarization diagram of GMA weld metal showed much lower passive current density than SMA weld metal in 4% $H_2/SO_4$ solution. And pitting corrosion rate test showed the same tendency. Relating the microstructure, chemistry and property, it can be concluded that GTA weld metal gives better toughness due to lower oxygen content, i.e. lower inclusion content, and better corrosion resistance due to higher Pitting Index(PI) than SMA weld metal.

  • PDF

Fatigue characteristics of $Pb(Zr,Ti)O_3$ capacitors on donor doping

  • Yang, Bee Lyong
    • 열처리공학회지
    • /
    • 제15권3호
    • /
    • pp.113-117
    • /
    • 2002
  • Fatigue characteristics of ferroelectric $Pb(Zr,Ti)O_3$ (PZT) based capacitors through donor doping is reported in this paper. La substitution up to 10% were carried out to study systematically the fatigue behaviors of epitaxial ferroelectric capacitors grown on Si using $(Ti_{0.9}Al_{0.1})N/Pt$ conducting barrier composite. Ferroelectric capacitors substituted with 10% La show sufficient low voltage switched polarization and fatigue free performance. Systematic decrease in the tetragonality of the ferroelectric phase (i.e., c/a ratio) results in the corresponding reduction in coercive voltage, sufficient remnant polarization at 1.5-3V, and good fatigue property.

호핑법에 의한 이온 공간전하 분극 열자극전류의 수치해석 (Numerical analysis of thermally stimulated current due to lonic space charge polarization by hopping method)

  • 김의균;국상훈
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제4권1호
    • /
    • pp.53-64
    • /
    • 1991
  • 절연체중에 있는 하전입자의 거동은 절연재료의 특성에 많은 영향을 준다. 본 연구에서는 호핑모델에 의한 수치해석법을 TSC특성과 쌍극자분극에 대한 TSC특성은 차이가 있었다. 실험과 대응시켜 가동이온에 관한 물성정수의 평가를 하였다. 호핑모델에 의해서 불포화 TSC와 I-V특성의 수치계산을 하였다.

  • PDF

Hopping 모델에 의한 이온 공간전하분극 숙련재전류의 수치해석 (Numerical Analysis of Thermally stimulated current of Ionic Space charge Polarijation by Hopping Model)

  • 김의균;국상훈
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1990년도 추계학술대회 논문집
    • /
    • pp.91-94
    • /
    • 1990
  • The behavior of charged particle in dielectrics have a many effects on characteristics of the insulating materials. In this paper, numerical analysis method by hopping model was investigated application of TSC. As the results, there was a difference between characteristics of TSC by dipole polarization. Physical constant of movable ion corresponding to the experimental results was evaluated and also. Numerical calculations of unsaturated TSC and I-V characteristics were carried out by was of hopping model.

솔-젤법으로 제조한 PZT박막의 유전 및 전기적 특성 (Dielectric and electric properties of sol-gel derived PZT thin Films)

  • 홍권;김병호
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제9권3호
    • /
    • pp.251-258
    • /
    • 1996
  • Sol-Gel derived ferroelectric Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_{3}$ thin films have been fabricated on Pt/Ti/ $SiO_{2}$/Si substrate. Two kinds of fast annealing methods, F-I (six times of intermediate and final annealing) and F-II(one final annealing after six times of intermediate annealing) were used for preparation of multi-coated PZT thin films. As the annealing temperature was increased, high capacitance could be obtained, for instance, 2700.angs.-thick PZT thin film annealed at 680.deg. C had a capacitance value of approximately 20nF at 1kHz. In addition, it is found that the dielectric constant is a function of the perovskite phase fraction. In case of F-I method, PZT thin film had a remanent polarization(Pr) of 8-15.mu.C/c $m^{2}$ and a coercive field( $E_{c}$) of 35-44kV/cm according to annealing temperature, whereas PZT film fabricated by F-II method had as high as 24-25.mu.C/c $m^{2}$ and 48-59kV/cm, respectively. As a result of measuring Curie temperature, PZT thin film had a range of 460-480.deg. C by F-I method and more or less higher range of 525-530.deg. C by F-II method, which implied that different microstructures could cause the different Curie temperature. Through I-V measurement, leakage current of PZT thin film fabricated by F-I and F-II methods was 64nA/c $m^{2}$ and 2.2.mu.A/c $m^{2}$ in the electric field of 100kV/cm, respectively.y.y.y.

  • PDF

절연파괴시험을 통한 3.3kV 유도전동기의 절연특성 연구 (A study on insulation characteristics with AC Breakdown Test for Stator Winding of 3.3kV class Induction Motor)

  • 이동근;이광호;최교남;김현일;곽희진;오봉근
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
    • /
    • pp.2118-2122
    • /
    • 2005
  • This test was performed to assess the corelation of insulation deterioration condition with breakdown voltage of the stator winding of 3.3kV class induction motors which have been in service for 10 years after being installed in 1993. The insulation diagnostic tests include resistance, polarization index(P.I), dissipation factor$({\Delta}tan{\delta})$, maximum partial discharges (Qmax) and AC breakdown test. we evaluated the corelation of insulation diagnostic test with AC breakdown test for stator wilding of high voltage induction motor.

  • PDF

$Bi_{3.25}Eu_{0.75}Ti_3O_{12}$ 박막의 구조 및 강유전 특성에 미치는 $LaNiO_3$전극의 영향 (Effect of $LaNiO_3$ electrodes on Structural and Ferroelectric Proerties of $Bi_{3.25}Eu_{0.75}Ti_3O_{12}$ Thin films)

  • 김경태;김창일;이철인;김태형
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
    • /
    • pp.75-78
    • /
    • 2004
  • $Bi_{3.25}Eu_{0.75}Ti_3O_{12}$ (BET) thin films were deposited on the $LaNiO_3$ (LNO (100))/Si and Pt/Ti/$SiO_2$/Si substrates by the metal-organic decomposition method. Structural and dielectric properties of BLT thin films for the applications in nonvolatile ferroelectric random access memories were investigated. Both the structure and morphology of the films were analyzed by x-ray diffraction (XRD) and atomic force microscope (AFM). Even at low temperatures $650^{\circ}C$, the BET thinfilms were successfully deposited on LNO bottom electrode and exhibited (001) and (117) orientation. Compared with the Pt electrode films, the BET thin films on the LNO electrode annealed at $650^{\circ}C$ showed better dielectric constantsand remanent polarization. The BET thin films on the LNO electrode for the annealing temperature of $650^{\circ}C$, the remanent polarization Pr and coercive field were $45.6\;C/cm^2$ and 171 kV/cm, respectively.

  • PDF

DSP기반 연료전지 하드웨어 시뮬레이터 구현 (Implementation of a DSP Based Fuel Cell Hardware Simulator)

  • 엄준현;임영철;정영국
    • 조명전기설비학회논문지
    • /
    • 제23권1호
    • /
    • pp.59-68
    • /
    • 2009
  • 분산진원으로서 연료전지 발전장치는 100w부터 수백[kw]의 용량을 가지며 종전의 대규모 전력설비와 비교하여 높은 신뢰도를 갖는 고품질의 전력을 공급할 수 있다. 본 연구에서는 소형 분산전원으로서 PEMFC(polymer electrolyte membrane fuel cell)연료전지 발전장치에 대한 PSIM(power electronics simulation tool) 모델을 설정하고 이를 바탕으로 DSP(digital signal processor)기반의 연료전지 하드웨어 시뮬레이터를 구현하였다. 연료전지 전류와 출력전압과의 관계는 연료전지의 전압-전류(V-I) 곡선 중 ohmic영역에서 1차 함수로 간략화 하였다. 구현된 시스템은 PEMFC 하드웨어 시뮬레이터, 절연형 풀 브리지 직류 부스트 컨버터 그리고 60[Hz] PWM인버터로 구성되어있다. 부하변동 및 과도상태에 대한 연료전지 하드웨어 시뮬레이터의 전압-전류-전력(V-I-P) 특성을 파악하였으며, 저항 부하 및 비선형 부하에 대한 전력변환기의 60[Hz] 정현파 교류출력 전압파형을 고찰하였다.

NaCl과 NaBr수용액에서 적층가공으로 제조된 Ti-6Al-4V 합금의 공식 저항성 비교 (Comparing Resistances to Pitting Corrosion of Additive Manufactured Ti-6Al-4V Alloys in NaCl and NaBr Aqueous Solutions)

  • 서동일;이재봉
    • Corrosion Science and Technology
    • /
    • 제18권3호
    • /
    • pp.110-116
    • /
    • 2019
  • Resistances to pitting corrosion of additive manufactured (AM) Ti-6Al-4V alloys in 0.6 M NaBr and 0.6 M NaCl aqueous solutions were compared using micro-droplet cell techniques. With respect to the pitting corrosion resistance, this study focused on two different types of halide anions in aqueous solutions, i.e. $Br^-$ and $Cl^-$. The differences between $Br^-$ and $Cl^-$ halide anions for breakdown on passive films of AM Ti-6Al-4V alloy were explained using Langmuir adsorption model with their equilibrium adsorption coefficients. The results of the analysis showed that the lower resistance to pitting potential of AM Ti-6Al-4V alloy in $Br^-$ aqueous solution was attributed to the higher equilibrium adsorption coefficient of Br-. In addition, micro-electrochemical test results showed that the pitting corrosion resistance of dark grains in additive manufactured Ti-6Al-4V alloy was lower as compared to that of bright grains due to the larger volume of ${\alpha}^{\prime}$ phase that caused the susceptibility to pit initiation.

직접메탄올 연료전지의 농도 및 온도변화에 따른 실험적 검증 (Experimental Validation of a Direct Methanol Fuel Cells(DMFCs) model with a Operating Temperatures and Methanol Feed Concentrations)

  • 강경문;고요한;이기용;주현철
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
    • /
    • pp.125.2-125.2
    • /
    • 2010
  • In this paper, both theoretical and experimental investigations have been performed to examine the effects of key operating parameters on the cell performance of a DMFCs (i.e., methanol feed concentration and operating temperature). For experiment, the membrane electrode assemblies (MEAs) were prepared using a conventional MEA fabrication method based on a catalyst coated electrode (CCE) and tested under various cell temperatures and methanol feed concentrations. The polarization curve measurements were conducted using in-house-made $25cm^2$ MEAs. The voltage-current density data were collected under three different cell temperatures ($50^{\circ}C$, $60^{\circ}C$, and $70^{\circ}C$) and four different methanol feed concentrations (1 M, 2 M, 3 M, and 4 M). The experimental data indicate that the measured I-V curves are significantly altered, depending on these conditions. On the other hand, previously developed one-dimensional, two-phase DMFC model is simulated under the same operating conditions used in the experiments. The model predictions compare well with the experimental data over a wide range of these operating conditions, which demonstrates the validity and accuracy of the present DMFC model. Furthermore, both simulation and experimental results exhibit the strong influences of methanol and water crossover rates through the membrane on DMFC performance and I-V curve characteristics.

  • PDF