• Title/Summary/Keyword: Hydrothermal conditions

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Study on the Underground Thermal Environment around Wells for a Design Method of Open-Loop Geothermal System (개방형 지열 시스템 설계법 개발을 위한 관정 주위 지중 온도 환경 검토)

  • Bae, Sangmu;Kim, Hongkyo;Kim, Hyeon-Woo;Nam, Yujin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.13 no.1
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    • pp.14-20
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    • 2017
  • Groundwater heat pump (GWHP) system can achieve higher performance of the system by utilizing heat source of the annual constant groundwater temperature. The performance of GWHP system depends on the ground thermal environment such as groundwater temperature, groundwater flow rate and hydraulic conductivity. In this study, the geothermal environment was analyzed by using numerical simulation for develop the two-well geothermal system. As the result, this paper shows the change of the groundwater level and underground temperature around wells according to the conditions of flow rate and hydraulic conductivity.

A Study on $CaO-SiO_2-H_2O$ System Hydrates Produced by Hydrothermal Reaction under High Pressure (高壓下의 水熱反應에 依한 $CaO-SiO_2-H_2O$ 系 硬化體에 關한 基礎的 硏究)

  • Lee, Hee-Soo
    • Journal of the Korean Chemical Society
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    • v.9 no.4
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    • pp.190-200
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    • 1965
  • It is a fundamental study for the hardened bodies of $CaO-SiO_2-H_2O$ system to clear up various physical properties and structures of the products, using the Seosan quartz and $Ca(OH)_2$(C. P. grade) as raw materials. Various samples were obtained by varying $CaO/SiO_2$ mole ratio (0.3∼2.1) and hydrothermal conditions ($100∼220^{\circ}C$ and 2∼14hr.) within the given limit. It was found that tobermorite phase as hydrate is contained in the hardened bodies and that the development of crystal has a great influence on the strengths and other physical properties of hardened bodies.

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Prediction of Possibility of Indoor Pipe Freezing in Heat Only Boiler Room through Thermal Analysis (열분석을 통한 열전용 보일러동 실내배관의 동파 가능성 예측)

  • Lim, Byoung-Ik;Chung, Kwang-Seop;Kim, Young-Il
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.3
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    • pp.19-28
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    • 2012
  • In a heat only boiler system of a steam power plant, outdoor air required for combustion is made to pass through indoor space for increasing the boiler efficiency. Due to heat generated by various equipments, temperature of the air that enters the boiler will increase resulting in combustion efficiency. If the outdoor air temperature is low, however, this will cause freezing and bursting of pipes which are filled with water. It is especially fatal to small diameter pipes and pipes connected to measuring instruments. The purpose of this study is find operation and outdoor conditions where this phenomena can happen and also establish preventive measures to avoid this problem.

A Study on the Improvement of the Water Source Energy Distribution Regulation for High Efficient Data Center Cooling System in Korea (데이터센터 냉방시스템 고효율화를 위한 국내 수열에너지 보급 제도 개선에 관한 연구)

  • Cho, Yong;Choi, Jong Min
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.17 no.3
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    • pp.21-29
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    • 2021
  • In this study, the current regulation of the water source energy, one of the renewable energy, was analyzed, and the improvement plan for the high efficient data center cooling system was suggested. In the improvement plan, the design and construction guidelines of the water source energy system permit to adopt the cooling and heating system with or without heat pump. In addition, it should also include the system operated in the cooling mode only all year-round. The domestic test standards to consider the water source operating conditions should be developed. Especially, it is highly recommended that the test standards to include the system with forced cooling and free cooling modes related with the enhanced data center cooling system adopting the water source energy.

Review of Hydrothermal Temperature by Depth of High-temperature Exposed Concrete (고온 노출 콘크리트의 깊이별 수열온도 검토)

  • Kwon, Hyun-woo;Kim, Young-Min;Lee, Gun-Cheol;Heo, Young-Sun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.127-128
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    • 2021
  • In this study, a study was conducted to analyze thermal diffusion according to the depth of concrete exposed to high temperatures. For thermal diffusion analysis, a test specimen in which K-type sheath thermocouples were poured in 0, 10, 20, 30, and 40 mm sections was manufactured, and thermal diffusion measurement was performed through one-sided heating for 180 minutes under heating conditions. As a result of the review, it was shown that as the temperature condition increased, the heat diffusion increased as the depth increased.

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Mineralogical Characteristics of Hydrothermal Laumontite and Adularia in the Breccia Zone of a Fault, Yangbuk-myeon, Gyeongju and Implications for Fault Activity (경주시 양북면 단층각력대에서 산출하는 로몬타이트와 아듈라리아의 광물학적 특징과 후기 단층활동)

  • Choo, Chang-Oh;Jang, Yun-Deuk;Chang, Chun-Joong
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.1
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    • pp.23-36
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    • 2012
  • Morphological and mineralogical characteristics of laumontite and adularia in the breccia zone in a fault, Yangbuk-myeon, Gyeongju, Korea suggest that they formed by reaction with hydrothermal alteration related to fault activity. Laumontite commonly occurring in the breccia zone is related to the presence of hydrothermal fluids bearing alkaline elements in the zone. Laumonite is characterized by elongated columnar form with aspect ratio varying 5~10. Laumontite and adularia whose characteristic euhedral forms are indicative of the latest product formed as rapid precipitation from fluids or replacements of Ca-plagioclase. Hydrothermal fluids reacted with intensively fractured granite, typical with high permeability, leached alkaline elements such as Ca, K, allowing laumontite and adularia to be precipitated under neutral to weak alkaline conditions. It is noteworthy that the formation process and genesis of low temperature minerals such as laumontite and adularia are very similar to those formed by wallrock alteration or hydrothermal alteration that occurred in epithermal deposits. Taking into account its characteristic morphology and chemistry, authigenic K-feldspar that commonly forms at low temperature in many fault zones must be adularia.

Studies on the growth and properties of orthophosphate crystals by the hydrothermal method (수열법에 의한 올소인산염 결정의 육성과 성질에 관한 연구)

  • Pan-Chae Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.2
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    • pp.139-147
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    • 1994
  • Orthophosphate crystals were grown by the hydrothermal method and the properties of grown crystals were investigated by means of X-ray diffraction. Vickers hardness tester, etc. The starting powders of $AIPO_4 and GaPO_4 $were prepared as a single phase by the solid state reaction of stoichiometric mixture of $AI_2O_3 or Ga_2O_3$ and $NH_4H_2PO_4$ and the subsequently by the hydrothermal treatment. The hydrothermal conditions for high growth rates of the orthophosphate crystals are as follows: $AlPO_4$ crystal; temperature ranges, between $170$~$200^{\circ}C$; temperatures difference, $15$~$20^{\circ}C;$, hydrothermal solvent, 4m HCl, $GaPO_4 crystal; temperature ranges, between $210 and 240^{\circ}C;$; temperature difference, $25$~$30^{\circ}C; $, hydrothermal solvent, 4m HCl. Morphologies of grown crystals tended to be bounded by (1010), (1011) and (0111) faces at low temperatures, and grew with well developed (0001) faces by increasing the growth temperature. On the other hand, the properties of orthophosphate crystals $(AlPO_4/GaPO_4)$ were as follows: lattice parameters (nm); a=0.494, c=1.094/a=0.490, c=1.105, density (gcm-3); 2.62/3.56, Vickers hardness (Nm^2); $1.02{\times}10^1^0/7.06{\times}10^9$, refractive indices; $ne=1.529{\pm}0.003, no=1.519{\pm}0.003/ne=1.611{\pm}0.006, no=1.599{\pm}0.006, birefringence; {\pm}0.01/{\pm}0.012$, dielectric constant (Fm-1); 6/7.

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Hydrothermal Synthesis and Structural Characterization of x mol% Calcia-Stabilized ZrO2 Nanopowders (x mol% 칼시아-안정화 지르코니아 나노분말의 수열합성 및 구조적 특성평가)

  • Ryu, Je-Hyeok;Moon, Jung-In;Park, Yeon-Kyung;Nguyen, Tuan Dung;Song, Jeong-Hwan;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.220-226
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    • 2012
  • Pure zirconia and $x$ mol% calcia partially stabilized zirconia ($x$ = 1.5, 3, and 8) nanopowders were synthesized by hydrothermal method with various reaction temperatures for 24 hrs. The precipitated precursor of pure zirconia and $x$ mol% calcia doped zirconia was prepared by adding $NH_4OH$ to starting solutions; resulting sample was then put into an autoclave reactor. The optimal experimental conditions, such as reaction temperatures and times and amounts of stabilizer CaO, were carefully studied. The synthesized $ZrO_2$ and $x$ mol% CaO-$ZrO_2$ ($x$ = 1.5, 3, and 8) powders were characterized by XRD, SEM, TG-DTA, and Raman spectroscopy. When the hydrothermal temperature was as low as $160^{\circ}C$, pure $ZrO_2$ and $x$ mol% CaO-$ZrO_2$ ($x$ = 1.5 and 3) powders were identified as a mixture of monoclinic and tetragonal phases. However, a stable tetragonal phase of zirconia was observed in the 8 mol% calcia doped zirconia nanopowder at hydrothermal temperature above $160^{\circ}C$. To observe the phase transition, the 3 mol% CaO-$ZrO_2$ and 8 mol% CaO-$ZrO_2$ nanopowders were heat treated from 600 to $1000^{\circ}C$ for 2h. The 3 mol% CaO-$ZrO_2$ heat treated at above $1000^{\circ}C$ was found to undergo a complete phase transition from mixture phase to monoclinic phase. However, the 8 mol% calcia doped zirconia appeared in the stable tetragonal phase after heat treatment. The result of this study therefore should be considered as the preparation of 8 mol% CaO-$ZrO_2$ nanopowders via the hydrothermal method.

Phase Change of Nanorod-Clustered $MnO_2$ by Hydrothermal Reaction Conditions and the Lithium-ion Battery Cathode Properties of $LiMn_2O_4$ Prepared from the $MnO_2$ (수열합성 조건에 따른 나노로드 클러스터형 $MnO_2$의 상변화와 이를 이용한 $LiMn_2O_4$의 리튬이온전지 양전극 특성)

  • Kang, Kun-Young;Choi, Min Gyu;Lee, Young-Gi;Kim, Kwang Man
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.541-547
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    • 2011
  • Nanorod-clustered $MnO_2$ precursors with ${\alpha}$-, ${\beta}$-, and ${\gamma}$-phases are synthesized by hydrothermal reaction of $MnSO_45H_2O$ and $(NH_4)S_2O_8$. The formation of nanorod-clustered ${\beta}-MnO_2$ is particularly confirmed under the conditions of high reactant concentration and hydrothermal reaction at $150^{\circ}C$. The spinel $LiMn_2O_4$ nanorod-clusters are also prepared by lithiating the $MnO_2$ precursors, varying the concentration of lithiating agent ($LiC_3H_3O_2{\cdot}2H_2O$) and heat treatment temperature, and characterized for use as cathode material of lithium-ion batteries. As a result, the nanorod-clustered $LiMn_2O_4$ prepared from the ${\beta}-MnO_2$ at higher $LiC_3H_3O_2{\cdot}2H_2O$ concentration and the annealing at $800^{\circ}C$ is proven to show the cubic spinel structure and to achieve the high initial discharge capacity of 120 mAh/g.

Effects of Growth Conditions on Properties of ZnO Nanostructures Grown by Hydrothermal Method (수열합성법으로 성장된 ZnO 나노구조의 성장조건에 따른 특성)

  • Cho, Min-Young;Kim, Min-Su;Kim, Ghun-Sik;Choi, Hyun-Young;Jeon, Su-Min;Yim, Kwang-Gug;Lee, Dong-Yul;Kim, Jin-Soo;Kim, Jong-Su;Lee, Joo-In;Leem, Jae-Young
    • Korean Journal of Materials Research
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    • v.20 no.5
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    • pp.262-266
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    • 2010
  • ZnO nanostructures were grown on an Au seed layer by a hydrothermal method. The Au seed layer was deposited by ion sputter on a Si (100) substrate, and then the ZnO nanostructures were grown with different precursor concentrations ranging from 0.01 M to 0.3M at $150^{\circ}C$ and different growth temperatures ranging from $100^{\circ}C$ to $250^{\circ}C$ with 0.3 M of precursor concentration. FE-SEM (field-emission scanning electron microscopy), XRD (X-ray diffraction), and PL (photoluminescence) were carried out to investigate the structural and optical properties of the ZnO nanostructures. The different morphologies are shown with different growth conditions by FE-SEM images. The density of the ZnO nanostructures changed significantly as the growth conditions changed. The density increased as the precursor concentration increased. The ZnO nanostructures are barely grown at $100^{\circ}C$ and the ZnO nanostructure grown at $150^{\circ}C$ has the highest density. The XRD pattern shows the ZnO (100), ZnO (002), ZnO (101) peaks, which indicated the ZnO structure has a wurtzite structure. The higher intensity and lower FWHM (full width at half maximum) of the ZnO peaks were observed at a growth temperature of $150^{\circ}C$, which indicated higher crystal quality. A near band edge emission (NBE) and a deep level emission (DLE) were observed at the PL spectra and the intensity of the DLE increased as the density of the ZnO nanostructures increased.