• Resources Recycling
• /
• v.31 no.6
• /
• pp.18-24
• /
• 2022

Dry reduction using natural gas was proposed to recover tin from waste tin oxide generated in a tin bath that was used for controlling the smoothness of architectural glass during production, and the reduction behavior was investigated. The utilized vertical natural gas dry reduction system is capable to process 4 L or 20 kg depending on input raw materials. The system was established by applying the upper intake and lower discharge method. The recovery rate was 97.2% at 800 ℃ and 4 sccm flow rate and increased with the amount of input gas. Hydrogen accounted for 23% of the discharge gas, showing a 16.6% hydrogen conversion rate. The reaction behavior of tin recovered via natural gas reduction provides basic data on the new waste resource reduction/recovery technology.

• Transactions on Electrical and Electronic Materials
• /
• v.6 no.5
• /
• pp.214-220
• /
• 2005

The ferroelectric properties of the $Pt/PZT(Pb(Zr,Ti)O_3)/Pt$ capacitors are severely degraded when they are annealed in hydrogen-containing environment. Hydrogen atoms created by the catalytic reaction of Pt top electrode during annealing in hydrogen ambient penetrate into PZT films and generate oxygen vacancies by the reduction of the PZT films, which is likely to cause the degradation. The degree of hydrogen-induced degradation and the direction of voltage shift in P-E curves of the pre-poled PZT capacitors after annealing in hydrogen ambient is dependent on the polarity of the pre-poling voltage. This implies that oxygen vacancies causing hydrogen induced degradation are generated by hydrogen ions having a polarity. The degraded ferroelectricity of the PZT capacitors can be effectively recovered by the shift of oxygen vacancies toward the Pt top electrode interface during post-annealing in oxygen environment with applying negative unipolar stressing.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.6
• /
• pp.522-529
• /
• 2020

This study evaluated the effect of improving the atmospheric environment based on the premise that the supply of hydrogen fuel cell vehicles (HFCV) will be achieved as many as the number of vehicles presented in the hydrogen economy activation roadmap announced by the Korean government in January 2019. The HFCV supply target (2.7 million passenger cars) suggested in the hydrogen economy revitalization roadmap was logically allocated to the five major metropolitan areas in Korea. Air pollution damage costs by region were calculated by reflecting the basic unit of damage cost to the estimated air pollutant emissions. As a result, it was confirmed that the benefits per unit of some cities in Gyeonggi-do were derived more than major cities in the metropolitan area.

• Journal of the Korean Chemical Society
• /
• v.13 no.2
• /
• pp.141-147
• /
• 1969

Organophosphorous compounds can be reduced by zinc metal in acidic solution after alkaline hydrolysis. Although phosphates and phosphonates did not evolve any gas, dithioates did evolve hydrogen sulfide and phosphine, thionates and thiolates did evolve only hydrogen sulfide. The evolved gases were qualitatively detected by means of lead acetate and silver nitrate or mercuric bromide papers and determined by spectrophotometrically. The reduction mechanism and analytical method of dithioates were proposed.

• Korean Journal of Veterinary Research
• /
• v.38 no.2
• /
• pp.273-279
• /
• 1998

The ability of bovine intact red blood cells to scavenge superoxide and hydrogen peroxide by superoxide dismutase, catalase and glutathione peroxidase was investigated. Intact red cells(up to 0.4%) suspensions did not inhibit ferricytochrome c reduction by superoxide in the superoxide generating system. On the other hand, intact red cell(0.4%) suspensions almost completely inhibit ferrocytochrome c oxidation by hydrogen peroxide. The ability of intact red cells to scavenge hydrogen peroxide was mainly attributed to either membrane bound catalase or glutathione peroxidase. The scavenge of hydrogen peroxide by 0.1~0.2% intact red cells showed a trend of dependence on mainly glutathione peroxidase. However, at blood cell concentration higher than 0.3%, the process depended upon peroxidase-independent scavengers like catalase. Enhancement of ferrocytochrome c oxidation by red cells treated with aminotriazole proved that the protection against hydrogen peroxide was due to catalase, while the protection in the presence of glutathione indicated scavenging effect of glutathione peroxidase against hydrogen peroxide.

• Journal of the Korea Safety Management & Science
• /
• v.16 no.4
• /
• pp.167-173
• /
• 2014

Hydrogen energy is expanding in range for civil use together with development of pollution-free power sources recently, and it is judged that the use of hydrogen will increase more as a part of carbon dioxide reduction measures according to the Climatic Change Convention. Especially, it is thought that the securement of safety of the used dispenser will be the biggest obstacle in the use of high-pressure hydrogen because the hydrogen station is operated in a high pressure. This study found risks in the process and problems on operation by making use of HAZOP(6 kinds), a qualitative safety evaluation technique, and FMEA(5 kinds), a fault mode effect analysis, for the hydrogen charging system at a hydrogen gas station, derived 6 risk factors from HAZOP and 5 risk factors from FMEA, and prepared measures for it.

• New & Renewable Energy
• /
• v.20 no.1
• /
• pp.110-115
• /
• 2024

Global sustainable energy needs and carbon neutrality goals make hydrogen a key future energy source. South Korea and Japan lead with proactive hydrogen policies, including South Korea's Hydrogen Law and Japan's strategy updates aiming for a hydrogen-centric society by 2050. A notable advance is the solar thermal chemical water-splitting cycle for green hydrogen production, spotlighted by Korea Institute of Energy Research (KIER) and Niigata University's joint initiative. This method uses solar energy to split water into hydrogen and oxygen, offering a carbon-neutral hydrogen production route. The study focuses on international collaboration in solar energy for thermochemical water-splitting and E-fuel production, highlighting breakthroughs in catalyst and reactor design to enhance solar thermal technology's commercial viability for sustainable fuel production. Collaborations, like ARENA in Australia, target global carbon emission reduction and energy system sustainability, contributing to a cleaner, sustainable energy future.

• Korean Journal of Materials Research
• /
• v.27 no.8
• /
• pp.438-444
• /
• 2017

In this work, the effects of hydrogen reduction on the microstructure and thermoelectric properties of $(GeTe)_{0.85}(AgSbTe_2)_{0.15}$ (TAGS-85) were studied by a combination of gas atomization and spark plasma sintering. The crystal structure and microstructure of TAGS-85 were characterized by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The oxygen content of both powders and bulk samples were found to decrease with increasing reduction temperature. The grain size gradually increased with increasing reduction temperature due to adhesion of fine grains in a temperature range of 350 to $450^{\circ}C$. The electrical resistivity was found to increase with reduction temperature due to a decrease in carrier concentration. The Seebeck coefficient decreased with increasing reduction temperature and was in good agreement with the carrier concentration and carrier mobility. The maximum power factor, $3.3{\times}10^{-3}W/mK^2$, was measured for the non-reduction bulk TAGS-85 at $450^{\circ}C$.

• Journal of the Korean Society of Combustion
• /
• v.18 no.1
• /
• pp.27-33
• /
• 2013

Hydrogen-dimethy ether(DME) partially premixed compression ignition(PCCI) engine combustion was investigated in a single cylinder compression ignition engine. Hydrogen and DME were used as low carbon alternative fuels to reduce green house gases and pollutant. Hydrogen was injected at the intake manifold with an injection pressure of 0.5 MPa at fixed injection timing, $-210^{\circ}CA$ aTDC. DME was injected directly into the cylinder through the common-rail injection system at injection pressure of 30 MPa. DME inejction timing was varied to find the optimum PCCI combustion to reduce CO, HC and NOx emissions. When DME was injected early, CO and HC emissions were high while NOx emission was low. As the DME injection was retarded, the CO and HC emissions were decreased due to high combustion efficiency. NOx emissions were increased due to the high in-cylinder temperature. When DME were injected at $-30^{\circ}CA$ aTDC, reduction of HC, CO and NOx emissions was possible with high value of IMEP.

• 한국태양에너지학회:학술대회논문집
• /
• 2012.03a
• /
• pp.113-119
• /
• 2012

The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction) and W-D (Water Decomposition) steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $CeO_2$ powder, was successfully achieved hydrogen production under field conditions. Through this experiment, we can analyze the characteristics of the catalyst and able to determine which is more advantageous thing to produce hydrogen compared with previous experiment that used ferrite-device.