• Title/Summary/Keyword: Hydrogen-oxidizing

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A study on the Effect of SOB(Sulfur-Oxidizing Bacteria) Media on the Removal of Hydrogen Sulfide in Water of Septic Tank (SOB(Sulfur Oxidizing Bacteria) Media가 정화조의 수중황화수소 제거에 미치는 영향에 관한 연구)

  • Song, Homyeon;Cho, Jeongil;Kim, Taeksoo;Kwon, Sucheol;Yu, Hyeongsik
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.59-67
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    • 2013
  • The odor occurring in the sewage system induces the displeasure, the disgust such as the headache, the vomit, etc. and increases the spiritual stress and disturbs the pleasant life of residents. These odors occur mainly in the area of combined sewage system treatment, being created in the personal sewage treatment plant such as septic tank and are incoming to sewage pipes and emitted to the outside through the manhole and the receiver, etc.; and this causes odors to the people. The Hydrogen Sulfide, the Methyl Mercaptan, the Ammonia, etc. are materials causing the odor, the more serious issue of odor is occurring since the septic tank of degradation process is being applied. The primary cause of odor is the decomposition of human feces in the septic tanks and sewage disposal facilities. The purpose of this study is reduction of hydrogen sulfide using air supplying and SOB(Sulfur-Oxidizing Bacteria). As a result of this study of the air supply system and the SOB media equipment by air supply, in case the air is injected to SOB media compared to the injection of air only, the removal efficiency the hydrogen sulfide was average 3.4 times higher.

Studies on Bonding Characteristics of Plywood by Kraft Black Liquor and Surface Activators (크라프트펄프 폐액(廢液)과 표면산화제(表面酸化劑)를 이용(利用)한 합판(合板)의 접착특성(接着特性)에 관(關)한 연구(硏究))

  • Chung, In-Ju;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.3
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    • pp.5-16
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    • 1988
  • This experiment was executed to investigate the effect of activation of veneer surface by oxidizing agents, hydrogen peroxide and nitric acid, on bonding characteristics of Malas(Homalium foetidum Benth) plywood, in which the effects of these oxidizing agents amount, pretreatment time, and pressing time and temperatue on shear strength of the plywood were examined and discussed. In this research the activation of veneer surface by oxidants was effective in raising shear strength but the difference in shear strength was not observed between hydrogen peroxide and nitric acid treatment. Hydrogen peroxide treatment, however, seemed to be more profitable to industrial application because of its lower concentration and easier handling than nitric acid. The bonding method by lignin-phenol adhesive through surface activation revealed inferior shear strength to phenol- and urea-formaldehyde adhesive but superior water resistance to urea-formaldehyde adhesive and this bonding method, in addition, have the advantage of lower cost compared with phenol-formaldehyde adhesive, Therefore, this bonding method by lignin-phenol adhesive through surface activation seemed to economical in manufacturing of water-resistant wood panel materials in future.

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Removal of Hydrogen Sulfide Using Porous Ceramic Biofilter Inoculated with Sulfur Oxidizing Bacteria (황산화 균주가 부착된 다공성 세라믹 biofilter를 이용한 $H_2S$ 제거)

  • 박상진;조경숙
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.649-655
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    • 1999
  • Biofiltration of polluted gas streams contained $H_2S$ was studied. The experiments were performed in a laboratory-scale reactor with a porous ceramic media inoculated with sulfur oxidizing bacterium, TAS which was isolated from activiated sludge. The concentration of $H_2S$ in the inlet gas varied from 109 to 3,841 ppm, at the various space velocities(SV) of 50 $h^{-1}$ to 250 $h^{-1}$. Various tests have been conducted to evaluate the effects of such parameters as pH, concentration of sulfate ion and retention time on the pressure drop and maximum elimination capacity. The removal efficiency of $H_2S$ decreased as the $H_2S$ concentration or gas velocity increased in the inlet gas. Pressure drop was insignificant in this system. The maximum elimination capacity could reach up to 16.35g-S/kg-dry packing material/day.

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Roles of Phosphoric Acid in Slurry for Cu and TaN CMP

  • Kim, Sang-Yong;Lim, Jong-Heun;Yu, Chong-Hee;Kim, Nam-Hoon;Chang, Eui-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.1-4
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    • 2003
  • The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$\^$nd/ step copper CMP slurry and hydrogen peroxide stability.

The Effect of Oxidizing Agents on Alkaloid Reduction of Tobacco Extract (담배추출물의 알카로이드감소에 미치는 산화제의 영향)

  • 황건중
    • Journal of Environmental Health Sciences
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    • v.8 no.2
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    • pp.33-46
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    • 1982
  • This experiment was carried out for the purpose of reducing alkaloid in reconstituted tobacco sheet and effluent of reconstituted tobacco sheet manufacturing company by treating oxidizing agents such as ozone, sodium hypochlorite, perchloric acid and hydrogen peroxide to tobacco extract created from the manufacturing process of reconstituted tobacco sheet. The effect of alkaloid reduction in tobacco extract by the volume added, time of treatment and pH of oxidizing agents were as follows: 1. When the solid rate of tobacco extract stood at 10 percent, the content of alkaloid, total sugar, total nitrogen and chlorine was 1,600mg/l, 11,000mg/l, 3,200mg/l and 4,000mg/l, respectively. 2. The effect of alkaloid reduction through ozone treatment was in proportion to time of ozone treatment. Alkaloid showed a 31.2 percent reduction under 8 hours' ozone treatment and 0.23g ozone consumed to remove lmg alkaloid. 3. Alkaloid reduction through sodium hypochlorite treatment was influenced by quantity of chlorine in sodium hypochlorite solution. To remove lmg alkaloid, 36.3mg chlorine was used. Reduction of alkaloid was not affected by time of sodium hypochlorite treatment, while showed the best reaction under pH 5-7. 4. The effect of alkaloid reduction by perchloric acid was under the control of the volume added and time of treatment of perchloric acid. The volume of perchloric acid required to remove alkaloid was on the decrease as time of treatment was getting longer. lmg alkaloid was removed by 0.15g perchloric acid under 8 hours' perchloric acid treatment. 5. Alkaloid reduction reacted slowly to the volume added and time of treatment of hydrogen peroxide. Under 8 hours' hydrogen peroxide treatment, it showed maximum removal, registering 10 percent alkaloid reduction.

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In the presence of organic solvent stability of CiP [coprinus cinereus peroxidase] (유기용매에서의 CiP [coprinus cinereus peroxidase]의 안정성)

  • Kim, Han-Sang;Cho, Dae-Haeng;Kim, Yong-Hwan
    • KSBB Journal
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    • v.23 no.4
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    • pp.340-344
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    • 2008
  • Coprinus cinereus peroxidase (CiP) was often used as a catalyst for oxidative polymerization of a variety of phenol derivatives to produce a new class of polyphenols. Economical point of view, to know the mechanism of enzyme deactivation is significantly important because cost of enzyme is critically high. Hydrogen peroxide being used as oxidizing agent induced deactivation of peroxidase by destruction of heme structure. In the presence of hydrogen peroxide the stability of peroxidase was unexpectedly improved by adding organic solvent. Especially 2-propanol significantly improved enzyme stability among tested solvents. Radical scavenging by organic solvents may play a major role in protecting peroxidase from the oxidation of oxidizing radicals.

Complex odor removal in pilot-scale biofilter with microorganisms immobilized on polymer gel media (미생물 포괄고정화 담체를 적용한 파일럿 스케일 바이오필터에서의 복합악취 제거)

  • Kim, Sun-Jin;Kim, Tae-Hyeong;Lee, Yun-Hee;Jang, Hyun-Sup;Song, Ji-Hyeon;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.741-750
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    • 2011
  • A pilot-scale biofilter was constructed to discover degradation characteristics of the complex odor discharged from Ansan wastewater treatment plant. Candida tropicalis for volatile organic compounds, sulfur oxidizing bacteria(SOB) for hydrogen sulfide, and bacteria extracted from feces soil were immobilized on a polymer gel media. According to this study, the EBCT was varied from 36 sec to 18 sec. Toluene was removed as 80% along the variations, but it was recovered as 100% within 1 week. All benzene and xylene were removed during the operation while the efficiency of hydrogen sulfur was temporary decreased at 18 sec of EBCT, thereafter it was recovered to 100% within a week. The maximum elimination capacities of the benzene, toluene, xylene, and hydrogen sulfur were 6.6 g/$m^{3}$/hr, 31.7 g/$m^{3}$/hr, 7.8 g/$m^{3}$/hr, and 133.6 g/$m^{3}$/hr, respectively. There were merits on removal both organic and inorganic complex odor using the pilot-scale biofilter embedded with microorganisms immobilized on polymer gel media.

Removal of Hydrogen Sulfide by Biofilter Media (담체 종류에 따른 황화수소의 제거특성)

  • Cha, Gyusuk
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.4
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    • pp.41-45
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    • 2007
  • It is very important that selection of packing media with large surface area, high limited back pressure in biofilter. The object of this study is the isolation of sulfur-oxidizing bacteria and the removal of hydrogen sulfide in biofilter by media. This investigation led to the following results: 1) we isolated Thiobacillus sp. IW. at an abandoned coal mine in Hwasun, Jeonnam Province. 2) The inorganic media showed better results than the organic media from experiments looking at removal characteristics and changes in pressure drop using various media. 3) Among the inorganic media, fibril and PU media showed best performance.

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The Influences of Water Vapor/Hydrogen Ratio, Gas-Flow Rate and Antimony on the Surface Oxidation of Trip Steels

  • Kwon, Youjong;Zhu, Jingxi;Sohn, Il-Ryong;Sridhar, Seetharaman
    • Corrosion Science and Technology
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    • v.10 no.6
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    • pp.189-193
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    • 2011
  • In the current paper, we are reporting the results from an investigation of the surface and sub-surface oxidation of a TRIP steel containing 2 wt.% Mn and 0.5 wt.% Al with and without 0.03 wt.% Sb. The oxidizing conditions in the gas were successively varied in terms of the linear gas flow-rate and dew-point, from conditions were gas-phase mass transport limited conditions prevailed, to those were solid state processes became the rate determining conditions. It was found, that at sufficient low oxidizing conditions (defined as flow-rate/dew-point), the metal surfaces were clear of any external oxides, and as the oxidizing conditions were increased, Mn- and Si- oxide nodules formed along with magnetite. As the oxidizing conditions were increased further, a dense magnetite layer was present. The limits of the various regions were experimentally quantified and a proposed hypothesis for their occurrences is presented. No obvious effect of Sb was noted in this micro-structural research of the oxides that results from the various conditions investigated in this study.