• Title/Summary/Keyword: Hydrogen-Oxygen Gas

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A Study for the Output Increament of the Hydrogen Gas Turbine with Water Injection (물분사 수소 가스터빈의 출력 향상을 위한 연구)

  • Jung, K.S.;Oh, B.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.1
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    • pp.1-7
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    • 1998
  • Most of today's energy supply is obtained from fossil fuels. Despite of high energy density, higher store efficiency and long mileage, fossil fuels cause environmental pollution and their reserves are limited. In this study pure hydrogen gas and oxygen gas are burned without the emission of pollution. A gas turbine is used to obtain power. Water is injected into a combustor, which prevents overheating and recovers cooling heat. Excessively supplied water is recirculated. With variation of mass flow rate and equivalence ratio, the affection of water injection rate and the temperature of injected water on efficiency and power are experimented. Injected water gets cooling heat, is expanded from liquid to vapor and raises the thermal efficiency. It is enable to determine the rate of water injection, which makes the maximum power. The increase of temperature of water injection raises the efficiency of the system.

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An Experimental Study on Measurement of Oxygen Concentration in the Cathode Channel of PEMFC by Using GC (GC를 이용한 고분자전해질형 연료전지의 공기극 채널 내 산소 농도 분포에 관한 실험적 연구)

  • Ha Taehun;Kim Han-Sang;Min Kyoungdoug
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.384-387
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    • 2005
  • Fuel cell has been well known as a clean alternative power for vehicles. Recently, an experimental technique has been developed measurement of species and distributions by using gas chromatograph. In this study, cathode channel oxygen distributions as various conditions were investigated using gas chromatograph and cell visualization. And discussed relation between flooding and oxygen concentrations. As a result of experiment, oxygen consumpt ion is affected wi th flooding. Flooding is observed in channel near hydrogen inlet, and oxygen consumption is low at that region.

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Effects of Temperature, Pressure, and Gas Residence Time on Methane Combustion Characteristics of Oxygen Carrier Particle in a Pressurized Fluidized Bed Reactor (가압 유동층 반응기에서 산소공여입자의 메탄 연소 특성에 미치는 온도, 압력 및 기체체류시간의 영향)

  • Ryu, Ho-Jung;Park, Sang-Soo;Moon, Jong-Ho;Choi, Won-Kil;Rhee, Young-Woo
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.173-182
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    • 2012
  • Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

A Theoretical Analysis on Hydrogen Gas Fueled Turbine Engine with No Emissiom Gas (배기가스가 없는 수소가스용 터빈엔진에 대한 이론적 해석)

  • Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.25-31
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    • 1994
  • It is very important factor to reduce air pollution from any engines. Some exhaust gases, as $CO_2$, $NO_X$ and $SO_X$, are the products by combustion of hydrocarbon fuel and air. Hydrogen is clean energy to keep our environment out of air pollution. In this study a turbine engine system is theoretically developed which produces pure water only with no exhaust gas by combustion of hydrogen and stoichiometric oxygen. The thermal efficiency of the whole system can be calculated by calculation of each part.

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Diamond Film Deposition by Microwave Plasma CVD Using a Mixture of $CH_4$, $H_2$, $O_2$, (마이크로웨이브 플라즈마 화학증착법에 의해 메탄, 수소, 산소의 혼합가스로부터 다이아몬드 박막의 합성)

  • 이길용;제정호
    • Journal of the Korean Ceramic Society
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    • v.27 no.4
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    • pp.513-520
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    • 1990
  • Diamond film was deposited on Si wafer substrate from a gas mixture of methane, hydrogen and oxygen by microwave plasma-assisted chemical vapor deposition. The effects of the pre-treatments of the substrate and of the oxygen addition on the diamond film synthesis are described. In order to obtain diamond film, the substrate was pre-treated with 3 kinds of methods. When the substrate was ultrasonically vibrated within the ethyl alcohol dispersed with 25${\mu}{\textrm}{m}$ diamond powder, the denset diamond film was deposited. Addition of oxygen in the gas mixture of methane and hydrogen improved the crystallinity of the deposited diamond film and also increased the deposition rate of the diamond film more than two times.

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Reduction Characteristics of Oxygen Carriers in a Pressurized Bubbling Fluidized Bed (가압 기포유동층에서 산소전달입자들의 환원반응특성)

  • YOON, JOO-YOUNG;BAE, DAL-HEE;BAEK, JEOM-IN;RYU, HO-JUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.589-596
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    • 2016
  • Effects of pressure, temperature, gas velocity, and fuel flow rate on reduction of three oxygen carriers, SDN70, OC-1, OC-2, were measured and investigated in a pressurized bubbling fluidized bed reactor. Among three oxygen carriers OC-2 was selected as the best oxygen carrier in view of fuel conversion and $CO_2$ selectivity. However, all oxygen carriers showed good reactivity even at high pressure conditions. SDN70 particle showed maximum reactivity at $900^{\circ}C$ and low reactivity at $950^{\circ}C$. However, reactivity decay of OC-1 and OC-2 particles at high temperature condition was negligible. The fuel conversion and the $CO_2$ selectivity slightly decreased as the gas velocity increased, whereas they are slightly increased as the fuel concentration increased.

Effect of Substrate Temperature and Hydrogen Ambient Gases on the Structural and Electrical Characteristics of IGZO Thin Films (기판온도 및 수소 분위기 가스에 따른 IGZO 투명전도성박막의 구조적 및 전기적 특성)

  • Bae, Jang Ho;Lee, Kyu Mann
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.1
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    • pp.12-16
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    • 2022
  • We have investigated the effect of the substrate temperature and hydrogen flow rate on the characteristics of IGZO thin films for the TCO (transparent conducting oxide). For this purpose, IGZO thin films were deposited by RF magnetron sputtering at room temperature and 300℃ with various H2 flow rate. Experiments were carried out while varying the hydrogen gas flow rate from 0sccm to 1.0sccm in order to see how the hydrogen gas affects the IGZO thin films. IGZO thin films deposited at room temperature and 300℃ showed amorphous. The lowest resistivity value was 0.379×10-5 Ωcm when the IGZO film was deposited at 300℃ and set up at 1.0sccm. As the oxygen vacancy rate increased, the resistivity intended to decrease. In conclusion, Oxygen vacancy affects the IGZO thin film's electrical characteristic.

A study on the characteristics of inner cell pressure for sealed type Ni-MH rechargeable battery using Zr-based hydrogen storage alloy as anode (Zr-based 수소저장합금을 음극으로 사용한 밀패형 Ni-MH 2차전지의 내압특성에 관한 연구)

  • Kim, Dong-Myung;Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.2
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    • pp.79-90
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    • 1997
  • Extensive work has been done on investigating the inner cell pressure characteristics of sealed type Ni-MH battery in which Zr-Ti-Mn-V-Ni alloy is used as anode. The inner cell pressure of this type Ni-MH battery much more increases with the charge/discharge cycling than that of the other type Ni-MH battery where commercialized $AB_5$ type alloy is used as anode. The increase of inner cell pressure in the sealed type Ni/MH battery using Zr-Ti-Mn-V-Ni alloy system is mainly due to the accumulation of oxygen gas during charge/discharge cycling. The accumulation of oxygen gas arises mainly due to the low rate of oxygen recombination on the MH electrode surface during charge/discharge cycling. The difference of oxygen recombination rate between $AB_5$ type electrode and Zr-Ti-Mn-V-Ni electrode is caused by the difference of electrode reaction surface area resulting from different particle size after their activation and the difference of surface catalytic activity for oxygen recombination reaction, respectively. After EIS analysis, it is identified that the surface catalytic activity affects much more dominantly on the oxygen recombination reaction than the reaction surface area does. In order to suppress the inner cell pressure of Ni-MH battery where Zr-Ti-Mn-V-Ni is used as anode, it is suggested that the surface catalytic activity for oxygen recombination should be improved.

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Structural and Electrical Characteristics of MZO Thin Films Deposited at Different Substrate Temperature and Hydrogen Flow Rate (증착 온도 및 수소 유량에 따른 MZO 박막의 구조적 및 전기적 특성)

  • Lee, Jisu;Lee, Kyu Mann
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.2
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    • pp.6-11
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    • 2018
  • In this study, we have studied the effect of substrate temperature and hydrogen flow rate on the characteristics of MZO thin films for the TCO(Transparent conducting oxide). MZO thin films were deposited by RF magnetron sputtering at room temperature and $100^{\circ}C$ with various $H_2$ flow rate(1sccm~4sccm). In order to investigate the effect of hydrogen gas flow rate on the MZo thin film, we experimented with changing the hydrogen in argon mixing gas flow rate from 1.0sccm to 4.0sccm. MZO thin films deposited at room temperature and $100^{\circ}C$ show crystalline structure having (002), (103) preferential orientation. The electrical resistivity of the MZO films deposited at $100^{\circ}C$ was lower than that of the MZO film deposited at room temperature. The decrease of electrical resistivity with increasing substrate temperature was interpreted in terms of the increase of the charge carrier mobility and carrier concentration which seems to be due to the oxygen vacancy generated by the reducing atmosphere in the gas. The average transmittance of the MZO films deposited at room temperature and $100^{\circ}C$ with various hydrogen gas flow was more than 80%.

Development of a High Efficiency Polymer Electrolyte Membrane Fuel Cell Stack under Pressurized Operating Conditions (고효율 가압형 고분자전해질 연료전지 셀스택 개발)

  • Han, In-Su;Seo, Hakyu;Jung, Jeehoon;Kim, Minsung;Shin, Hyunkhil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.125.1-125.1
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    • 2010
  • A high efficiency polymer electrolyte membrane (PEM) fuel cell stack was developed for pressurized pure hydrogen and oxygen supplying conditions. The design objective for the cell stack was to maximize the electric efficiency and to minimize exhaust-gas emissions from it simultaneously. To achieve this objective, the cell stack was designed to use pure hydrogen and oxygen as fuel and oxidant, respectively, and to be operated under high gas inlet pressures and in a stage-wise dead-end operation mode. Major components constituting the cell stack, such as membrane electrode assembly, bipolar-plate, and gasket, have been developed to meet a target durability even in severe operating conditions: high gas inlet pressures and usage of pure oxygen. A high-power fuel cell stack was assembled using these components to verify the performance. The cell stack showed a good performance in terms of the efficiency and maximum power output.

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