• 한국석유지질학회지
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• 제14권1호
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• pp.45-52
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• 2008

천연가스로부터 청정연료인 합성유를 제조하는 GTL기술은 1920년대 군수의 목적으로 독일의 Fisher와 Tropsch에 의해서 석탄으로부터 합성유를 제조하는 기술의 필요에 의해 처음으로 개발되었다. 이후, 1960년대 인종차별로 인한 정치적 고립으로 석유수급이 어려웠던 남아프리카공화국의 수송용 연료의 필요에 의해 Sasol사에서 본격적으로 FT(Fisher-Tropsch) 합성기술을 상용화하기 시작했다. 최근까지도 저렴한 석유자원으로 인해 GTL기술이 원유 정제기술로부터 얻어지는 석유제품에 비해 경제성을 확보하지 못하여 본격적인 상업화가 지연되어 왔으나, 에너지 자원의 수급 및 기타 경제적, 환경적 변화로 인해 GTL사업에 대한 관심이 고조되고 있으며 보유 석유자원이 한계에 다다라 상대적으로 풍부한 천연가스의 석유화를 목표로 하고 있는 카타르를 중심으로 GTL플랜트 건설이 추진되고 있다. 천연가스를 원료로 석유제품(디젤 및 나프타, 윤활기유 등)을 만드는 GTL기술은 크게 3가지 공정으로 구분되는데, 천연가스에서 수소와 일산화탄소를 제조하는 합성가스 제조공정(Synthesis Gas Generation), 합성가스를 FT합성반응에 의해 고분자 선형탄화수소로 전환시키는 FT합성공정(FT Synthesis)과 FT합성유로부터 석유제품을 만드는 개질공정(Product Upgrading)으로 구성된다. 생산된 제품은 유황 및 질소화합물 등을 적게 함유하고 있고, 정유플랜트 연료보다 방향족성분이 적어, 연소 시 인체에 해로운 물질을 적게 생산하는 청정연료이며, 천연가스를 저온 액화하는 LNG사업에 비하여 운송이 용이하고 안정성이 높다는 장점을 가지고 있다.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2004년도 학술대회 논문집
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• pp.87-90
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• 2004

This paper describes development of power transformer maintenance system using intelligent dissolved gases in oil analysis. The used gases are acetylene(C2H2), hydrogen(H2), ethylene(C2H4), methane(CH4), ethane(C2H6), carbon monoxide(CO) and carbon dioxide(CO2). The rule and neural network based gas analysis methods are used for artificial intelligent diagnosis. It is indicated that this program is efficient for diagnosis of oil immersed transformers diagnosis from application of gas analysis data of serviced transformer which has local overheating

• 한국추진공학회지
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• 제13권3호
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• pp.58-63
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• 2009

세계적으로 강화되는 오염물질 배출규제와 유가의 급등은 미래 수송수단의 변화를 가져올 것으로 예상된다. 새로운 대체에너지가 나타나기 까지는 화석연료를 대체할 에너지원으로 수소가 가장 유력하다. 가까운 미래의 항공기는 수소 가스터빈엔진이나 연료전지와 같은 동력장치를 사용할 것으로 과학자들은 예측하고 있다. 향후 연료전지 동력 항공기가 실현되기 위해서는 동력밀도가 높은 연료전지, 고압의 기체 또는 액체상태의 수소연료저장 장치, 그리고 경량의 고효율 전기모터가 개발되어야 한다.

• 에너지공학
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• 제9권2호
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• pp.83-88
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• 2000

In this study, the performance and pollutant emission of CNG engine using diesel oil as a source of ignition, so called CNG dual fuel diesel engine is considered by experiment. One of the unsolved problems of the natural gas dual fuel engine is that there is too much exhaust of total hydrocarbon (THC) at a low equivalent mixture ratio. To fix it, a natural gas mixed with hydrogen was applied to engine test. The results showed that the higher the mixture ratio of hydrogen to natural gas, the higher the combustion efficiency. and when the amount of the intake air is reached to 90% of WOT, the combustion efficiency was promoted. But, like a case making the injection timing earlier, the equivalent mixture ratio for the knocking limit decrease and the produce of NOx increases.

• Environmental Engineering Research
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• 제10권3호
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• pp.122-130
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• 2005

Gasification of carbonaceous wastes such as shredded tire, waste lubricating oil, plastics, and powdered coal initiates a single-stage reforming reactor(reformer) Without catalyst and a syngas burner. Syngas is combusted with $O_2$ gas in the syngas burner to produce $H_2O\;{and}\;CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevates the temperature of reactor above $1,200^{\circ}C$, and hydrogen gas fraction reaches 65% of the product gas output. Reactants and heat necessary for the reaction are provided through the syngas burner only. Neither $O_2$ gas nor steam is injected into the reforming reactor. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and the product syngas is recycled into syngas burner.

• Corrosion Science and Technology
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• 제4권6호
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• pp.236-241
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• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• 한국대기환경학회지
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• 제31권4호
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• pp.368-377
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• 2015

Bunker C fuel oil is a high-viscosity oil obtained from petroleum distillation as a residue. The sulfur content of bunker C fuel oil is limited to 4.0% or even lower to protect the environment. Because bunker C fuel oil is burned in a furnace or boiler for the generation of heat or used in an engine for the generation of power, carbon dioxide is emitted as a result of combustion. The objective of this study is to investigate $CO_2$ emission characteristics of bunker C fuel oil by sulfur contents. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and $CO_2$ emission factors were determined. The results showed that hydrogen content increases and carbon content decreases by reducing sulfur contents for bunker C fuel oil with sulfur contents less than 1.0%. For sulfur contents between 1.0% and 4.0%, carbon content increases as sulfur content decreases but there is no evident variation in hydrogen content. Net calorific value increases by reducing sulfur contents. $CO_2$ emission factor, which is calculated by dividing carbon content by net calorific value, decreases as sulfur content decreases for bunker C fuel oil with sulfur contents less than 1.0% but it showed relatively constant values for sulfur contents between 1.0% and 4.0%.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.284-284
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• 2010

Currently, hydrogen has been produced by Steam Reforming or partial oxidation reforming processes mainly from oil, coal, and natural gas and results in the production of $CO_2$. However, these are influenced greatly on the green house effect of the earth. so it is important to find the new way to produce hydrogen utilizing water without producing any environmentally harmful by-products. In our research, we use microwave water plasma and photocatalyst to improve dissociation rate of water. At low pressure plasma, electron have high energy but density is low, so temperature of reactor is low. This may cause of recombination in the generated hydrogen and oxygen from splitting water. If it want to high dissociation rate of water, it is necessary to control of recombination of the hydrogen and oxygen using photocatalyst. We utilize the photocatalytic material($TiO_2$, ZnO) coated plasma reactor to use UV in the plasma. The quantity of hydrogen generated was measured by a Residual Gas Analyzer.

• 센서학회지
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• 제5권4호
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• pp.41-46
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• 1996

변압기 절연유중 용존수소를 감지하기 위해 Pd/Pt 게이트 MISFET 센서를 제조하고 그 특성을 조사하였다. 동일 칩안에 내장형 히터와 온도측정용 다이오드를 제조하고 MISFET의 전압 드리프트를 줄이기 위해 차동형구조로 하였다. 수소유입 드리프트를 줄이기 위해, 양쪽 FET의 게이트 절연층을 실리콘 산화막과 실리콘 질화막의 2중 구조로 하였다. 수소감지막의 블리스터를 줄이기 위해 Pd/Pt 2중 금속층을 증착하였다. 제조된 센서의 변압기 절연유에 대한 수소감지 특성은 40mV/10ppm 감도와 0.14mV/day 안정도를 보였다.

• 한국자동차공학회논문집
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• 제1권2호
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• pp.34-41
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• 1993

In order to reduce harmful substances such as particulates and nitric oxides emitted from diesel engine, man kinds of methodology like high pressure spray of diesel fuel oil, exhaust gas recirculation, emulsified fuel usage and dual fuelling have been studied. Dual fuelling of a diesel engine with hydrogen which is well-known as the clean fuel and has excellent combustibility is expected to be effective in reducing harmful substances from diesel engine. This experimental study was conducted to investigate the effect of premixed hydrogen with intake air on the performance and particulate emission characteristics using a single cylinder, prechamber type diesel engine. As a result, it was clarified that a hydrogen-premixed diesel engine can be operated in the state of lower particulate emission and slightly aggravated fuel economy, compared with the conventional diesel engine.