• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.4
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• pp.384-391
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• 2007

Hydrogen-blending effects in flame structure and NO emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane to the blending fuel of methane-hydrogen through $H_2$ molar addition up to 30%. Flame structure, which can be described representatively as a fuel consumption layer and a $H_2$-CO consumption layer, is shown to be changed considerably in hydrogen-blending methane flames, compared to pure methane flames. The differences are displayed through maximum flame temperature, the overlap of fuel and oxygen, and the behaviors of the production rates of major species. Hydrogen-blending into hydrocarbon fuel can be a promising technology to reduce both the CO and $CO_2$ emissions supposing that NOx emission should be reduced through some technologies in industrial burners. These drastic changes of flame structure affect NO emission behavior considerably. The changes of thermal NO and prompt NO are also provided according to hydrogen-blending. Importantly contributing reaction steps to prompt NO are addressed in pure methane and hydrogen-blending methane flames.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.493-502
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• 2012

Syngas laminar burning velocity measurements were carried out at atmospheric pressure and ambient temperature using the Bunsen flame configuration with nozzle burner as a fundamental study on flame stability of syngas fuel. Representative syngas mixture compositions ($H_2$:CO) such as 25:75%, 50:50% and 75:25% and equivalence ratios from 0.5 to 1.4 have been conducted. Average laminar burning velocities have been determined by the stabilized nozzle burner flames using the angle method, radical surface area method and compared with the data obtained from the other literatures. And the results of each experimental methodologies in the various composition ratios and equivalence ratios were coincided with the result of numerical simulation. Especially, it was confirmed that there was necessary to choice a more accurate measurement methodology even the same static flame method for the various composition ratios of syngas fuel including hydrogen. Also, it was reconfirmed that the laminar burning velocities gradually increased with the increasing of hydrogen content in a fuel mixture.

• Nuclear Engineering and Technology
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• v.54 no.8
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• pp.2960-2973
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• 2022

Since Fukushima nuclear power plant (NPP) accident in 2011, the importance of research on various severe accident phenomena has been emphasized. Particularly, detailed analysis of combustion risk is necessary following the containment damage caused by combustion in the Fukushima accident. Many studies have been conducted to evaluate the risk of local hydrogen concentration increases and flame propagation using computational code. In particular, the potential for combustion by local hydrogen concentration in specific areas within the containment has been emphasized. In this study, the process of flame propagation generated inside a reactor core to containment during a loss of coolant accident (LOCA) was analyzed using MELCOR 2.1 code. Later in the LOCA scenario, it was expected that hydrogen combustion occurred inside the reactor core owing to oxygen inflow through the cold leg break area. The main driving force of the oxygen intrusion is the elevated containment pressure due to the molten corium-concrete interaction. The thermal and mechanical loads caused by the flame threaten the integrity of the containment. Additionally, the containment spray system effectiveness in this situation was evaluated because changes in pressure gradient and concentrations of flammable gases greatly affect the overall behavior of ignition and subsequent containment integrity.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.11a
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• pp.393-396
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• 2008

The study of nitrogen dilution effect on flame stability was experimentally investigated in non-premixed turbulent lifted hydrogen jet with coaxial air. hydrogen gas was used as a fuel and coaxial air was injected to make flame liftoff. And both of the fuel jet and coaxial air velocity were fixed as $u_F$=200 m/s and $u_A$=16 m/s, while nitrogen diluents mole fraction was varied from 0 to 0.2. For the analysis of flame structure and flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF had been performed. It was found that the turbulent flame propagation velocity increased as decreasing of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity, even though the mole fraction of nitrogen diluents gas was changed.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.209-214
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• 2003

Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, the radical concentration, the NOx formation in freely propagating $CH_4/O_2/N_2$ flames. The additives used are carbon dioxide and hydrogen chloride which have a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, $CO_2$ addition significantly contributes toward the reduction of flame speed and flame temperature by the physical effect, whereas addition of HCl mainly does by the chemical effect. The impact of HCl addition on the decrease of the radical concentration is about 1.6-1.8 times as large as $CO_2$ addition. Hydrogen chloride addition is higher on the reduction of EINO than $CO_2$ addition because of the chemical effect of HCl.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.42-48
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• 2004

Lean laminar premixed propane and methane flames which were anchored by a hydrogen-pilot flame in a tube were investigated experimentally. The flame shapes were observed by varying mean velocity from 10cm/s to 140cm/s and equivalence ratio from 0.45 to 0.8. In this study, behaviors of flames are divided into five regions such as tail-out, flash-back, flickering, stable and vibrating flames with respect to the mean velocity and the equivalence ratio. Although the flames are unstable in both the flickering and the vibrating region, they have different characteristics such as the frequency, sound generation and creation process of flame curvature. The flickering region exists near the flammability limit and the flame flickers in a frequency of about 10Hz. When flame front is bended, the propane flame front is straightened and the methane flame front is bended more by thermo-diffusive instability. In the vibrating region, the flame vibrates emitting audible sound in a frequency of about 100Hz. In the boundary of vibrating region, the vibration of flame changes between two modes such as single frequency vibration and dual frequency vibration. Increase and decrease of vibration in each mode are determined by thermo-acoustic instability.

• Journal of the Korean Society of Combustion
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• v.5 no.1
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• pp.19-30
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• 2000

The characteristics of NOx emissions in pure hydrogen nonpremixed flames with coaxial air are analyzed numerically for the three model cases of coaxial air flames classified by varying coaxial air velocity and/or fuel velocity. In coaxial air flames, the flame length is reduced by coaxial air and can be represented as a function of the ratio of coaxial air to fuel velocity. Coaxial air decreases flame reaction zone, resulting in reducing flame residence time significantly. Finally, the large reduction of EINOx is achieved by the decrease of the flame residence time. It is found that because coaxial air can break down the flame self-similarity law, appropriate scaling parameters, which are different from those in the simple jet flames, are recommended. In coaxial air flames, the flame residence time based on the flame volume produces better results than that based on a cube of the flame length. And some portion of deviations from the 1/2 scaling law by coaxial air may be due to the violation of the linear relationship between the flame volume and the flame reaction zone.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.261-266
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• 2003

An experimental study has been conducted to evaluate the effects of $CO_{2}$ on heat transfer from hydrogen oxygen-enriched flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which mounted on top of the furnace. Five composition conditions of oxidizer were chosen with replacing $N_{2}$ with $CO_{2}$. In a steady state, total and radiative heat flux rates from the flame to the wall of furnace has been measured using heat flux meters. Temperature distribution in furnace also has been checked. Increasing $CO_{2}$ ratio in the oxidizer, the dominant heat transfer mode was changed into convection from radiation. Temperature in the furnace decreased but total heat flux increased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.8 s.227
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• pp.937-944
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• 2004

An experimental study has been conducted to evaluate the effects of $CO_2$ on heat transfer from oxygen-enriched hydrogen flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which was mounted on top of the furnace. Five different oxidizer compositions were prepared by replacing $N_2$ with $CO_2$. In a steady state, the total as well as radiative heat flux from the flame to the wall of furnace have been measured using a heat flux meter. Temperature distribution in furnace also has been measured and compared. By increasing $CO_2$ proportion in the oxidizer, the convection played a more significant role rather than radiation. Overall temperature in the furnace was seen to be decreased, while the total heat flux has increased.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.11-12
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• 2013

To investigate the effect of an inner diameter of the extension tube on the self-ignition when high pressurized hydrogen abruptly released through a tube, both experimental and numerical approach are used. The result show that there is a possibility to have successful ignition when the tube diameter is decreased even at the pressure that could not give sustainable flame with a larger diameter tube. Numerical simulation show the flame development inside the tube and weak and stretch flame spout the tube for 10.9 mm tube, whereas strong complete flame has been generated for 3 mm tube.