• Journal of Energy Engineering
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• v.26 no.4
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• pp.7-13
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• 2017

As environmental problems become a problem of survival, interest in eco-friendly energy is increasing to improve the environment. So, demand for eco-friendly fuels such as hydrogen, LPG and CNG is increasing. In particular, Korea, which relies on imports of most fuels, is investing in the development of hydrogen energy, which is favorable in terms of high production volume and energy independence. However, As demand grows every year, a variety of accidents occur in various ways, ranging from small leak incidents to massive fires and explosion, thus research needs to be done. So, in this study, compared and analyzed cases of hydrogen, LPG, CNG accidents occurring at domestic and overseas refueling stations. and various programs were used for assessing risk, estimated the flame length due to gas leakage and evaluated the dangerous distance.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.2
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• pp.146-153
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• 2013

CNG buses has contributed to improve air quality in cities. But it is difficult to meet the next emission regulations such as EURO-VI without the help of additional post-processing device. Hydorgen has higher flame speed and lower combustion temperature that make it thermal efficiency increase with leaner operation. Using hydrogen natural gas blend (HCNG) fuel is promising technology which can reduce $NO_x$ and $CO_2$ emissions for a natural gas vehicle. However, fuel flow rate of HCNG should be increased since hydrogen's energy density per volume is much smaller than natural gas. In the present study, the characteristics of fuel supply system and its applicability were evaluated in a heavy duty natural gas engine. The results showed that the potential of fuel pressure regulator and fuel metering valve had enough capacity with HCNG. Employed mixer did not affect the distribution characteristics of mixture.

• International Journal of Automotive Technology
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• v.7 no.4
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• pp.501-508
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• 2006

The effect of chemical additives, such as dimethyl ether(DME), ethanol, carbon disulfide on the soot formation were examined numerically. ill this study, the Frenklach soot mechanism was used as a base mechanism to predict the soot formation in the ethane flame. The combination of Westbrook's DME mechanism, Marinov's ethanol mechanism, and chemical kinetic mechanism for hydrogen sulfide and carbon disulfide flames was made with the base mechanism because the DME, ethanol, $CS_2$ additives are added into the ethane fuel. CHEMKIN code was used as a numerical analysis software to simulate the effect of chemical additives on reduction of the polycyclic aromatic hydrocarbons(PAH's) which are soot precursors. From the numerical results it is observed that addition of DME, ethanol and $CS_2$ into ethane fuel can reduce PAH species significantly. That means theses additives can reduce soot formation significantly. Results also strongly suggest suppression of soot formation by these additives to be mainly a chemical effect. Hand OH radicals may be the key species to the reduction of PAH species for additives.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.209-219
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• 2006

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Different shock tube fill pressures have various inflow conditions. $15^{\circ}$ inclined hydrogen fuel injection is located before the cavity. Oblique shock is generated at the trailing edge of the cavity and reflects off the top and bottom wall. For non-reacting flow, static pressures in low equivalence ratio are similar to those in no fuel injection. As equivalence ratio is increased, static pressures are increased in the duct. In the similar equivalence ratio, static pressures are increased when total enthalpy is decreased. For reacting flow, the flame is occurred near the cavity. The combustion is weak locally in the middle of the duct. The up and down pressure distribution in the duct means that the supersonic combustion is generated.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.249-251
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• 2014

Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4//oxygen$ mixture using two-section porous media combustor. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. $H_2/CO$ ratio and module M from concentration of flue gas measured by Gas Chromatography was similar to those calculated by equilibrium. But it was made sure that the heat loss effect becomes more influential than heat recirculation effect as the mixture gets richer. To generate synthesis gas appropriate for methanol production, insulated pressurized porous media combustor will be designed and built in the future.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.364-367
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• 2005

A series of computational simulations have been carried out for non-reacting and reacting flows in channel-type and divergent scramjet combustor configurations with and without a cavity. Transverse injection of hydrogen is considered with the injection pressure varying from 0.5 to 1.5 MPa. The detailed resolution of the oscillatory flow and flame dynamics are captured at sufficient scale to identify the underlying physical mechanisms, and the role of combustor configuration, cavity and amount of heat addition could be understood.

• YAKHAK HOEJI
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• v.20 no.3
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• pp.125-129
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• 1976

The aim of this investigation was to develop a quantitative gas-liquid chromatographic method of analysis forhyosyamine and scopolamine, and to apply this method to the analysis of preparations. The trimethylsily(TMS) derivatives of the alkaloids were found to be far superior to the nonsilylating compounds in charomatagrams. Bis(trimethylsilyl) acetamide(BSA) was evaluated and found to be a good reagent for silyation of the alkaloids. The optimum derivatization conditions were heating the alkaloids in a closed tube at $70^{\circ)$ for 30 min with a 150 molar excess of BSA to the alkaloids were found to be alkaloids. Calibration curves for the two alkaloids were alkaloid. The standard deviations were 1.1% for hyoscyamine and 1.5% for scopolamine. The minimum detectable amount using the hydrogen flame ionization edtector was determined to be 2$\times$10$^{-11}$ moles of each alkaloid injected.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.152-157
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• 2008

The biodiesel becomes one of the favorite alternative fuel applied to diesel engines. This research aims to understand the physics of spray and combustion characteristics of a biodiesel fuel in a constant volume chamber. For spray visualization, biodiesel was injected into a combustion chamber and a high speed camera was applied at various combustion conditions. To investigate heat-release rates and flame propagations, spark was ignited on a hydrogen fuel for the premixed combustion and then biodiesel was injected directly. In addition, parametric study was made by various geometries of combustion chambers and temperatures of fuels and injection pressures. This technology may contribute to improve the performance of bio-diesel engine and reduce emissions in future.

• Journal of the Korean Society of Combustion
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• v.4 no.2
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• pp.51-62
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• 1999

NOx formation in turbulent flames is strongly coupled with temperature, superequilibrium concentration of O radical, and residence time. This implies that in order to accurately predict NO level, it is necessary to develop sophisticated models able to account for the complex turbulent combustion processes including turbulence/chemistry interaction and radiative heat transfer. The present study numerically investigates the turbulent nonpremixed hydrogen jet flames using the laminar flamelet model. Flamelet library is constructed by solving the modified Peters equations and the turbulent combustion model is extended to nonadiabatic flame by introducing the enthalpy defect. The effects of turbulent fluctuation are taken into account by the presumed joint PDFs for mixture fraction, scalar dissipation rate, and enthalpy defect. The predictive capability of the present model has been validated against the detailed experimental data. Effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

• Journal of the Korean Society of Combustion
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• v.12 no.1
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• pp.21-27
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• 2007

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Different shock tube fill pressures have various inflow conditions. $15^{\circ}$ inclined hydrogen fuel injection is located before the cavity. Oblique shock is generated at the trailing edge of the cavity and reflects off the top and bottom wall. For non-reacting flow, static pressures in low equivalence ratio are similar to those in no fuel injection. As equivalence ratio is increased, static pressures are increased in the duct. In the similar equivalence ratio, static pressures are increased when total enthalpy is decreased. For reacting flow, the flame is occurred near the cavity. The combustion is weak locally in the middle of the duct. The up and down pressure distribution in the duct means that the supersonic combustion is generated.