• 한국수소및신에너지학회논문집
• /
• 제22권3호
• /
• pp.313-318
• /
• 2011

This study is about characteristics of generating efficiency and $NO_x$ emissions of a 30 kW gas engine generator in case of using model biogas with hydrogen addition. In this case, both generating efficiency and $NO_x$ emissions are lower than the case of using urban gas (LNG). However, generating efficiency and $NO_x$ emissions are higher than the case of using model biogas only. It means that adding hydrogen which has a high flame propagation velocity has the possibility to improve the generating efficiency, but simultaneously it is also able to increase the $NO_x$ emissions of a gas engine generator.

• 한국수소및신에너지학회논문집
• /
• 제2권1호
• /
• pp.47-56
• /
• 1990

Pure titanium rods were oxidized by anodic oxidation, furnace oxidation and flame oxidation and used as a electrode in the photodecomposition of water. The maximum photoelectrochemical conversion efficiency(${\eta}$) was found for flame oxidized electrode ($1200^{\circ}C$ for 2 min in air), 0.8 %. Anodically oxidized electrodes have minimum photoelectrochemical conversion efficiencies, 0.3 %. Furnace oxidized electrode ($800^{\circ}C$ for 10min in air) has 0.5% phtoelectrochemical efficiency and shows a band-gap energy of about 2.9eV. The efficiency shows a parallelism with the presence of the metallic interstitial compound $TiO_{O+X}$(X < 0.33) at the metal-semiconductor interface, the thickness of the sub oxide layer and that of the external rutile scale.

• 공업화학
• /
• 제8권1호
• /
• pp.84-91
• /
• 1997

대기압하에서 수소를 첨가한 연소염장치를 이용하여 몰리브덴 기판 위에 다이아몬드 필름을 증착시켰다. 기판 온도의 증가에 따라 핵생성밀도가 증가하였으며, $1000^{\circ}C$ 이상에서는 흑연화되고 이것이 수소 원자에 의해 에칭되었다. $C_2H_2/O_2$ 유량비를 증가시킬수록 핵생성밀도는 증가하였지만 결정형태가 구형화되며 비정질카본이 많이 증착되었다. $H_2$를 첨가하면, 표면 활성도가 향상되어 다이아몬드 핵생성밀도가 증가되었으며, 비정질카본을 에칭시켜 우수한 결정성의 다이아몬드 필름을 얻을 수 있었다. 증착시간을 증가시키면 다이아몬드 필름의 두께가 증가하였다.

• 대한기계학회논문집B
• /
• 제29권1호
• /
• pp.55-62
• /
• 2005

Combustion Characteristics and quenching criteria of micro combustor in various condition was exploited experimentally. Two different gases were used, and various geometric matrixes were considered to figure out quenching characteristic of micro combustor. The micro combustor studied in this study was constant volume, and has cylindrical shape. Geometric parameter of combustor was defined to be combustor height and diameter. The effect of height was exploited parametrically as 1 mm, 2mm and 3mm and the effect of diameter was parameterized to be 7.5mm and 15mm. Three different combustibles. (1) Stoichiometric mixture of methane and are, (2) Stoichiometric mixture of hydrogen and air and (3) Mixture of hydrogen and air with fuel stoichiometry of two were used. Pressure transition during combustion process was recovered. The ratio of maximum pressure to initial pressure responded favorably with the change of height of combustor and the initial pressure, the maximum pressure was also increased. The flame propagation was observed only when a specific condition was satisfied. From the experiment the condition that guarantees stable propagation of flame was tabulated. The tabulated results includes criteria of quenching according to combustor height, combustor diameter, species of fuel and initial pressure.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
• /
• pp.62-68
• /
• 2004

A comprehensive numerical analysis has been carried out for both non-reacting and reacting flows in a scramjet engine combustor with and without a cavity. The theoretical formulation treats the complete conservation equations of chemically reacting flows with finite-rate chemistry of hydrogen-air. Turbulence closure is achieved by means of a k-$\omega$ two-equation model. The governing equations are discretized using a MUSCL-type TVD scheme, and temporally integrated by a second-order accurate implicit scheme. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel/air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the .underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flow-field. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

• 한국추진공학회지
• /
• 제25권4호
• /
• pp.36-42
• /
• 2021

본 연구에서는 리오셀 섬유를 사용하여 연속식 흑연직물을 제조함에 있어, 리오셀 섬유에 phosphoric acid, ammonium phosphate, diammonium hydrogen, triammonium phosphate의 인계난연제를 처리 후 열중량, 푸리에변환적외선분광, C-핵자기공명분광, X-선 회절, 중량 분석을 통해 나타나는 물리적, 화학적 구조 변화에 대하여 고찰하였다. 인계난연제에 의한 열적 거동을 분석을 통해 내염화 공정의 온도, 가스, 처리시간 등에 대한 조건을 설정하였다. 연속식 내염화, 탄화, 흑연화 공정을 통해 인장강도 1,007.19±11.47 N/5 cm와 수율 25.3%의 흑연직물을 제조하였다.

• Nuclear Engineering and Technology
• /
• 제52권12호
• /
• pp.2836-2846
• /
• 2020

During severe nuclear power plant (NPP) accidents, a H₂/CO mixture can be generated in the reactor pressure vessel by core degradation and in the containment as well by molten corium-concrete interaction. In spite of its importance, a state-of-the-art methodology predicting H₂/CO combustion risk relies predominantly on empirical correlations. It is therefore necessary to develop a proper methodology for flammability evaluation of H₂/CO mixtures at ex-vessel phases characterized by three factors: CO concentration, high temperature, and diluents. The developed methodology adopted Le Chatelier's law and a calculated non-adiabatic flame temperature model. The methodology allows the consideration of the individual effect of the heat transfer characteristics of hydrogen and carbon monoxide on low flammability limit prediction. The accuracy of the developed model was verified using experimental data relevant to ex-vessel phase conditions. With the developed model, the prediction accuracy was improved substantially such that the maximum relative prediction error was approximately 25% while the existing methodology showed a 76% error. The developed methodology is expected to be applicable for flammability evaluation in chemical as well as NPP industries.

• 한국수소및신에너지학회논문집
• /
• 제26권2호
• /
• pp.164-169
• /
• 2015

Recent research has focused on alternative fuel to improve engine performance and to comply with emission regulation. Finding an alternative fuel and reducing environment pollution are the main goals for future internal combustion engines. The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched CNG fuel in SI engine and is to clarify the effects of hydrogen enrichment in CNG fuelled engine on exhaust emission and performance. An experimental study was carried out to obtain fundamental data for performance and emission characteristics of hydrogen enrichment in SI engine. The experiment was conducted at 2500 rpm, bmep 2 bar, 4 bar conditions while CNG fuel was mixed with 10, 20 and 30% hydrogen blends. From the experimental results, combustion duration was shortened due to rapid flame propagation velocity of hydrogen and these were attributed to the burning velocity increasing exponentially with increasing hydrogen blending ratio. Hydrogen has much wider flammable limit than methane, gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustion. By adding hydrogen, $CO_2$ and HC were reduced. However, $NO_X$ was increased dut to high rate of heat release for hydrogen substitutions.

• 대한기계학회논문집B
• /
• 제37권9호
• /
• pp.829-836
• /
• 2013

석탄을 개질한 합성천연가스의 조성에 변화가 있을 경우 화염의 연소특성에 대하여 연구하였다. 본 연구의 목적은 동축 공기 합성천연가스 확산화염을 구현하여 연료조성에 따른 화염안정성과 화염구조, 분광특성, 온도분포를 실험적인 방법으로 연구하는 것이다. 각 화염의 분광특성을 관찰하기 위하여 분광기를 사용하였으며 연소장 내 온도측정을 위하여 K 형 열전대를 사용하였다. 연료 분사기 출구속도는 $u_F$ =5~40 m/s 사이에서 조절하였고 공기 분사기 출구속도는 $u_A$ =0~0.43 m/s 사이에서 조절하였다. 연소 동특성에 대한 실험을 통해 합성천연가스에 수소 성분이 증가하면 화염안정화 영역이 증가하고 부상화염 높이가 낮아져 화염길이가 짧아지는 것을 알 수 있었다.

• 한국수소및신에너지학회논문집
• /
• 제17권4호
• /
• pp.362-370
• /
• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.