• Title/Summary/Keyword: Hydrogen dilution

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A Study on Enhancement of Combustion Performance by Dilution of Hydrogen in Heavy-Duty Hydrogen Engine (수소기관의 수소연료의 희석에 의한 역화억제효과에 관한 연구)

  • KIM, S.Y.;KIM, Y.Y.;Kim, Y.T.;LEE, JONG T.
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.4
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    • pp.348-354
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    • 2004
  • Hydrogen gas has several merits such as lower ignition energy, wide flammability and shorter quenching distance. It leads to high thermal efficiency but backfire occurrence. In this study, feasibility of expansion of BFL(Back-Fire Limit) equivalence ratio and combustion characteristics by a dilution of hydrogen fuel are experimently examined by using experimental heavy duty single cylinder hydrogen fueled engine. As results, it is found that BFL equivalence ratio is expanded to rich range and torque is increased.

Development of Bioreactors for Hydrogen-Producing Immobilized Photosynthetic Bacteria(I) : Evaluation of lmmobilized CSTR for Hydrogen Productivity and Effectiveness Factor (광합성 박테리아를 이용한 고성능 수소 생산 고정화 생물반응기의 개발(I) 고정화 연속 교반탱크 반응기에서의 수소 생산성 및 효율인자 평가)

  • 선용호;한정우
    • KSBB Journal
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    • v.8 no.3
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    • pp.243-255
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    • 1993
  • In this study, it was observed that hydrogen Productivity varied with stirrer speed, bead radius, input glucose concentration and dilution rate in a continuous stirred tank reactor in which immobilized R. rubrum KS-301 was used as a hydrogen-producing bacterium The mass transfer resistance due to cell immobilization was also studied. In order to estimate an effectiveness factor, Des of glucose was first obtained, which was subsequently represented by the correlation equation between Dos and Xb, As a result external mass transfer resistance could be neglected for stirrer speeds greater than 400rpn With bead radius increasing, the hydrogen productivity and internal effectiveness factor decreased. With input 91ucose concentration increasing, the hydrogen productivity and interval and external effectiveness factor increased. Although an Internal effectiveness factor was not affected, hydrogen productivity Increased with dilution rate increasing. An overall effectiveness factor remained nearly constant for the dilution rates investigate4 but increased with input 91ucose concentration increasing.

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Biofuel Production by Immobilized Living Cells - Hydrogen Production by Photosynthetic Bacteria - (고정화 미생물에 의한 에너지 생산 - 광합성 박테리아에 의한 수소 생산 -)

  • 조영일;선용호
    • Microbiology and Biotechnology Letters
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    • v.13 no.3
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    • pp.303-309
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    • 1985
  • Continuous production of hydrogen by Ca alginate-immobilized photosynthetic bacteria was studied in a packed-bed bioreactor. The dilution rate and input concentration of carbonaces substrate were selected as operating parameters. To choose the strain for immobilization, hydrogen productivities of Rhodopseudomonas caposulata 10006 and Rhodospirillum rubrum KS-301 were compared through preliminary batch cultures of their free cells: the former was found to show better hydrogen productivity in spite of its lower specific growth rate. For the continuous production of hydrogen by immobilized R capsulata, the optimum dilution rate was about 0.84 h$^{-1}$ . The Immobilized tells gave better hydrogen yield and conversion efficiency than free ones. And a kinetic parameter K'$_{m}$ was determined for the packed-bed bioreactor, being practically constant for a specific range of dilution rates.s.

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Characteristics of the Bioreactors of Hydrogen-producing Immobilized Cells (III) -Hydrogen Production in a Nozzle Loop Reactor- (수소생산 고정화 생물반응기의 특성(III) -루프 반응기에서의 수소 생산-)

  • 이충곤;선용호;한정우;이현순;조영일
    • Microbiology and Biotechnology Letters
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    • v.17 no.6
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    • pp.629-633
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    • 1989
  • In the continuous reactor, the hydrogen production rate and residual glucose concentration were increased with increase of input glucose concentration, dilution rate, and recycle rate. The maximum production rate was 91 mL/Lㆍh at dilution rate 0.4/h, input glucose concentration 5.4g/L, and recycle rate 70/h in this experimental range.

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Surface and Structural Features of a-Si Thin Films Prepared by Various H2/H2+SiH4 Dilution (수소 가스 분율(H2/H2+SiH4)에 따른 비정질 실리콘 박막의 표면 및 구조 분석)

  • Kwon, Jin-Up
    • Journal of the Korean institute of surface engineering
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    • v.44 no.2
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    • pp.39-43
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    • 2011
  • Amorphous silicon thin film was deposited by Plasma Enhanced Chemical Vapor Deposition (PECVD). Each films were prepared in different dilution in the chamber gas. As a result, silicon crystallites and crystal volume fraction was increased with raising the hydrogen dilution in the gas and optical band gap was decreased. Increasement of the hydrogen contents in the chamber affected on surface roughness. In this study, thickness and surface roughness of the a-Si thin film by different hydrogen dilution was investigated by various techniques.

Tribological Behaviors of DLC Thin Films Deposited using Precursor Gas diluted by Hydrogen under Aqueous Environment (수중 환경에서 수소로 희석된 반응 가스를 이용하여 증착된 DLC 박막의 트라이볼로지 거동)

  • Lee, Jin-U;Mun, Myeong-Un;Lee, Gwang-Ryeol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.338-339
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    • 2012
  • This study examined the friction and wear behavior of diamond-like carbon (DLC) films deposited from a radio frequency glow discharge using a hydrogen diluted benzene gas mixture. The DLC films were deposited on Si (100) and polished stainless steel substrates by r.f.-PACVD at hydrogen to benzene ratios, or the hydrogen dilution ratio, ranging from 0 to 2.0. The wear test was carried out in both ambient and aqueous environments using a home-made ball-on-disk type wear rig. The stability of the DLC coating in an aqueous environment was improved by diluting the benzene precursor gas with hydrogen, suggesting that hydrogen dilution during the deposition of DLC films suppress the initiation of defects in the film and improved the adhesion of the coating to the interface.

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The Effect of N2 Dilution on the Flame Stabilization in a Non-Premixed Turbulent H2 Jet with Coaxial Air (질소 희석이 수소 난류확산화염의 화염안정성에 미치는 영향)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.7
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    • pp.477-485
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    • 2009
  • The study of nitrogen dilution effect on the flame stability was experimentally investigated in a non-premixed turbulent lifted hydrogen jet with coaxial air. Hydrogen gas was used as a fuel and coaxial air was used to make flame liftoff. Each of hydrogen and air were injected through axisymetric inner and outer nozzles ($d_F=3.65\;mm$ and $d_A=14.1\;mm$). And both fuel jet and coaxial air velocity were fixed as $u_F=200\;m/s$ and $u_A=16\;m/s$, while the mole fraction of nitrogen diluents gas was varied from 0.0 to 0.2 with 0.1 step. For the analysis of flame structure and the flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF laser diagnostics had been performed. The stabilization point was selected in the most upstream region of the flame base and defined as the point where the turbulent flame propagation velocity was equal to the axial component of local flow velocity. We found that the turbulent flame propagation velocity increased with the decrease of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity and axial strain rate, even though nitrogen diluents mole fraction was changed.

Anodization of $TiO_2$ with Seawater Electrolyte; Evaluation of Hydrogen Production in PEG and Photocatalytic Cr(VI) Reduction (해수전해질을 이용한 양극산화 $TiO_2$ 제조; 광전기화학적 수소제조 및 Cr(VI) 환원처리 연구)

  • Shim, Eun-Jung;Park, Min-Sung;Her, A-Young;Joo, Hyun-Ku;Yoon, Jae-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.404-409
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    • 2009
  • The present works were performed that titanium foil was anodized in various dilution ratios of seawater and distilled water with 10V external voltage applied, then annealed at $450^{\circ}C$ to obtain $TiO_2$ on the Ti substrate. The prepared samples were characterized by instruments (XRD, SEM, and photocurrent) and used to investigate rate of hydrogen production in photoelectrochemical cell as well as Cr(VI) reduction. As the results of experiments, the anodized $TiO_2$ in seawater electrolytes, which are ranged from 15 to 50 times dilution of seawater, was showed a relatively higher hydrogen production (ca. 97~110 umol/hr-$cm^2$) and Cr(VI) reduction (ca. 95% reduction).

Fabrication of $TiO_2$ Electrode with Seawater; Production of Hydrogen and Cr(VI) Reduction (해수전해질을 활용한 광전극제조 및 광활성 평가)

  • Shim, Eun-Jung;Park, Min-Sung;Her, A-Young;Joo, Hyun-Ku;Yoon, Jae-Kyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.226-229
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    • 2009
  • The present works were performed that titanium foil was anodized in various dilution ratios of seawater and distilled water with 10V external voltage applied, then annealed at $450^{\circ}C$ to obtain $TiO_2$ on the Ti substrate. The prepared samples were characterized by instruments (XRD, SEM, and photocurrent) and used to investigate rate of hydrogen production in photoelectrochemical cell as well as Cr(VI) reduction. As the results of experiments, the anodized $TiO_2$ in seawater electrolytes, which are ranged from 15 to 50 times dilution of seawater, was showed a relatively higher hydrogen production (ca. 97~110 umol/hr-$cm^2$) and Cr(VI) reduction (ca. 95% reduction).

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Effects of Volatile Solid Concentration and Mixing Ratio on Hydrogen Production by Co-Digesting Molasses Wastewater and Sewage Sludge

  • Lee, Jung-Yeol;Wee, Daehyun;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.24 no.11
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    • pp.1542-1550
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    • 2014
  • Co-digesting molasses wastewater and sewage sludge was evaluated for hydrogen production by response surface methodology (RSM). Batch experiments in accordance with various dilution ratios (40- to 5-fold) and waste mixing composition ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100, on a volume basis) were conducted. Volatile solid (VS) concentration strongly affected the hydrogen production rate and yield compared with the waste mixing ratio. The specific hydrogen production rate was predicted to be optimal when the VS concentration ranged from 10 to 12 g/l at all the mixing ratios of molasses wastewater and sewage sludge. A hydrogen yield of over 50 ml $H_2/gVS_{removed}$ was obtained from mixed waste of 10% sewage sludge and 10 g/l VS (about 10-fold dilution ratio). The optimal chemical oxygen demand/total nitrogen ratio for co-digesting molasses wastewater and sewage sludge was between 250 and 300 with a hydrogen yield above 20 ml $H_2/gVS_{removed}$.