• Journal of Environmental Health Sciences
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• v.30 no.2
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• pp.149-153
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• 2004

The influences of pH on hydrogen production were also investigated over the pH range from 4.1 to 8.0 at HRT 10 hours. The hydrogen content for the produced gas was changed from 41 to 71% with corresponding pHs throughout this experiment. The produced hydrogen/carbon dioxide ratio was not vary significantly up to 6.0, then steepenly increased with increases in the pH. The maximal hydrogen yield was found to be 3.16 $\ell$/g sucrose at pH 5.0. Acetate production yield increased with increased pH, but butyrate production yield decreased with increased pH. Biomass yield increased with increased pH.

• Nuclear Engineering and Technology
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• v.51 no.7
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• pp.1749-1757
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• 2019

Predicting lower flammability limits (LFL) of hydrogen has become an ever-important task for safety of nuclear industry. While numerous experimental studies have been conducted, LFL results applicable for the harsh environment are still lack of information. Our aim is to develop a calculated non-adiabatic flame temperature (CNAFT) model to better predict LFL of hydrogen mixtures in nuclear power plant. The developed model is unique for incorporating radiative heat loss during flame propagation using the CNAFT coefficient derived through previous studies of flame propagation. Our new model is more consistent with the experimental results for various mixtures compared to the previous model, which relied on calculated adiabatic flame temperature (CAFT) to predict the LFL without any consideration of heat loss. Limitation of the previous model could be explained clearly based on the CNAFT coefficient magnitude. The prediction accuracy for hydrogen mixtures at elevated initial temperatures and high helium content was improved substantially. The model reliability was confirmed for $H_2-air$ mixtures up to $300^{\circ}C$ and $H_2-air-He$ mixtures up to 50 vol % helium concentration. Therefore, the CNAFT model developed based on radiation heat loss is expected as the practical method for predicting LFL in hydrogen risk analysis.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2022.11a
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• pp.160-161
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• 2022

Hydrogen is bridge fuel with high energy content and environmentally friendly to satisfy the stringent IMO regulation relating to greenhouse gas (GHG) emissions. There is growing interest in hydrogen in numerous nations and regions illustrated by an extensive range of research and development in technology. Regarding maritime applications, researchers have recognized the utilization of hydrogen as a fuel for fuel cells, a device that converts the chemical energy of the fuel to electrical energy. Solid oxide fuel cell (SOFC), with high working temperature, is easy to combine with the waste heat recovery cycles/devices to increase output power and thermodynamic performances as well. Furthermore, the cold energy from liquid hydrogen supplied to SOFC can also be used to generate more power. In this study, we proposed a SOFC integrated system with the idea of combining the waste heat recovery from the SOFC exhaust stream and cold energy utilization from LH₂. The designation is aimed to target small-scale vessel which uses electric propulsion for short distances voyage.

• Journal of the Korean Electrochemical Society
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• v.3 no.1
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• pp.19-24
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• 2000

It is increasingly necessary to use poly-Si n's as high resolution and integration of Tn for LCD. Excimer Laser Crystallization (ELC) of a-Si is mainly used as a low temperature process. But the ELC method for the fabrication of poly-Si has the eruption problems associated with hydrogen in the a-Si film. So we need a dehydro-genation process additionally. Hydrogen in a-Si film can degrade the quality of poly-Si film and electrical properties of device due to the hydrogen eruption and voids which occur during the excimer laser annealing. In this study, we propose mesh-type PECVD as the a-Si film deposition method for achieving the low concentration hydrogen. Mesh-type PECVD was found to reduce the hydrogen content substantially. We could obtain a as-deposited a-Si film with hydrogen contents less than $1\%$ at $300^{\circ}C$. We also investigated the behavior by XeCl excimer laser annealing of a-Si fabricated by mesh-type PECVB. As a result, we were able to confirm the broad process window in contrast to the narrow process range typically obtained in ELC. Hydrogen eruption was not observed in poly-Si films after ELC These results suggests that mesh-type PECVD is a viable method to achieve the low hydrogen content a-Si and improve the process windows for ELC.

• Journal of Biosystems Engineering
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• v.20 no.3
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• pp.299-306
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• 1995

This study was carried to find out relationships between water content and sugar content in fruit and vegetables and present the possibility of estimating sugar content by measuring water content. Water content and sugar content of melons, peaches, and apples were measured. Both F-test and linear regression analysis on the experimental data were done. The regression models were developed and validated. The results were summarized as follow : 1. According to the F-test, the coefficients of determinant were greater than 0.8, and significance probability was less than 0.0001 in each materials. 2. According to the regression analysis of melons, peaches, and apples, the standard errors of calibration(SEC) were 0.67 brix%, 0.82 brix%, and 0.72 brix%, respectively. 3. The standard errors of prediction(SEP) were 0.76 brix%, 1.03 brix%, and 0.77 brix%, respectively. 4. The relationship between sugar content and water content in apple was successfully applied to measure the sugar content from hydrogen NMR spectrum of apple samples.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.7
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• pp.627-633
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• 2011

Performance of a hydrogen generator for a fuel cell unmanned aircraft was evaluated as the change of temperature environment. Sodium borohydride ($NaBH_4$) was used as a hydrogen source due to its high hydrogen content and good storability. The hydrogen gas was generated by the hydrolysis reaction using a catalytic reactor. Reaction chambers were set up with the range of temperatures from -20 to $60^{\circ}C$. The hydrogen generation rate and temperatures changes of reactor and separator were measured at the $NaBH_4$ concentrations of 20 and 25wt.%. As a result, the hydrogen generation rate was decreased as the repeated reaction cycles. It showed that the hydrogen generation rate was stable at low temperature, while at high temperature the hydrogen generation rate was rapidly decreased. The performance degradation was mainly caused by the catalyst loss and $NaBO_2$ deposition on the catalyst surface.

• The Korean Journal of Ceramics
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• v.4 no.4
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• pp.279-285
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• 1998

The $UO_2$ pellets are usually sintered under hydrogen gas atmosphere. Hydrogen gas may cause unexpected early failure of the refractory bricks in the sintering furnace. In this work, nitrogen was mixed with hydrogen to investigate the effect of nitrogen gas on a failure machanism of the refractory bricks and on the microstructure of the $UO_2$ pellet. The hydrogen-nitrogen mixed gas experiments show that the larger nitrogen the mixed gas contains, the less the refractory materials are reduced by hydrogen. The weight loss measurements at $1400^{\circ}C$ for fire clay and chamotte refractories containing high content of $SiO_2$ indicate that the weight loss rate for the mixed gas is about half of that for the hydrogen gas. Based on the thermochemical analyses, it is proposed that the weight loss is caused by hydrogen-induced reduction of free $SiO_2$ and/or $SiO_2$ bonded to $Al_2O_3$ in the fire clay and chamotte refractories. However, the retardation of the hydrogen-induced $SiO_2$ reduction rate under the mixed gas atmosphere may be due to the reduction of the surface reaction rate between hydrogen gas and refractory materials in proportion to volume fraction of nitrogen gas in the mixed gas. On the other hand, the mixed gas experiments show that the test data for $UO_2$ pellet still meet the related specification values, even if there exists a slight difference in the pellet microstructural parameters between the cases of the mixed gas and the hydrogen gas.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.199-204
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• 2006

We manufactured the metal hydrides of $(Ti_{0.88}Mg_{0.12})H_2$ using a very easy and cheap way that Ti-12%Mg blending powder was mechanically milled with liquid milling media such as isopropyl alcohol ($C_3H_8O$, containing oxygen) and hexane ($C_6H_{14}$, no oxygen) as hydrogen source. The $(Ti_{0.88}Mg_{0.12})H_2$ synthesized in isopropyl alcohol contained the high oxygen of 11.2%, while one in hexane had the low oxygen content of 0.7%. Such a difference of oxygen content affected the dehydriding behavior, phase transformation, and microstructural evolution at high temperature, which was investigated through X-ray diffraction and DSC measurements, and electron microscope observations.

• Nuclear Engineering and Technology
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• v.46 no.3
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• pp.423-430
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• 2014

An in-pile performance test of HANA claddings was conducted at up to 67 GWD/MTU in the Halden research reactor in Norway over a 6.5 year period. Four types of HANA claddings (HANA-3, HANA-4, HANA-5, and HANA-6) and a reference Zircaloy-4 cladding were used for the in-pile test. The evaluation parameters of the HANA claddings were the corrosion behavior, dimensional changes, hydrogen uptake, and tensile strength after the claddings were tested under the simulated operation conditions of a Korean commercial reactor. The oxide thickness ranged from 15 to 37 mm at a high flux region in the test rods, and all HANA claddings showed corrosion resistance superior to the Zircaloy-4 cladding. The creep-down rate of all HANA claddings was lower than that of the Zircaloy-4 cladding. In addition, the hydrogen content of the HANA claddings ranged from 54 to 96 wppm at the high heat flux region of the test rods, whereas the hydrogen content of the Zircaloy-4 cladding was 119 wppm. The tensile strength of the HANA and Zircaloy-4 claddings was similarly increased when compared to the un-irradiated claddings owing to the radiation-induced hardening.

• Journal of Hydrogen and New Energy
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• v.27 no.5
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• pp.494-502
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• 2016

A 1-dimensional heterogeneous reactor model with the gas-solid interfacial phase gradients was developed for the simulation of the packed bed reactor where the exothermic reversible water gas shift reaction for the natural gas steam reformed gas was proceeding in adiabatic mode. Experimental results obtained over the WGS catalyst, C18-HA, were best simulated when the frequency factor of the reaction rate constant was adjusted to a half the value reported over another WGS catalyst, EX-2248, having the same kinds of active components as the C18-HA. For the reactor of the inside diameter 158.4 mm and the bed length 650 mm, the optimum feeding temperature of the reformed gas was simulated to be $194^{\circ}C$, giving the lowest CO content in the product gas by 1.68 mol% on the basis of dried gas. For reactors more extended in the bed length, the possible lowest CO content in the product gas with the optimum feeding temperature of the reformed gas were suggested.