• 한국수소및신에너지학회논문집
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• 제28권1호
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• pp.9-16
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• 2017

Hydrogen forms metal hydrides with some metals and alloys leading to solid-state storage under moderate temperature and pressure that gives them the safety advantage over the gas and liquid storage methods. However, it has disadvantages of slow hydrogen adsorption-desorption time and low thermal conductivity. To improve characteristics of metal hydrides, it is important that activation and thermal conductivity of metal hydrides are improved. In this study, we have been investigated hydrogen storage properties of Hydralloy C among Ti-Mn alloys. Also, the characteristics of activation and thermal conductivity of Hydralloy C were enhanced to improve kinetics of hydrogen adsorption-desorption. As physical activation method, PHEM (planetary high energy mill) was performed in Ar or $H_2$ atmosphere. Hydralloy C was also activated by $TiCl_3$ catalyst. To improve thermal conductivity, various types of ENG (expanded natural graphite) were used. The prepared samples were compacted at pressure of 500 bar. As a result, the activation properties of $H_2$ PHEM treated Hydralloy C was better than the other activation methods. Also, the amounts of hydrogen storage showed up to 1.6 wt%. When flake type ENG was added to Hydralloy C, thermal conductivity and hydrogen storage properties were improved.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.90-97
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• 2006

Hydrogen is used as a chemical feedstock in several important industrial processes, including oil refineries and petro-chemical production. But, nowadays hydrogen is focused as energy carrier on the rising of problems such as exhaustion of fossil fuel and environmental pollution. Thermochemical hydrogen production by nuclear energy has potential to efficiently produce large quantities of hydrogen without producing greenhouse gases, and research of nuclear hydrogen, therefore, has been worked with goal to demonstrate commercial production in 2020. The oil refineries and petro-chemical plant are very large, centralized producers and users of industrial hydrogen, and high-potential early market for hydrogen produced by nuclear energy. Therefore, it is essential to investigate and analyze for state of domestic hydrogen market focused on industrial users. Hydrogen market of petro-chemical industry as demand site was investigated and worked for demand forecast of hydrogen in 2020. Also we suggested possible supply plans of nuclear hydrogen considered regional characteristics and then it can be provided basis for determination of optimal capacity of nuclear hydrogen plant in 2020.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.330-338
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• 2002

A long-term energy system in the future is expected to be based on the ideal circulation system between water and hydrogen in the sense that the hydrogen prepared from water eventually returns to water again after its use. Currently, with respect to the hydrogen energy system, it is predicted that the turning-point at which the production cost of hydrogen will become to be lower than that of fossil fuels would be after 2010. However, fuel cell technology would be able to be practically used for the applications to the transportation vehicles and small-scale power sources from 2004, and therefore, an efficient construction of the infrastructure covering hydrogen production and supply systems would be required with short-/mid-term technologies for the $CO_2$ reduction associated with fossil fuel utilization. In this paper, the hydrogen quantity available in domestic market has been estimated focusing on the hydrogen by-produced from domestic industries, and also the infrastructure for hydrogen-driven vehicles like fuel cell cars has been reviewed.

• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.204-213
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• 2002

In this work, hydrogen production by a 2-step water-spritting thermochemical cycle based on metal oxides redox pairs was investigated on the bases of the thermodynamics and technical feasibility. Also, a 2nd-law analysis performed on the closed cyclic process indicates a maximum exergy conversion efficiency of 7.1% when using a solar cavity-receiver operated at 2300K and air/Fe3O4 molar ratio = 10.

• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 추계 총회 및 학술발표회
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• pp.119-123
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• 2005

The thermochemical splitting of water has been proposed as a clean method for hydrogen production. The IS process is one of the thermochemical water splitting processes using iodine and sulfur as reaction agents. HI decomposition procedure to obtain hydrogen is one of the key operations in the process, because equilibrium conversion of HI is low (22% at $450^{\circ}C$). The silica membranes prepared by CVD. method were applied to the decomposition reaction of HI vapor. The permeation characteristics of hydrogen and nitrogen belong to the Knudsen flow pattern.

• 한국수소및신에너지학회논문집
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• 제13권1호
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• pp.90-99
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• 2002

In order to utilize hydrogen energy in a large-scale in the future, development of effective hydrogen storage method is essentially required as well as that of efficient hydrogen production method. The hydrogen storage method using metal hydrides has been holding the spotlight as a safer and higher-density hydrogen storage method than conventional hydrogen storage methods such as liquid hydrogen or compressed hydrogen storage method. However when metals react with hydrogen to store hydrogen as metal hydrides, they undergo exothermic reactions, while metal hydrides evolve hydrogen by endothermic reaction. Therefore, hydrogen storage tank should have such structure that it can absorb or release reaction heat rapidly and efficiently. In this study, a review on the improvement of the heat release and absorption structure in the hydrogen storage tank was conducted, and as a result, a new type of hydrogen storage tank with the structure of vertical-type wall was designed and manufactured. Experimental results showed that this new type of tank could be used as an efficient hydrogen storage tank because its structure is simpler and manufacture is easier than cup-type hydrogen storage tank with the structure of packed horizontal cup.

• 한국수소및신에너지학회논문집
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• 제12권1호
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• pp.65-73
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• 2001

Carbon nanotubes were prepared by catalytic decomposition of $CH_4$ using Ni-MgO catalyst at various temperatures. $H_2$ effect on crystallinity and morphology during the synthesis of carbon nanotubes was investigated. The crystallinity and morphology were characterized by SEM, TEM, XRD, TGA, and Raman spectroscopy. In addition, the hydrogen adsorption properties were evaluated by PCT measurement in a hydrogen pressure range between 1 and 120 bar. The optimal synthesis temperature of carbon nanotubes was elevated in the presence of $H_2$, although significant difference of carbon nanotube morphology was not found. It is believed that hydrogen served as self-cleaner mops the amorphous carbon on the catalyst surface. It is proved that the carbon nanotubes have multi-walled structure, short length with a outer diameter of 20 ~40nm and open tips after elimination of the catalyst. The amount of hydrogen adsorbed in carbon nanotubes is increased as the pressure of hydrogen is increased and reaches 1.3 wt % under the hydrogen pressure of 120 bar at room temperature.

• 한국수소및신에너지학회논문집
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• 제33권5호
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• pp.463-469
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• 2022

After reviewing the current status of hydrogen buses and hydrogen charging stations in the United States, as well as related laws and programs, it was found that the federal and state governments supported the supports of hydrogen buses and the deployment of hydrogen charging infrastructure through various policies and programs. In order to promote the spread of domestic and overseas hydrogen buses and hydrogen charging infrastructure, it is necessary to develop and apply various legal systems and programs that can provide incentives to hydrogen bus manufacturers, hydrogen charging station installers, hydrogen bus operating organizations and entities. It is necessary to develop and apply various legal systems and programs that can provide incentives to hydrogen bus manufacturers, hydrogen charging station installers, hydrogen bus operating organizations and entities.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.565-572
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• 2021

Hydrogen is currently produced from natural gas reforming or industrial process of by-product over than 90%. Additionally, there are green hydrogens based on renewable energy generation, but the import of green hydrogen from other countries is being considered due to the output variability depending on the weather and climate. Due to low density of hydrogen, it is difficult to storage and import hydrogen of large capacity. For improving low density issue of hydrogen, the gaseous hydrogen is liquefied and stored in cryogenic tank. Density of hydrogen increase from 0.081 kg/m³ to 71 kg/m3 when gaseous hydrogen transfer to liquid hydrogen. Density of liquid hydrogen is higher about 800 times than gaseous. However, since density and boiling point of liquid hydrogen is too lower than liquefied natural gas approximately 1/6 and 90 K, to store liquid hydrogen for long-term is very difficult too. To overcome this weakness, this paper introduces storage method of hydrogen based on liquid/solid (slush) and facilities for producing slush hydrogen to improve low density issue of hydrogen. Slush hydrogen is higher density and heat capacity than liquid hydrogen, can be expected to improve these issues.

• 한국수소및신에너지학회논문집
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• 제26권2호
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• pp.105-113
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• 2015

In order to accelerate hydrogen society in current big renewable energy trend, it is very important that hydrogen can be transported and stored as a fuel in efficient and economical fashion. In this perspective, liquid hydrogen can be considered as one of the most prospective storage methods that can bring early arrival of the hydrogen society by its high gravimetric energy density. In this study, a small-scale hydrogen liquefier has been designed and developed to demonstrate direct hydrogen liquefaction technology. Gifford-McMahon (GM) cryocooler was employed to cool warm hydrogen gas to normal boiling point of hydrogen at 20K. Various cryogenic insulation technologies such as double walled vacuum vessels and multi-layer insulation were used to minimize heat leak from ambient. A liquid nitrogen assisted precooler, two ortho-para hydrogen catalytic converters, and highly efficient heat pipe were adapted to achieve the target liquefaction rate of 1L/hr. The liquefier has successfully demonstrated more than 1L/hr of hydrogen liquefaction. The system also has demonstrated its versatile usage as a very efficient 150L liquid hydrogen storage tank.