• 한국수소및신에너지학회논문집
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• 제24권3호
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• pp.242-248
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• 2013

The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched LPG fuel in LPG engine and is to clarify the effects of hydrogen enrichment in LPG fuelled engine on exhaust emission and performance. An experimental study was carried out to obtain fundamental data for performance and emission characteristics of hydrogen enrichment in LPG engine. The research was held by changing the hydrogen ratio to 0, 5, 10, 20% in 1500rpm, bmep 2 and 4bar. The result turned out that the combustion duration was shortened due to fast flame propagation of hydrogen. And the amount of Carbon dioxide and Hydrocarbon decreased. However, the amount of NOX increased, which is thought to be the result of high adiabatic flame temperature of hydrogen. It has been confirmed that this phenomenon has changed by the Hydrogen mixing ratio.

• 한국분말재료학회지
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• 제13권5호
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• pp.336-339
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• 2006

Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as pain size (or particle size), internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary fur a significant improvement in magnetic properties. In the present work, nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated from the powder mixtures of (99.9% purity) $FeCl_2$ and $CoCl_2$ by chemical solution mixing and hydrogen reduction.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2011년도 후기공동학술대회 논문집
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• pp.88-89
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• 2011

The study on synthesis of carbon nanomaterials by H2 mixing in counterflow methane diffusion flames has been experimentally conducted. We have also investigated on effect of catalyst and temperature in flame. The counterflow flame was formed by many kind of gas (fuel side using $CH_4-H_2-N_2$ and oxidizer side $N_2-O_2$) and nitrogen shields discharge on each other side to cut off oxidizer of the atmosphere. Ferrocene was used as a metal catalyst for CNTs synthesis. substrate was used to deposit carbon nanomaterials and these were analyzed by FE-SEM. We could find that carbon nanotubes and many kind of carbon nano materials were formed in Cu wire substrate, through this experiment.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.503-511
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• 2018

There have been many studies of combustion in the circulating fluidized bed. However, little study is available for combustion of wood pellet together fed with wood chip. The mixed ratio of two fuels is an useful information when thermal power company would receive the Renewable Energy Portfolio Standard (RPS) from government. In this study, the combustion behavior and kinetics of such biomass fuels are evaluated using fluidized bed reactor and thermogravimetric analyzers. The mixing ratio of wood chip relative to wood pellet was varied at different temperatures. The results show that a combustion reactivity changed significantly at the wood chip mixing ratio of 40%, particularly at low temperature condition.

• 한국대기환경학회지
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• 제31권2호
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• pp.173-180
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• 2015

The purpose of this study was to fabricate a ferric nitrate impregnated activated carbon, and the performance for hydrogen sulfide by adsorption was evaluated. Sodium hydroxide was utilized to control pH in the process during generation of ferric hydroxide on the surface of the carbon. Critical mixing duration for generation of ferric hydroxide on the carbon was 48 hrs at pH 1 of the solution, in which the chemical adsorption of hydrogen sulfide was enhanced. The adsorption capacity of the impregnated carbon increased up to 0.10 g hydrogen sulfide/g carbon, which was 4.3 times higher than that of the raw carbon. Presence of FeOOH on the surface of the impregnated carbon was examined by X-ray diffraction.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.153-158
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• 2012

The hydrogenation of $AlB_2$-type BaGaGe exhibits a metal to insulator (MI) transition, inducing a puckering distortion of the original hexagonal [GaGe] layers. We investigate the electronic structure changes associated with the hydrogen-induced MI transition, using extended H$\ddot{u}$ckel tight-binding band calculations. The results indicate that hydrogen incorporation in the precursor BaGaGe is characterized by an antibonding interaction of $\pi$ on GaGe with hydrogen 1s and the second-order mixing of the singly occupied antibonding $\pi^*$ orbital into it, through Ga-H bond formation. As a result, the fully occupied bonding $\pi$ band in BaGaGe changes to a weakly dispersive band with Ge pz (lone pair) character in the hydride, which becomes located just below the Fermi level. The Ga-Ge bonds within a layered polyanion are slightly weakened by hydrogen incorporation. A rationale for this is given.

• 한국표면공학회지
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• 제37권5호
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• pp.243-248
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• 2004

A palladium-nikel(Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support formed with nickel powder. Plasma surface treatment process is introduced as pre-treatment process instead of HCI activation. Pd coating layer was prepared by dc magnetron sputtering deposition after $H_2$ plasma surface treatment. Palladium-nickel alloy composite layer had a fairly uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature of 773 K and pressure of 2.2psi. The hydrogen permeance was 6 ml/minㆍ$\textrm{cm}^2$ㆍatm and the selectivity was 120 for hydrogen/nitrogen($H_2$/$N_2$) mixing gases at 773 K.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.86-94
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• 2006

This paper investigates the effects of acoustic forcing on NOx emissions and mixing process in the near field region of turbulent hydrogen nonpremixed flames. The resonance frequency was selected to force the coaxial air jet acoustically, because the resonance frequency is effective to amplify the forcing amplitude and reduce NOx emissions. When the resonance frequency is acoustically excited, a streamwise vortex is formed in the mixing layer between the coaxial air jet and coflowing air. As the vortex develops downstream, it entrains both ambient air and combustion products into the coaxial air jet to mix well. In addition, the strong vortex pulls the flame surface toward the coaxial air jet, causing intense chemical reaction. Acoustic excitation also causes velocity fluctuations of coaxial air jet as well as fuel jet but, the maximum value of centerline fuel velocity fluctuation occurs at the different phases of $\Phi$=$180^{\circ}$ for nonreacting case and $\Phi$=$0^{\circ}$ for reacting case. Since acoustic excitation enhances the mixing rate of fuel and air, the line of the stoichiometric mixture fraction becomes narrow. Finally, acoustic forcing at the resonance frequency reduces the normalized flame length by 15 % and EINOx by 25 %, compared to the flame without acoustic excitation.

• 한국수소및신에너지학회논문집
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• 제20권4호
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• pp.265-273
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• 2009

Proton Exchange Membrane Fuel Cell (PEMFC) has low operating temperature and high efficiency. And PEMFC consists of many components as bipolar plate, gas diffusion layer, membrane etc.. Flow-field in bipolar plate roles path for transporting reactants to membrane. Therefore a design of flow-field has an effect on PEMFC's performance. In this study, Computational Fluid Dynamics (CFD) simulations were performed for comparing mixed multiple serpentine (MMS) flow-field and multiple serpentine (MS) flow-field. And we studied an effect according to change mixing region design in MMS flow-field. Finally the applicability of results is verified by performing CFD simulation about fixed MMS flow-field which is combined good designs.

• 한국수소및신에너지학회논문집
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• 제20권2호
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• pp.161-167
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• 2009

The regulation of the $CO_2$ emit from vehicles have become much more stringent in recent years. This stringent regulation is more request vehicle manufacturers to develop the alternative fuel vehicles for reducing exhaust emissions. LPG fuel is more clean energy compares with gasoline and diesel fuel. Especially, $CO_2$ emission of LPG Vehicle is less than gasoline vehicle and almost equal to diesel vehicle. For this reason, recently korean government is extending LPG fuel for hybrid car and light duty vehicle. In domestic, Propane is mixing $15{\sim}30%$ to butane for improvement of cold start at winter season. Therefore, In this paper was investigated that the characteristics of emissions according to propane mixing rate with 0, 10, 20, 30% were compared and analyzed by the vehicle test using LPG vehicle according to the FTP75 mode. It was also investigated the characteristics of nano-particle emit with propane mixing rate.