• Title/Summary/Keyword: Hydrogen Mixing

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Measurements of Transient Mixing Concentrations between Solid Powder and Liquid Fuel (고체분말/액체연료의 과도혼합 농도 분포 측정)

  • Doh, Deoghee;Yum, Jooho;Cho, Gyeongrae;Min, Seongki;Kim, Myungho;Ryu, Gyongwon;Yoo, Namhyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.6
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    • pp.678-687
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    • 2012
  • Concentration fields of solid powder in a liquid fuel were quantitatively measured by a visualization technique. The measurement system consists of a camcoder and three LCD monitors. The solid powder (glass powder) were filled in a head tank which was installed over a main mixing tank ($D{\times}H$, $310{\times}370mm$). The main mixing tank was filled with JetA1 fuel oil. With a sudden opening of the upper tank by pressurized nitrogen gas with 1.9 bar, the solid powder were poured into the JetA1 oil. An impeller type agitator was being rotated in the mixing with 700 rpm for the enhancements of mixing. Uniform visualization for the mixing flow field was made by the light from the three LCD monitors, and the visualized images were captured by the camcoder. The color images captured by the camcoder The color information of the captured images was decoded into three principle colors R, G, and B to get quantitattive relations between the concentrations of the solid powder and the colors. To get better fitting for the strong non-linearity between the concentration and the color, a neural network which has strong fitting performances was used. Analyses on the transient mixing of the solid powders were quantitatively made.

Dynamic thermal Design of a 1-ton Class Bio-Hydrogen Production System Simulator Using Industrial Waste Heat and by-Products (산업배열 및 부산물을 활용한 1톤급 바이오수소 생산 시뮬레이터 동적 열설계)

  • Kim, Hyejun;Kim, Seokyeon;Ahn, Joon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.5
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    • pp.259-268
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    • 2017
  • This paper proposes a hydrogen-based social economy derived from fuel cells capable of replacing fossil fuels and resolving global warming, It thus provides an entry for developing economically feasible social configurations to make use of bio-hydrogen production systems. Bio-hydrogen production works from the principle that microorganisms decompose water in the process of converting CO to $CO_2$, thereby producing hydrogen. This study parts from an analysis of an existing 157-ton class NA1 bio-hydrogen reactor that identifies the state of feedstock and reactor conditions. Based on this analysis, we designed a 1-ton class bio-hydrogen reactor process simulator. We carried out thermal analyses of biological heat reactions, sensible heat, and heat radiation in order to calculate the thermal load of each system element. The reactor temperature changes were determined by modeling the feed mixing tank capacity, heat exchange, and heat storage tank. An analysis was carried out to confirm the condition of the feed mixing tank, heat exchanger, heat storage tank capacity as well as the operating conditions of the system so as to maintain the target reactor temperature.

Basic Study of Spray-Behavior Characteristics of Emulsified Fuel (에멀젼연료의 분무거동특성에 관한 기초연구)

  • Yeom, Jeong Kuk;Yoon, Jeong Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.9
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    • pp.763-771
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    • 2014
  • As a preliminary study on the spray behavior characteristics of emulsified fuel, the fuel properties (viscosity, surface tension, and density) and evaporation characteristics of a fuel droplet were investigated. The emulsified fuel was made by mixing diesel and $H_2O_2$. In addition, the macroscopic spray behavior characteristics such as the spray penetrations and spray angles of the emulsified and diesel fuels were compared. The stirring condition of the emulsified fuel was a 9:1 mixture of the diesel fuel and the surfactant span 80. The mixing ratios for the hydrogen peroxide were set at EF2, EF12, EF22, EF32, EF42, EF52, EF62, EF72, EF82, and EF92. The injection pressures were set at 400, 600, 800, and 1000 bar. We found that as the mixing ratio of the hydrogen peroxide was increased from EF2 to EF52, the viscosity of the emulsified fuel increased. However, afterward, the viscosity of the emulsified fuel gradually decreased and approached the viscosity value of the diesel fuel. Therefore, generally oil-in-water emulsions were used for the hydrogen peroxide mixing ratios up to 52 (EF52), and water-in-oil emulsions were used for the hydrogen peroxide mixing ratios above 52. Finally, the spray behavior characteristics (spray penetration and spray angle) of the emulsified fuel were found to be almost independent of the mixing ratio.

Study on Fuel Characteristics Depending on Mixing Ratio of Bio-Butanol and Bio-Ethanol (바이오부탄올, 바이오에탄올 혼합비율에 따른 연료적 특성 연구)

  • KIM, SHIN;KIM, JAE-KON;PARK, CHEON-KYU;HA, JONG-HAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.704-711
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    • 2017
  • Korea, which has a high dependency on energy imports, is greatly affected by fluctuations in international oil prices. In order to offset these effects, various policies such as 'diversification of energy sources' and 'energy mix' are being pursued. Renewable Fuel Standard (RFS) is a policy promoted for this purpose, and a compulsory mixing system is applied only to the diesel. In order to reduce dependence on fossil fuels in various countries, they are concentrating on the dissemination of bio-alcohol as well as bio-diesel, and commercialization through various verification. In this study, evaluation of domestic materials and vehicles was carried out to promote domestic bio alcohol fuel. We analyzed the fuel characteristics of domestic quality standard items by mixing them with gasoline of automobile at a certain mixing ratio (0%, 3%, 6%, and 10%).

Analyses of Steady State Mixing Process of Two-Liquids Using Artificial Intelligence (인공지능을 이용한 이종액체 정상 상태 혼합의 혼합과정 해석)

  • KONG, DAEKYEONG;YUM, JUHO;CHO, GYEONGRAE;DOH, DEOGHEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.5
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    • pp.523-529
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    • 2018
  • Two liquids which are generally used as fuels of rockets are mixed and their mixing process is quantitatively investigated by the use of particle image velocimetry (PIV). As working fluids for the liquid mixing, Dimethylfuran (DMF) and JetA1 oils have been used. Since the specific gravity of DMF is larger than that of JetA1 oil, the DMF oil has been set at the lower part of the JetA1 oil. For better visualization of the mixing process, Rhodamin B powder has been blended into the DMF oil. An agitator having 3 blades has been used for mixing the two liquids. For quantitative visualization, a LCD monitor has been used as a light source. A color camera, camcoder, has been used for recording the mixing process. The images captured by the camcoder have been digitized into three color components, R, G, and B. The color intensities of R, G, and B have been used as the inputs of the neural network of which hidden layer has 20 neurons. Color-to-concentration calibration has been performed before commencing the main experiments. Once this calibration is completed, the temporal changes of the concentration of the DMF has been quantitatively analyzed by using the constructed measurement system.

Self Ignition Phenomena of High Pressure Hydrogen Released into Tube with Diaphragm Rupture Conditions (튜브 내 누출되는 고압수소의 격막파열조건에 따른 자발점화 현상)

  • Lim, Han Seuk;Lee, Sang Yoon;Lee, Hyoung Jin;Jeung, In-Seuck
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.215-218
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    • 2014
  • High combustion efficiency of hydrogen could make it an ideal source of green energy in the future. At this time, high pressure vessel is the most reasonable method of storing hydrogen. However, such a high pressurized vessel could pose a critical threat if ruptured. For this reason, it is important to understand the mechanism of hydrogen's self-ignition when a high-pressure hydrogen released into air. This paper presents several visualization images as experimental results using high-speed camera. From the visualization images, the ignition is initiated near rupture disk immediately after failure of disk. And the initial ignition and flame is stronger as a rupture pressure increases. However, this ignition region do not affect the general self-ignition mechanism when a high-pressure hydrogen is released into air through tue after failure of disk.

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Synthesis and Properties of Fe-Ni Nano-sized Powders using Metal Nitrates (금속질산염을 이용한 Fe-Ni 나노분말의 제조 및 특성)

  • Joo, Min-Hee;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.191-195
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    • 2009
  • The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate have been investigated. $Fe_2O_3$/NiO composite powders were prepared by chemical solution mixing of Fe- and Ni-nitrate and calcination at $350^{\circ}C$ for 2 h. The calcined powders were hydrogen-reduced at $350^{\circ}C$ for 30 min. The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate were analyzed by TG in air and hydrogen atmosphere, respectively. TG and XRD analysis for hydrogen-reduced powders revealed that the $Fe_2O_3$/NiO phase transformed to $FeNi_3$ phase at the temperature of $350^{\circ}$. The activation energy for the hydrogen reduction, evaluated by Kissinger method, was measured as 83.0 kJ/mol.

Improved Microstructural Homogeneity of Ni-BCY Cermets Membrane via High-Energy Milling (고에너지 밀링을 통한 Ni-BaCe0.9Y0.1O3-δ 서멧 멤브레인의 미세구조 균질성 향상)

  • Kim, Hyejin;Ahn, Kiyong;Kim, Boyoung;Lee, Jongheun;Chung, Yong-Chae;Kim, Hae-Ryoung;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.648-653
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    • 2012
  • Hybridization of dense ceramic membranes for hydrogen separation with an electronically conductive metallic phase is normally utilized to enhance the hydrogen permeation flux and thereby to increase the production efficiency of hydrogen. In this study, we developed a nickel and proton conducting oxide ($BaCe_{0.9}Y_{0.1}O_{3-{\delta}}$: BCY) based cermet (ceramic-metal composites) membrane. Focused on the general criteria in that the hydrogen permeation properties of a cermet membrane depend on its microstructural features, such as the grain size and the homogeneity of the mix, we tried to optimize the microstructure of Ni-BCY cermets by controlling the fabrication condition. The Ni-BCY composite powder was synthesized via a solid-state reaction using $2NiCO_3{\cdot}3Ni(OH)_2{\cdot}4H_2O$, $BaCeO_3$, $CeO_2$ and $Y_2O_3$ as a starting material. To optimize the mixing scale and homogeneity of the composite powder, we employed a high-energy milling process. With this high-energy milled composite powder, we could fabricate a fine-grained dense membrane with an excellent level of mixing homogeneity. This controlled Ni-BCY cermet membrane showed higher hydrogen permeability compared to uncontrolled Ni-BCY cermets created with a conventionally ball-milled composite powder.

Prediction of Damage Area due to Explosion of LNG-Hydrogen Mixed Gas (도시가스-수소 혼합가스의 누출사고 영향범위 분석)

  • Chan-sik, Yoon;Jin-du, Yang;Gil-soo, Na;Sung-Hyun, Im;Ki-young, Kim;Eun-ki, Choi
    • Explosives and Blasting
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    • v.40 no.4
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    • pp.27-34
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    • 2022
  • The government is promoting various policies to reduce greenhouse gas emissions for carbon neutrality, one of the key tasks is to revitalize the hydrogen economy. As one of these policies the government has formulated a plan to incorporate hydrogen into existing city gas pipes, and aims to commercialize 20% hydrogen mixing by 2026. In preparation for the commercialization of city gas and hydrogen mixture, this study quantitatively predicts the scale of damage and the range of impact in the event of leakage of these two gas mixtures. The quantitative damage prediction method is to calculate the damage conversion distance through the calculation of the TNT equivalent by setting the leakage amount of the gas mixture in the event of an accident under a virtual scenario.