• Nuclear Engineering and Technology
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• 제51권1호
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• pp.238-248
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• 2019

In the high-temperature and high-pressure irradiation environments, the multi-field coupling processes of hydrogen diffusion, hydride precipitation and mechanical deformation in Zircaloy cladding tubes occur. To simulate this hydrogen-induced complex behavior, a multi-field coupling method is developed, with the irradiation hardening effects and hydride-precipitation-induced expansion and hardening effects involved in the mechanical constitutive relation. The out-pile tests for a cracked cladding tube after irradiation are simulated, and the numerical results of the multi-fields at different temperatures are obtained and analyzed. The results indicate that: (1) the hydrostatic stress gradient is the fundamental factor to activate the hydrogen-induced multi-field coupling behavior excluding the temperature gradient; (2) in the local crack-tip region, hydrides will precipitate faster at the considered higher temperatures, which can be fundamentally attributed to the sensitivity of TSSP and hydrogen diffusion coefficient to temperature. The mechanism is partly explained for the enlarged velocity values of delayed hydride cracking (DHC) at high temperatures before crack arrest. This work lays a foundation for the future research on DHC.

• Journal of Welding and Joining
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• 제32권5호
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• pp.1-6
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• 2014

This study aims at manufacturing SA welded API-X70 line-pipe with sour gas resistance. A pipe was manufactured by JCO bending process and SA welding using the API-X70 plate guaranteed HIC resistance. SA welded pipe was expanded in order to reduce the residual stress. The evaluation of a pipe for resistance to HIC and SSCC were performed by the RS D 0004 and RS D 0005 standards. For verification that a pipe has acceptable resistance to HIC, fullscale test was carried out. Results showed no cracking for the HIC and SSCC.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.165-166
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• 2006

Nb-Ti alloys were hydrogenated to prepare fine and contamination-free powders. Cracks were introduced in the alloys when they were annealed at 1473 K and cooled in a hydrogen atmosphere. The fragments produced by hydrogen-induced cracking are brittle and the friability enhanced with the Ti content of the alloy, which is beneficial for further refinement of particle size. We also demonstrate that Nb-Ti powders with the average particle size less than 1 m can be produced by ball milling at a temperature lower than 203 K. Furthermore, hydrogen-free powders can then be obtained by annealing above the temperature corresponding to hydrogen desorption from Nb solid solution.

• Corrosion Science and Technology
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• 제6권1호
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• pp.29-32
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• 2007

The final goal of this study is to develop the core technologies applicable to the design, operation and maintenance of welds in nuclear structures. This study includes predicting microstructure changes and residual stress for welded parts of nuclear power plant components. Furthermore, researches are performed on evaluating fatigue, corrosion, and hydrogen induced cracking and finally constructs systematically integrated evaluation system for structural integrity of nuclear welded structures. In this study, metallurgical and mechanical approaches have been effectively coordinated considering real welding phenomena in the fields of welds properties such as microstructure, composition and residual stress, and in the fields of damage evaluations such as fatigue, corrosion, fatigue crack propagation, and stress corrosion cracking. Evaluation techniques tried in this study can be much economical and effective in that it uses theoretical/semi-empirical but includes many additional parameters that can be introduced in real phenomena such as phase transformation, strength mismatch and residual stress. It is clear that residual stress makes great contribution to fatigue and stress corrosion cracking. Therefore the mitigation techniques have been approached by reducing the residual stress of selected parts resulting in successful conclusions.

• 한국군사과학기술학회지
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• 제13권5호
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• pp.769-774
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• 2010

It happened fractures on special bolt which supported main landing gear actuator up-lock rod of aircraft. Cracks were initiated mainly from the center hole and the external thread of the special bolt. To find out failure root causes, metallographic, fractographic analyses as well as test work were carried out. From the fractographic study by SEM work, fracture occurred by a brittle intergranular type failure. The fracture could be occurred primarily by solid-metal-induced embrittlement due to cadmium embrittler penetrated into the flaw existed after machining work for center hole and thread on the bolt during baking treatment processing to eliminate hydrogen. For its successful application, cadmium EP bolts require proper and adequate baking treatment after electroplating, and make no more drilled center hole on the bolt to prevent same failure.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.396-401
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• 2002

A practical method for evaluating the possibility of the occurrence of cracking in actual thick-plate T-joint weldments is presented in this study. Systematic experiments based on the method of the design of experiment are conducted in order to investigate the crack tendency in relation to typical welding parameters such as diffusible hydrogen, restraint intensity, preheating temperature and so on. The elastic analysis using the [mite element techniques is employed to quantify the restraint intensities of the specimens. The defined restraint intensities are treated in numerical way for the sake of considering the most uncertain factor among some major factors that govern the cracking phenomena due to welding. The critical plane for judgment of the crack occurrence or crack density is presented as a function of typical welding parameters including determined restraint intensities. The results of numerical estimation by the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problem having extensive uncertainties.

• International Journal of Korean Welding Society
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• 제4권1호
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• pp.38-45
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• 2004

A practical method for evaluating the possibility of the occurrence of cracking in actual thick-plate T-joint weldments is presented in this study. Systematic experitrients based on the method of the design of experiment are conducted in order to investigate the crack tendency in relation to typical welding parameters such as diffusible hydrogen, restraint intensity, preheating temperature and so on. The elastic analysis using the fmite element techniques is employed to quantify the restraint intensities of the specimens. The defined restraint intensities are treated in numerical way for the sake of considering the most uncertain factor among some major factors that govern the cracking phenomena due to welding. The critical plane for judgment of the crack occurrence or crack density is presented as a function of typical welding parameters including determined restraint intensities. The results of numerical estimation by the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problem having extensive uncertainties.

• Corrosion Science and Technology
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• 제3권5호
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Carbon letters
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• 제24권
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• pp.28-35
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• 2017

We demonstrated an effective way of preparing melt spinnable mesophase pitches via catalytic hydrogenation of petroleum residue (fluidized catalytic cracking-decant oil) and their subsequent thermal soaking. The mesophase pitches thus obtained were analyzed in terms of their viscosity, elemental composition, solubility, molecular weight, softening point and optical texture. We found that zeolite-induced catalytic hydrogenation under high hydrogen pressure contributed to a large variation in the properties of the pitches. As the hydrogen pressure increased, the C/H ratio decreased, and the solubility in n-hexane increased. The mesophase pitch with entirely anisotropic domains of flow texture exhibited good meltspinnability. The mesophase carbon fibers obtained from the catalytically hydrogenated petroleum residue showed moderate mechanical properties.

• Nuclear Engineering and Technology
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• 제45권7호
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• pp.929-940
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• 2013

Environmental fatigue of the metallic components in light water reactors has been the subject of extensive research and regulatory interest in Korea and abroad. Especially, it was one of the key domestic issues for the license renewal of operating reactors and licensing of advanced reactors during the early 2000s. To deal with the environmental fatigue issue domestically, a systematic test program has been initiated and is still underway. The materials tested were SA508 Gr.1a low alloy steels, 316LN stainless steels, cast stainless steels, and an Alloy 690 and 52M weld. Through tests and subsequent analysis, the mechanisms of reduced low cycle fatigue life have been investigated for those alloys. In addition, the effects of temperature, dissolved oxygen level, and dissolved hydrogen level on low cycle fatigue behaviors have been investigated. In this paper, the test results and key analysis results are briefly summarized. Finally, an on-going test program for hot-bending of 347 stainless steel is introduced.