• 한국수소및신에너지학회논문집
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• 제17권3호
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• pp.347-352
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• 2006

분자전해질연료전지 내의 다공성 기체확산층은 반응가스의 확산과 전자이동통로의 역할을 수행할 뿐만 아니라 전기화학반응에 의해 공기극에서 생성된 수분(기상 혹은 액상)을 반응면으로부터 분리판 채널 방향으로 이동시켜 배출시키는 중요한 역할을 한다. 따라서 물관리를 통한 성능향상을 위해서는 기체 확산층의 구조 및 재료특성에 대한 심도 릴은 연구가 필요하다. 실제 단위전지 체결시 기체확산층은 분리판의 리브(rib)에 의해 눌리게 되며, 그 부분의 기공 크기 분포의 변화를 야기한다. 또한 리브 전단부분에서 탄소 섬유가 손상을 입으며, 탄소 섬유를 감싸고 있는 PTFE coating이 벗겨지게 되어 표면화학적 특성이 달라진다. 본 연구에서는 단위전지 체결 시 분리판에 의해 눌리는 기체확산층의 기공 크기 분포 변화를 측정하였으며, 기공의 소수성에서 친수성으로의 변화를 알아보았다. Mercury 기공 측정기와 PMI 기공 측정기는 큰 기공 분포의 변화에, 질소의 흡/탈착을 이용한 BET 방식은 작은 크기의 기공 분포 변화 관찰에 사용되었다. 체결압에 의한 탄소섬유의 구조적 변화와 아울러 표면의 습윤 정도의 변화를 XPS와 물/알콜 Uptake를 이용해 알아보았다. 이 연구를 바탕으로 물관리를 통한 연료전지 성능 향상을 위한 최적 GDL 선정에 기반이 되는 자료를 도출하였다.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.530-537
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• 2012

This work experimentally investigates that Diesel-DME blended fuel influences combustion characteristics and emissions (NOx, CO, HC, smoke) in a single-cylinder DI diesel engine. Diesel is used as a main fuel and DME is blended for the use of its quick evaporating characteristics. Diesel and DME are blended by the method of weight ratio. Weight ratios for Diesel and DME are 95:5 and 90:10 respectively and the both ratios have been used altogether in blended fuel. The experiments are conducted in this study single cylinder engine is equipped with common rail and injection pressure is 700 bar at 1200 rpm. The amount of injected fuels is adjusted to obtain the fixed input calorie value as 972.2 J/cycle in order to compare with the fuel conditions. DME is compressed to 15 bar by using nitrogen gas thus it can be maintained the liquid phase. In this study, different system compared others paper is common rail system, also there is combustion and emission about compared DME and diesel fuel. It is expected to be utilized about blended fuel.

• 한국수소및신에너지학회논문집
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• 제34권1호
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• pp.59-68
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• 2023

In this study, the performance of high-pressure fuel pumps was compared to find a high-pressure pump suitable for dimethyl ether (DME) fuel, and to establish a database of basic data on flow rates. The use of DME in compression ignition engines can reduce pollutant emissions. The cetane value of DME is higher than that of diesel fuel. The physical properties of DME are similar to liquefied gasoline gas (LPG), and when pressurized at a pressure of 6 bar or more, it changes from gas to liquid. Two types of high pressure pumps used in this study were independent injection type pump and a wobble plate type pump. Two high-pressure pumps with different injection types were compared. By measuring and comparing the performance changes of the two high-pressure pumps, a pump suitable for DME was selected and performance improvement measures were proposed. The changed experimental conditions to measure the performance change of the high pressure pump were increased in the units of 100 to 1,000 rpm and 100 rpm, and the experiment was performed at common rail pressures 300 and 400 bar. it was confirmed that the DME inside the fuel supply system remained in a liquid state through temperature sensors, pressure sensors, and pressure gauges. As a result of the experiment, it was confirmed that the flow rate discharged from the high-pressure fuel pump increased as the motor rotational speed increased, and the flow rate of the high-pressure fuel pump

• 한국가스학회지
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• 제13권1호
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• pp.45-51
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• 2009

본 논문은 국내에 건설된 충전소를 분석 검토하여 수소충전소에 대한 안전성 평가를 실시함으로써 수소충전 소의 안전성에 대한 확인과 충전소 설치 시 필요한 기준마련에 기초자료를 제공하는 것이 궁극적인 목표이다. 안전성 평가 방법으로 FMEA (Failure Mode and Effect Analysis)를 사용하였고, 충전소를 크게 4개의 공정(제조, 압축, 저장, 충전)으로 분류하였다. 또한 각각의 발견된 위험요소에 S (severity), O (occurrence), D (detection)의 점수를 부여하여 이 세 요소의 곱의 값인 RPN (Risk Priority Number)의 수치를 이용하여 위험의 우선순위를 정하고, 이를 바탕으로 시나리오를 생성하였다. 생성한 시나리오를 기반으로 사고피해영향평가 결과 주요한 사고 유형으로 jet fire와 폭발이 나타났고, PSA (pressure swing adsorption) 공정 feed line에서의 누출의 경우 원료물질에 따라 CO가스의 농도가 상이할 수도 있으나, CO가스중독 위험성을 함께 예측되었다.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.134-142
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• 2012

A bipolar plate is a major component of a fuel cell stack, which occupies 50~60% of the total weight and over 50% of the total cost of a typical fuel cell stack. In this study, a composite bipolar plate is designed and fabricated to develop a compact and light-weight direct methanol fuel cell (DMFC) stack for a small-scale Unmanned Aerial Vehicle (UAV) application. The composite bipolar plates for DMFCs are prepared by a compression molding method using resole type phenol resin as a binder and natural graphite and carbon black as a conductor filler and tested in terms of electrical conductivity, mechanical strength and hydrogen permeability. The flexural strength of 63 MPa and the in-plane electrical conductivities of 191 S $cm^{-1}$ are achieved under the optimum bipolar plate composition of phenol : 18%; natural graphite : 82%; carbon black : 3%, indicating that the composite bipolar plates exhibit sufficient mechanical strength, electrical conductivity and hydrogen permeability to be applied in a DMFC stack. A DMFC with the composite bipolar plate is tested and shows a similar cell performance with a conventional DMFC with graphite-based bipolar plate.

• Nuclear Engineering and Technology
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• 제50권2호
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• pp.246-252
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• 2018

A series of simulated reactivity-initiated accident (RIA) tests on irradiated fully recrystallized boiling water reactor Zircaloy-2 cladding has been performed by means of the expansion-due-to-compression (EDC) test method. The EDC method reproduces fuel pellet-clad mechanical interaction (PCMI) conditions for the cladding during RIA transients with respect to temperature and loading rates by out-of-pile mechanical testing. The tested materials had a large variation in burnup and hydrogen content (up to 907 wppm). The results of the EDC tests showed variation in the PCMI resistance of claddings with similar burnup and hydrogen content, making it difficult to clearly identify ductile-to-brittle transition temperatures. The EDC-tested samples of the present and previous work were investigated by light optical and scanning electron microscopy to study the influence of factors such as azimuthal variation of the Zr-hydrides and the presence of hydride rims and radially oriented hydrides. Two main characteristics were identified in samples with low ductility with respect to hydrogen content and test temperature: hydride rims and radial hydrides at the cladding outer surface. Crack propagation and failure modes were also studied, showing two general modes of crack propagation depending on distribution and amount of radially oriented hydrides. It was concluded that the PCMI resistance of irradiated cladding under normal conditions with homogenously distributed circumferential hydrides is high, with good margin to the RIA failure limits. To further improve safety, focus should be on conditions causing nonfavorable hydride distribution, such as hydride reorientation and formation of hydride blisters at the cladding outer surface.

• 한국산업융합학회 논문집
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• 제26권6_3호
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• pp.1289-1295
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• 2023

Polyurethane foam insulation required for storing and transporting cryogenic liquefied gas is already widely used as a thermal insulation material for commercial LNG carriers and onshore due to its stable price and high insulation performance. These polyurethane foams are reported to have different mechanical performance depending on the density, and the density parameter is determined depending on the amount of the blowing agent. In this study, density-dependent polyurethane foam was fabricated by adjusting the amount of blowing agent. The mechanical properties of polyurethane foam were analyzed in the room temperature and cryogenic temperature range of -163℃ at 1.5 mm/min, which is a quasi-static load range, and the cells were observed through microstructure analysis. The characteristics of linear elasticity, plateau, and densification, which are quasi-static mechanical behaviors of polyurethane foam, were shown, and the correlation between density and mechanical properties in a cryogenic environment was confirmed. The correlation between mechanical behavior and cell size was also analyzed through SEM morphology analysis. Polyurethane foam with a density of 180 kg/m³ had a density about twice as high as that of a polyurethane foam with a density of 96 kg/m³, but yield strength was about 51% higher and cell size was about 9.5% smaller.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.313-320
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• 2002

The characteristics of the AISI bipolar plates have been investigated to replace the expensive graphite bipolar plates. It was found from the contact resistance evaluation of graphites, composites, and AISI that the contact resistance of AISI was the lowest, but it could approach to that of composites at higher compression forces. The single cell operation using the AISI bipolar plates revealed that the lower performance of the AISI single cell compared to the graphite one was due to not only the higher contact resistance but the flooding effect caused by high wettability of AISI. The performance of the AISI single cell could be improved if the channels were modified appropriately. The large size AISI single cell was operated to investigated the size effect on the performance.

• 한국연소학회지
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• 제14권1호
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• pp.31-38
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• 2009

The effects of acoustic excitation of coaxial air on mixing enhancement and reduction of nitrogen oxides (NOx) emission were investigated. A compression driver was attached to the coaxial air supply tube to impose excitation. Measurements of NOx emission with frequency sweeping were performed to observe the trend of NOx emission according to the fuel and air flow conditions and to inquire about the effective excitation frequency for reducing NOx. Then, Schlieren photographs were taken to visualize the flow field and to study the effect of excitation. In addition, phase-locked particle image velocimetry (PIV) was performed to acquire velocity field for each case and to investigate the effect of vortices more clearly. Direct photographs and OH chemiluminescence photographs were taken to study the variation of flame length and reaction zone. It was found that acoustic forcing frequencies close to the resonance frequencies of coaxial air supply tube could reduce NOx emission. This NOx reduction was influenced by mixing enhancement due to large-scale vortices formed by fluctuation of coaxial air jet velocity.

• 한국수소및신에너지학회논문집
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• 제20권4호
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• pp.344-351
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• 2009

A multi-zone model was used to predict the operating range of homogeneous charge compression ignition (HCCI) engine, the boundaries of the operating range were determined by knock (presented by ring intensity), misfire (presented by sensitivity of indicated mean effective pressure to the initial temperature). A HCCI engine fueled with Di-Methyl Ether (DME) was simulated under different initial temperature and equivalence ratios, and the operating range was well produced by the model. Furthermore, the model was applied to develop the operating range for thermal stratification in the preceding condition of initial temperature and equivalence ratios. The computations were conducted using Senkin application of the CHEMKINII kinetics rate code.