• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1601-1608
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• 2010

A scandium(III) porphyrin-based fluoride-selective potentiometric sensor and its application in the analysis of hydrofluoric acid is described. Scandium(III) octaethylporphyrin, an ionophore recently developed for the optical fluoride sensor, was employed as a host molecule for the selective binding with fluoride in the plasticized PVC membrane. Nernstian response for $F^-$ between $10^{-4.6}$ to $10^{-1}$ M was observed at a glycine-phosphate buffer (pH 3.0). The selectivity pattern was observed as $F^-$, salicylate $\gg$ $SCN^-$ > $Cl^-$, $Br^-$, $NO_3{^-}$, $ClO_4{^-}$, which is consistent with the binding constant data measured in the plasticized PVC membrane based on a sandwich membrane method. This highly selective and reversible fluoride-sensitive electrode was employed for the analysis of hydrofluoric acid (HF). A disposable differential-type HF sensor was fabricated on the screen-printed electrode and demonstrated its ability to detect the neutral HF in the acidic solution.

• Fire Science and Engineering
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• v.27 no.6
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• pp.83-88
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• 2013

Catastrophic disasters are sprouting out recently, i.e., the radiation leaks and the hydrofluoric acid gas leaks, etc. The restoration work for these kinds of disasters is very harmful and dangerous for human beings to handle themselves, thus allowing manless robots to fly the reconnaissance planes over to the disaster stricken areas and do the necessary work instead. For this endeavor and purpose, we created and tested an intelligent robot that can inspect those areas, using Mbed (ARM processor) technology temperature sensors and gas sensors aided by CAM (Computer-Aided Manufacturing) cameras. Also, HTTP Server, PC, androids and their combined efforts allow their remote controlled operation from far away with timing control. These intelligent robots can be on duty for 24 hours, minimizing the accidents and crimes and what not, and can respond more quickly when these misfortunes actually happen. We can anticipate the economic effects as well, derived from the reduced needs for hiring human resources.