• Title/Summary/Keyword: Hydrocarbon-water system

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Correlation of Liquid-Liquid Equilibrium of Four Binary Hydrocarbon-Water Systems, Using an Improved Artificial Neural Network Model

  • Lv, Hui-Chao;Shen, Yan-Hong
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.370-376
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    • 2013
  • A back propagation artificial neural network model with one hidden layer is established to correlate the liquid-liquid equilibrium data of hydrocarbon-water systems. The model has four inputs and two outputs. The network is systematically trained with 48 data points in the range of 283.15 to 405.37K. Statistical analyses show that the optimised neural network model can yield excellent agreement with experimental data(the average absolute deviations equal to 0.037% and 0.0012% for the correlated mole fractions of hydrocarbon in two coexisting liquid phases respectively). The comparison in terms of average absolute deviation between the correlated mole fractions for each binary system and literature results indicates that the artificial neural network model gives far better results. This study also shows that artificial neural network model could be developed for the phase equilibria for a family of hydrocarbon-water binaries.

Study on Performance Characteristic of Water-Cooled Type Beat Pump Using Hydrocarbon Refrigerants (탄화수소계 냉매를 이용한 수냉식 히트점프의 성능특성에 관한 연구)

  • Jun Chul-Ho;Lee Ho-Saeng;Kim Jae-Dol;Yoon Jung-ln
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.8
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    • pp.870-876
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    • 2005
  • This study of the performance characteristics of natural refrigerants such as R-290 (propane), R-6OOa (iso-butane) and R-1270 (propylene) has investigated to compare with conventional HCFC's refrigerant R-22 for water-cooled heat pump system. The experimental apparatus has basic parts of cycle that uses the water as a heat source. The Performance of the water-cooled system using hydrocarbon refrigerants had been getting better than R-22 from start-up to the similar evaporating temperature after stabilizing system. Through the above it is possible that hydrocarbon refrigerants could be drop-in alternatives for R-22.

The Removal of Petroleum Hydrocarbon from Fine Soil in Soil Washing Water using Advanced Oxidation Processes

  • Jang, Gwan-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.362-367
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    • 2014
  • This study was performed to test the applicability of the ozone/hydroxy radical reaction system, which applied advanced oxidation processes, to remove total petroleum hydrocarbon (TPH) from the fine soil in washing water of the soil washing process. Removal efficiency was tested on 40 L of washing water in a pilot reaction tank. Fine soil contaminated with $800mg\;kg^{-1}$ TPH was prepared at 5% and 10% suspended solids. Testing conditions included ozone/hydroxy radical flow rates of 40, 80, and $120L\;min^{-1}$, and processing time of 2 to 12 hours. The removal efficiency of petroleum hydrocarbon from water waster by ozone/hydroxy radical was increased with higher flow rates and lower percentages of suspended solids. Optimal efficiency was achieved at $80L\;min^{-1}$ flow rate for 4 hours for the 5% suspended solids, and $120L\;min^{-1}$ for 6 hours for the 10% suspended solids. These results verified the efficiency of hydroxy radical in removing TPH and the applicability of the ozone/hydroxy radical reaction system in the field.

Investigation of the Geoelectrical Response at the Hydrocarbon-impacted Zone (유류 오염대의 전기적 물성 특성 연구)

  • Kim, Chang-Ryol;Ko, Kyung-Seok;Kim, Jung-Ho
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.225-230
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    • 2007
  • A physical model experiment with GPR and 3-D resisitivity survey were conducted to investigate the geoelectrical response of hydrocarbon-impacted zone, so called smeared zone, on the geophysical data. The results from the experiment show that GPR signals were enhanced when LNAPL was present as a residual saturation in the water saturated system (${\varepsilon}_r$ = 21) due to less attenuation of the electromagnetic energy through the medium, compared to when the medium was saturated with only water (${\varepsilon}_r$ = 21). 3-D resistivity data obtained from the former gas station site demonstrate that the highly contaminated zones could be imaged with low resistivities attributed to the biodegradation of petroleum hydrocarbons at the aged, hydrocarbon-impacted sites. The study results also show that the geophysical methods, as a non-invasive sounding technique, can be a very useful tool for mapping hydrocarbon-contaminated zones.

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The effect of the structure of each component on the o/w microemulsion droplet size and stability

  • Changgui Han;You
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.20-40
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    • 1996
  • The oil in water type ME of 4 component system was composed with POE monoalkyl ether and POE sorbitan monoalkyl ester as surfactant, saturated hydrocarbon, side chain structure and aromatic structure as oil, and glycerine as cosurfactant using high pressure homogenizer. The objective of this study was to examine the role of surfactant and oil structure on droplet size and stability. The experimental results showed that the droplet size was smaller with bigger polarity of oil, less hydrocarbon, longer hydrophilic chain of surfactant and higher concentration of glycerine. SQ and LP systems showed very stable but AB and ISB system unstable microemulsion.

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Performance Characteristics of Air-Cooled Heat Pump System using Hydrocarbon Refrigerants According to Variation of Outdoor Temperature (실외 온도 변화에 따른 HC계 공랭식 히트펌프 시스템의 성능 특성)

  • Jun Chul-Ho;Lee Ho-Saeng;Kim Jae-Dol;Yoon Jung-In
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.3
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    • pp.218-224
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    • 2006
  • The performance of an air to water vapor compression heat pump has been investigated experimentally. The main purpose of this study was to study the possibilities of using hydrocarbon refrigerants as a working fluid to replace R-22 for vapor compression heat pumps. Pure R-22 and R-290, R-600a, R-1270 were considered as working fluids. The performance of the system was characterized by compression shaft work, refrigeration capacity, pressure ratio, discharge temperature and COP. The experimental apparatus has basic parts of cycle that uses the air as a heat source. The experimental results show that refrigeration capacity of HC refrigerants is same or higher than that of R-22. On the other hand, compression shaft work of HC refrigerants is lower than that of R-22. Compression shaft work is lower than that of R-22. Come to the conclusion that, it is possible that hydrocarbon refrigerants could be drop-in alternatives for R-22.

A Review on Recent Development and Application of Marine Controlled-Source Electromagnetics (Marine CSEM의 최근 기술 개발 및 적용 사례)

  • Song, Yoon-Ho;Kim, Hee-Joon;Seol, Soon-Jee
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.12a
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    • pp.87-100
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    • 2007
  • Marine controlled source electromagnetics (CSEM) or sea bed logging (SBL) is an emerging technology which can provide quantitative information on hydrocarbon reservoir embedded in marine sediment. Electromagnetic responses to the resistive formation saturated with a certain amount of hydrocarbon can be characterized by less attenuated profile otherwise exponentially attenuated fields in conductive sea water or through sediments, and thus can be regarded as a direct indicator of hydrocarbon. In this paper, we introduce the technology of marine CSEM in terms of its physical characteristics and in comparison of typical three-dimensional (3-D) seismic method. History and evolution of commercial marine CSEM are also briefly summarized. We then introduce a representative case history showing how marine CSEM works in reality. Outlook of future applications and technical advances to be made are discussed. Finally, we demonstrate a test example of 2.5-D inversion of synthetic data as the groundwork of 3-D inversion of field data that is to be the ultimate goal of technical development.

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Studies on the Micelle Formation of Surfactant Solution(2) - Self-Diffusion by Phase Transition in Ternary System of Surfactant/Hydrocarbon/Water - (계면활성제 수용액에서 미셀형성(제2보) - 계면활성제/탄화수소/물의 상 변화에 따른 자기확산 -)

  • Choi, Seung Ok;Lee, Jin Hee;Kim, Sang Chun;Nam, Ki Dae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.112-117
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    • 1999
  • The pulsed field gradient NMR method has been used to determine self-diffusion coefficients in ternary N-alkyl-N, N-dimethylamine oxide/hydrocarbon/$D_2O$ system. For n = 12, 14, 16 and n' = 8, 10, 12, 14, 16, in the micellar phase, diffusion is chiefly governed by the hydrodynamic transport of micelles, supplemented by an exchange of solubilized hydrocarbon upon micellar collisions. This investgation is performed by variations in both the surfactant alkyl chain length and in the size of the hydrocarbon molecules. In cubic phases, the solvent still exhibits values of the diffusion coefficients which are typical for motion in a continuous water phase, with the microemulsion droplets acting as obstacle. Mobilities of the surfactant in the gel state were low and have been determined only for the surfactant($C_{12}DMAO$) with the shortest alkyl chain length. Exchange of hydrocarbon between micellar entities in the gel was found to be occured by a hopping process, the associated rate decreased with alkyl chain length of the surfactant.

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The Study of Microbial Population & Dynamics in Hydrocarbon Contaminated Areas (유류오염지역의 미생물 분포 및 활성도에 관한 연구)

  • 김무훈;김순기;이원권;경우성;박덕신
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.28-31
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    • 1999
  • The purpose of this study is to see the effect of microbial population and dynamics of the indigeonous microorganisms on hydrocarbon contaminated areas. The microbial structures and activities to determine the microbial capabilities of the contaminated sites are very important for the remedial action technology selection. Throughout microbial studies on different conditions by ETS(Electron Transport System) and microbial activity analysis, it was found that aeration and water contents are the most important factors in this site remediation. According to test results, Burkholderia spp. was dominant species, and acclimation is also an important factor for the accerelated biodegradation.

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A Study on the Rapid Cooling Vacuum System for the Storage and Transportation of the Cold Agriculture and Livestock Products (농축산물의 저장 및 유통을 위한 감압증발 급냉각 시스템에 관한 연구)

  • 김성규;김원녕;김경석;최순열;전현필
    • Journal of Advanced Marine Engineering and Technology
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    • v.21 no.1
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    • pp.26-36
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    • 1997
  • Recently, the new refrigerating system, using non - fluorinated hydrocarbon refrigerants has to be developed for the agricultural fields. One of that kinds of systems is the cooling system using the water vapor and vacuum, in which the water evaporate at the low temperature under vacuum and absorb the large amount of the latent heat. If vapor with large amount of latent heat is removed from the system, the system is cooled accordingly. The characteristics of cooling under the vacuum was observed and measured using experimental apparatus, which is consisted of vacuum chamber, the ejectors, the pumps and the measurement apparatus. As the results of experiments, we know that the evaporation in the vacuum occurs vigorously when the materials to be cooled has more amounts of heat before cooling, and by which effects the materials can be cooled. The cooling vacuum system is more efficient than other methods when the agricultural products is chilled or dried.

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