• Title/Summary/Keyword: Hydrocarbon flame

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The Role of Oxygen Atom in the NOx Formation of DME/Air Nonpremixed Flames (DME/Air 비예혼합화염의 NOx 생성에서 산소원자의 역할)

  • Kim, Tae-Hyun;Hwang, Cheol-Hong;Lee, Seung-Ro;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.14 no.1
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    • pp.9-18
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    • 2009
  • The NOx emission characteristics of DME in counterflow nonpremixed flames were investigated numerically, and brief experiments were carried out to compare the flame shapes and NOx emissions with those of $C_{3}H_{8}$ and $C_{2}H_{6}$. The DME flames were calculated using Kaiser's mechanism, while the $C_{2}H_{6}$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show that DME flame has the characteristics of partial premixed flame and the flame length becomes very shorter compared with general hydrocarbon fuels and then, the NOx emission of DME is low as much as 60 % of $C_{3}H_{8}$. In the calculated results of counterflow nonpremixed flames, the $EI_{NO}$ of DME nonpremixed flame is low as much as 50 % of the $C_{2}H_{6}$ nonpremixed flame. The cause of $EI_{NO}$ reduction is attributed mainly to the characteristics of partial premixed flame due to the existence of O atom in DME and partly to the O-C bond in DME, instead of C-C bond in hydrocarbon fuels.

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Experimental Investigation of Scalar Dissipation Rates in Lean Hydrocarbon/Air Premixed Flames

  • Chen, Yung-Cheng;Bilger, Robert W.
    • Journal of the Korean Society of Combustion
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    • v.6 no.2
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    • pp.43-49
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    • 2001
  • Instantaneous, three-dimensional scalar dissipation rates of the reaction progress variable are measured in turbulent premixed Bunsen flames of lean hydrocarbon/air mixtures with the two-sheet, two-dimensional Rayleigh scattering technique. The flames investigated are located in the turbulent flame-front regime on a newly proposed combustion diagram for premixed flames. The conditionally-averaged mean scalar dissipation rates, $N_{\zeta}$ are found to be lower than the calculated laminar values, indicating a locally broadened flame front. In agreement with previous measurements, the maximum of $N_{\zeta}$, decreases strongly with increasing Karlovitz numbers. The conditional probability density functions are close to a log-normal distribution for scalar dissipation rates conditioned at the progress variable value where the scalar dissipation is maximum in unstretched laminar flame calculations. The time scale for the Favre-averaged mean scalar dissipation rate decreases in general across the turbulent flame brush from the unburnt to burnt side.

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Combustion Characteristics of the Atomized Hydrocarbon Liquid-fuel Spray Injected through a Slit-jet Nozzle (Slit-jet 노즐을 통해 분사되는 탄화수소계 액체연료 분무의 연소특성)

  • Kim, Min Sung;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.1
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    • pp.43-49
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    • 2016
  • An experimental study was performed to investigate the combustion characteristics of the liquid hydrocarbon fuel atomized by an ultrasonic oscillator. Configuration of the flame was caught by the DSLR camera, and images were analyzed in detail through a post-processing. Temperature of the flame zone was measured using thermocouple. It is resulted that the flame area is proportional to the mass flow rate of carrier gas as well as the voltage applied to the ultrasonic oscillator. Temperature of the flame zone is measured and analyzed according to variation in the operating condition of the burner, too.

NOx Emission Characteristics of Dimethyl Ether/Air Nonpremixed Flames (DME/Air 비예혼합화염의 NOx 생성특성)

  • Hwang, Cheol-Hong;Kum, Sung-Min;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.11
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    • pp.926-935
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    • 2007
  • The NOx emission characteristics of DME in laminar coaxial jet and counterflow nonpremixed flames were investigated using experimental and numerical approaches, respectively. The flame structure and NOx emission of DME were compared with those of $C_2H_6$ and $C_3H_8$. The DME flame was calculated using the Kaiser's mechanism, while the $C_2H_6$ and $C_3H_8$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show in coaxial jet flame that DME flame has the characteristics of partial premixed flame and the flame length decreases up to 1/3 than that of $C_3H_8$ in the same condition of fuel mass flowrate. Then, the NOx emission of DME decreases to 40% approximately, comparing with that of $C_3H_8$. In the calculated results of counterflow nonpremixed flame, DME flame shows the $EI_{NO}$ decreases up to 50% approximately than those of$ C_2H_6$ and $C_3H_8$ flames when the equivalent fuels are consumed per unit mass and time. Although the overall NOx reaction path of DME is similar with other hydrocarbon fuels, it can be identified that DME flame has a distinct NO reduction mechanism due to the reburning NO chemistry in fuel rich region. From these results, we can conclude that the different NOx emission characteristics of DME flame with other hydrocarbon fuels are attributed to not the temperature increase and the activation of NO reactions due to O atom in DME fuel but the rapid processes of pyrolysis/oxidation.

Flame Synthesis of Carbon Nanofibers using SUS304 Substrates (촉매금속 기판을 사용한 탄소나노섬유의 연소합성)

  • Lee, Gyo-Woo;Jurng, Jong-Soo;Hwang, JungHo
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1378-1383
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    • 2003
  • Synthesis of carbon nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was illustrated. Stainless steel plates were used for the catalytic metal substrate. The effects of radial distance and residence time of the substrate were investigated. The role of hydrocarbon composition in the fuel was also viewed. Nanofibers with a diameter range of 30-70 nm were found on the substrate. The carbon nanofibers were formed and grown in the region from 4 to 5.5 mm from the central axis of a flame outside of the visible flame front in the radial direction. The minimum residence time required for the formation of carbon nanofibers were about 20 seconds, and over 60 seconds were required for the full-scale growth. The characteristic time of the formation of carbon nanofibers was much shorter than that of the substrate temperature growth. In this study, the variation in hydrocarbon composition had no significant effect on the formation and growth of the carbon nanofibers.

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An Experimental Study of Cyclic Combustion Characteristics at Starting and Idling Phase on Spark Ignition Engine (SI 엔진의 시동 및 아이들 구간에서의 점화시기에 따른 싸이클별 연소현상에 관한 실험적 연구)

  • Choi, Seong-Won;Choi, Kwan-Hee;Myung, Cha-Lee;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3317-3322
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    • 2007
  • THC(Total Hydrocarbon) emissions during cold start and warm-up phase constitute the majority of THC emissions during the FTP-75 mode. As the basic approach to improve the emission performance of Gasoline engine during transient phase, the effect of spark timing retard from MBT on THC emission characteristics is studied by engine test using a Fast response Flame Ionization Detector(FFID). A cyclic analysis of the combustion process shows that high THC emissions are produced first few cycles during the transient phase. This paper presents the results of engine performance and emission of Gasoline engine with various spark timing. consequently, This paper was focused on the combustion phenomena with various spark timing during transient phase which was analyzed by Fast response Flame Ionization Detector (FFID) equipment to measure the cyclic THC emission characteristics.

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Combustion Characteristics According to the Equivalence Ratio of Hydrocarbon Fuel/Air Premixture Excited by Ultrasonic Standing Wave (정상초음파가 인가된 탄화수소계 연료/공기 혼합물의 당량비에 따른 연소특성)

  • Kim, Min Cheol;Bae, Seong Hun;Hong, Joon Yeol;Kim, Jeong Soo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.628-631
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    • 2017
  • An experimental study of the combustion characteristics according to the equivalence ratio of hydrocarbon fuel/air premixture excited by ultrasonic standing wave are presented. The image of the propagating flame was acquired using a high-speed camera, and the combustion characteristics of each fuel were closely observed through image processing. it was conformed that ultrasonic standing wave has been found to stimulate the combustion reaction in the stoichiometric ratio.

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Behavior of the Ultrasonically-atomized Liquid-fuel Flame Injected through a Slit-jet Nozzle (Slit-jet 노즐을 통해 분사되는 초음파 무화 액체연료 화염의 거동)

  • Kim, Min Cheol;Kim, Min Sung;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.6
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    • pp.1-10
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    • 2018
  • An experimental study was performed for the behavior of the burner flame which results from burning of the liquid hydrocarbon fuel atomized by an ultrasonic transducer. Configurations of the flame and combustion-field were caught by both high-speed camera and thermo-graphic camera, and those images were analyzed in detail through a image post-processing. As a result, the combustion-field grew and reaction-temperature rose due to the strengthening of combustion reaction with the increasing flow-rate of carrier-gas. In addition, a phenomenon of flame flickering was discussed through the comparative analysis of the variational behavior between the visible flame and IR (Infrared) flame-field. Also, the flickering frequency of the flame was confirmed through FFT (Fast Fourier Transform) analysis employing the flame area.

Combustion of Low Concentration VOC on a Turbulent Partially Premixed Flame (난류 부분예혼합 화염을 이용한 난연성 유증기 처리에 관한 연구)

  • Ahn, Taekook;Park, Sunho;Nam, Younwoo;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.207-210
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    • 2014
  • The potential of combustion treatment of low concentration VOC on a turbulent partially premixed flame has been studied experimentally. The significant decrease in hydrocarbon concentration from the low concentration VOC was observed with a turbulent partially premixed flame. The VOC/inert gas mixture whose fuel concentration is beyond the flammability limit could be treated in this method.

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An experimental study on the mechanism of hydrocarbon emissions (배기 Hydrocarbon의 생성과정에 과한 실험적 연구)

  • 심현성;박찬준;이대운
    • Journal of the korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.25-31
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    • 1991
  • The formation process of hydrocarbon emissions was investigated in SI engine. The time- resolved concentrations of hydrocarbon emissions were measured using a high gas sampling valve and a gas chromatography. The gas was sampled at exhaust port, or the position of spark plug, or the wall of combustion chamber. The experiments were conducted using the Alpha engine of Hyundai Motor Company. The fuel used was methanol or propane. It was found that the effect of the quenching layer of combustion chamber wall on hydrocarbon emissions was not significant. The increasing rate of hydrocarbon concentration at combustion chamber wall near crevice and oil layer after flame was reached was much higher than that at the position of spark plug. The hydrocarbon concentrations at exhaust port had two peak values just after opening exhaust valve and just before closing it.

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