• Title/Summary/Keyword: Hydrocarbon(HC)

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On the automobile catalytic converter (자동차용 촉매전환기에 관하여)

  • 정석호
    • Journal of the korean Society of Automotive Engineers
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    • v.7 no.2
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    • pp.18-26
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    • 1985
  • 최근에 들어 환경보전에 대한 시민의식이 고조되고 깨끗한 자연 및 생활환경을 유지하려는 노력 이 각계에서 일고 있다. 이와 관련된 문제점의 하나가 대기오염이며 이 오염원 중의 하나가 자 동차 배기물로서 특히 탄화수소(hydrocarbon:HC), 일산화탄소(CO), 질소산화물(NO$_{x}$)에 의 한 대기오염의 심각히 대두되어 왔으며 현재 환경청 등에 의해 국가적 차원에서 자동차 배기물에 대한 규젤ㄹ 강화하려는 움직임을 보이고 있다. 미국의 경우 연도별 배기규제기준을 살펴 보면 표.1 과 같으며, 국내에서도 88년까지 미국, 일본수준으로 신규제작차의 배출혀용기준을 강화할 계획으로 있다. 표1의 규제치르 보면 60년대의 비규제기간중의 배출량에 비해 탄화수소의 경우 96%, CO는 96%, NO$_{x}$는 76%의 감소를 보여주고 있으며 이 규제치는 5만mile을 규정된 방법으로 주행한 후 복잡한 사이클과정의 연방정부 시험절차 (Federal Test Procedure, FTP 또는 Constant Volume Sampling-Cold and Hot, CVS-CH)를 거쳐 만족하여야 한다. 상기의 규제치들을 만족시키기 위한 실용적 방법으로서 촉매전환기(catalytic converter)가 채택되고 있 으며 따라 본 해설에서는 자동차용 촉매전화기에 대한 자료들을 정리하여 특성, 문제점 등을 살펴 보고자 한다.

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A Study on the Emissions of Homogeneous Charge Compression Ignition Engine (균질혼합압축점화기관의 배출가스특성에 관한 연구)

  • Han, Sung-Bin;Choi, Gyeung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.3
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    • pp.324-329
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    • 2004
  • As a new concept in engines and a power source for future automotive applications, the HCCI(Homogeneous Charge Compression Ignition) engine has been introduced. Essentially a combination of spark ignition and compression ignition engines, the HCCI engine exhibits low NO$_x$ and PM emissions as well as high efficiency under part load. In this research, a 4 cylinder diesel engine was converted into a HCCI engine, and propane was used as the fuel. The main parameters for this research are fuel flow rate and the temperature of the intake manifold, and the effects of such on a HCCI engine's performance and exhaust was investigated.

Power and Emission Characteristics of DI Diesel Engine with a Soybean Bio-diesel Fuel (바이오디젤유를 사용한 직접분사식 디젤엔진의 출력성능 및 배출가스 특성)

  • Choi, B.C.;Lee, C.H.;Park, H.J.
    • Journal of Power System Engineering
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    • v.6 no.3
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    • pp.11-16
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    • 2002
  • This paper describes the power performance and emission characteristics of the high speed direct injection diesel engine (2.9 litter displacements) driven by soybean oil asknown a bio diesel fuel. The results were compared to diesel fuel with blending bio diesel fuels. The soybean bio diesel fuel was added in the diesel fuel in concentration varying from 25% to 75% volume rates. We measured the emissions according to ECE 13 mode and full load, fixedengine speed. When the 25% bio diesel fuel was used, NOx emission at the ECE 13 mode test slightly decreased compared with diesel base engine. Over engine speed of 2000 rpm, the level of unburned hydrocarbon(HC) and carbon monoxide(CO) were the same to the diesel engine. Smoke emission decreased asthe blending bio diesel fuel rate increased.

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Study on n-Butane Autothermal Reforming for Portable Fuel Cell (휴대용 연료전지를 위한 부탄 자열개질에 관한 연구)

  • Bae, Gyu-Jong;Kang, In-Young;Lim, Sung-Kwang;Bae, Joong-Myeon;Kim, Ju-Yong;Lee, Chan-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.11 s.254
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    • pp.1123-1130
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    • 2006
  • This study discusses about research efforts of hydrogen generation from hydrocarbon(e.g., diesel, gasoline, natural gas, and LPG), especially, butane reforming by using Autothermal Reforming Reaction (ATR) technology. Several catalysts were selected for butane ATR. Thermodynamic reactor conditions (temperature, $O_2$/C, S/C) are varied and reforming characteristics of 2 catalysts (Pt and Rh on ceramic supports) and 1 commercial catalyst (FCR-HC35) have been examined. To understand reaction behaviors in an ATR reactor comprehensively, temperature profiles of reactor were observed. By mass transfer limitation, fuel conversion decreases when GHSV increases. Significant temperature variation along the reactor was observed and it was mainly due reaction kinetics difference between exothermic oxidation and endothermic reforming reaction.

Optimal Design of Positive Crankcase Ventilation Valve (PCV(Positive Crankcase Ventilation) 밸브 최적화 설계)

  • Lee, J.H.;Kim, J.H.;Lee, Y.W.
    • Journal of Power System Engineering
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    • v.10 no.2
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    • pp.68-74
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    • 2006
  • In the development of new automobiles, the efforts to reduce environmental problems like air pollution have been risen. Blowby gas consists of about $20{\sim}35%$ of total amount of Hydrocarbon (HC), one of dangerous pollutants issuing from automobiles. A PCV valve is a very small component in an automotive engine but it is a very important part. Because that a PCV valve is used to control blowby gas and to recirculate it into a manifold automatically. Although it has very simple operating principle, designing a PCV valve is so difficult due to interaction between fluid and solid. In this study, our purpose is to develop a design program for a PCV valve and to verify its efficiency. Both Bernoulli equation and 4th order Runge-Kutta method were adopted to predict spool displacements and flow patterns. Comparing with experiments, it was found that both spool diameters and displacements were predicted well, however, flow rates showed a little differences because of the assumption of non viscous flow.

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Reducing technology of fuel-NOx generation using fuel-rich/-lean catalytic combustion (연료(燃料) 과농(過濃)/희박(稀薄) 조절(調節)의 촉매연소(觸媒燃燒)에 의한 Fuel-Nox 저감(低減) 기술(技術))

  • Kang, S.K.;Lee, S.J.;Ryu, I.S.;Shin, H.D.;Han, H.S.
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.55-62
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    • 2006
  • A two-step fuel-rich/fuel-lean catalytic combustion seems to be one of the most effective methods to control simultaneously the NO generation and the hydrocarbon (HC) conversion from fuel-bound nitrogen. By controlling equivalent air ratio for maintaining fuel-rich and fuel-lean condition over each catalytic layer, space velocity, inlet temperature, and catalyst component, the HCand ammonia conversion efficiency higher than 95% could be achieved, with ammonia conversion to NO remaining below 5%. The experimental results wouldbe applied to the combustion of land fill gas and to gasified refuse-derived fuels as a method of minimizing NO generation.

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Effect of pre-post injection timing of diesel fuel for naval vessel on the combustion and emission characteristics in an optically-accessible single cylinder diesel engine (단기통 디젤엔진에서 함정용 디젤유의 전·후 분사시기가 연소 및 배출가스 특성에 미치는 영향)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.868-876
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    • 2014
  • The objective of this study is focused on the analyzing combustion, carbon monoxide and hydrocarbon emission characteristics of marine diesel oil, utilized for naval propulsion engine, with varying pre-post injection timing of an optically accessible single cylinder engine. And also the combustion process is analyzed by means of a high speed camera visualization. On the result of retarding pre-injection timing toward main injection timing, the mean effective pressure and maximum pressure of combustion chamber are increased; however, the heat release rate is decreased. Furthermore, the emission rates of carbon monoxide and hydrocarbon are reduced in this case. In hence, when a post-injection timing is advanced, the mean effective pressure and maximum pressure are increased, because the combustion has been performed under the high temperature and high pressurized environment during main injection time, and the emission rates of carbon monoxide and hydrocarbon are increased. From the experimental results, it considered that retarding of pre-injection timing affects to shorten the ignition delay of main injection clearly, and to raise the flame intensity comparing to the advanced state. The ignition delay during post-injection is not appeared at any post-injection time, but the flame intensity has been weakened gradually according to the retarding of post-injection timing.

According to the type of commercial antifreeze experimental study of vehicle emissions (상용부동액 종류에 따른 자동차 배출가스의 실험적 연구)

  • Hong, Sung-In
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.4002-4006
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    • 2014
  • The automotive exhaust gases generated by the vehicles containing carbon monoxide, hydrocarbons and lead, is a large concern because of their harm to human health or the living environment. To reduce exhaust gas, it is important to develop a variety of techniques that are currently being used by elemental analysis to determine the optimal conditions. In this study, the anti-freeze coolant contained in the exhaust gas was examined, which can affect the emissions. The effects of the commercially available coolant from five domestic companies on the HC, NOx and $CO_2$ emissions were analyzed to determine the optimal amount of antifreeze. In addition, antifreeze products from the five companies were analyzed with respect to driving time of the cooling fan and the correlation of the NOx emission analysis. The temperature of the engine oil was matched using a manual gear of small passenger inspection standard speed $40{\pm}2Km/h$ so the vehicle could meet the specifications for inspection $90{\sim}93^{\circ}C$. The Company D fan operation time resulted in the shortest antifreeze, $CO_2$ and NOx emissions.

Knock Characteristic Analysis of Gasoline and LPG Homogeneous Charge Compression Ignition Engine (가솔린과 LPG 예혼합 압축 착화 엔진의 노킹 특성)

  • Yeom, Ki-Tae;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.54-62
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    • 2007
  • The knock characteristics in an engine were investigated under homogeneous charge compression ignition (HCCI) operation. Liquefied petroleum gas (LPG)and gasoline were used as fuels and injected at the intake port using port fuel injection equipment. Di-methyl ether (DME) was used as an ignition promoter and was injected directly into the cylinder near compression top dead center (TDC). A commercial variable valve timing device was used to control the volumetric efficiency and the amount of internal residual gas. Different intake valve timingsand fuel injection amounts were tested to verify the knock characteristics of the HCCI engine. The ringing intensity (RI) was used to define the intensity of knock according to the operating conditions. The RI of the LPG HCCI engine was lower than that of the gasoline HCCI engine at every experimental condition. The indicated mean effective pressure (IMEP) dropped when the RI was over 0.5 MW/m2and the maximum combustion pressure was over 6.5MPa. There was no significant relationship between RI and fuel type. The RI can be predicted by the crank angle degree (CAD) at 50 CA. Carbon monoxide (CO) and hydrocarbon (HC) emissions were minimized at high RI conditions. The shortest burn duration under low RI was effective in achieving low HC and CO emissions.

Exhaust Emissions Characteristics on the SI Engine according to the Air-Fuel Mixture with Ozone (혼합기 오존 첨가에 따른 SI기관의 배기배출물 특성)

  • Lee, B.H.;Yi, C.S.;Lee, Y.H.;Lee, C.K.;Jeong, H.M.;Chung, H.S.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.5-10
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    • 2006
  • In a conventional and lean operating engine, the state of mixture is very important in the combustion and emission characteristics. Lean operation is known to decrease the formation while maintaining a good fuel economy, but the unstable operation due to misfire and erratic combustion prevents engines from being operated at very lean mixtures, so both combustion rates and exhaust emission formation need to be satisfied comparably. In this study, it is designed and experimented the modified engine, and analyzed the combustion and exhaust emission according to the change of engine speed and with adding ozone. The conclusions were drawn out and enumerated as follows. 1. At the experimental result of automobile diesel engine, it has been verified that the formation of particulate matter(PM) gas is able to be lower with the addition of optimum quantities of ozone. 2. Carbon monoxide(CO) was formed by the lack of oxygen and the thermal dissociation in the combustion process. Therefore, with the change of swirl valve's position and addition of oxygen and ozone, CO formation was decreased by the increasing of excessive O2, but it was increased by the temperature of combustion gas growing higher. As a result of the two effects, CO formation was decreased in this study. 3. Hydrocarbon(HC) was formed by the lack of O2, and the flow of mixture in cylinder. According to opening of the swirl valve and adding the oxygen and ozone, hydrocarbon gas was decreased by 20%, 9%, and 27.5%, respectively. 4. Nitric oxides($NO_x$) was strongly affected by the combustion gas temperature. As a result of respectively experimental conditions, $NO_x$ formation was increased about 20% due to (be the) high(er) combustion gas temperature.

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