• Title/Summary/Keyword: Hydration number

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The Plastic Cracking Properties of Fly Ash Concrete with Various Curing Conditions (양생조건에 따른 플라이애쉬 콘크리트의 소성수축균열 특성)

  • Nam, Jae-Hyun;Park, Jong-Hwa
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.1 s.23
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    • pp.91-98
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    • 2007
  • In this study, the property and plastic cracking pattern of concrete were compared and analyzed with the replacement ratio of fly ash 0, 5, 10, 15, 20% by cement weight. And curing conditions of concrete were given variously such as indoors(with wind speed as 0, 300, 500m/min), outdoors and chamber. The hydration temperature had a tendency to decrease as the replacement ratio of fly ash increased, and in the case of the wind speed 0m/min, it was showed that the moment that the amount of evaporation of water from surface of reference concrete was more than the volume of bleeding was 90 min since casting concrete. The time that the crack initiated had a tendency to be more quickly as the replacement ratio of fly ash increased. The number, length, width and area of crack in the indoor curing, exposed outdoor curing, enclosed outdoor curing had a tendency to decrease as the replacement ratio of fly ash increased. The crack had a tendency to decrease in sequence of exposed outdoor, enclosed outdoor curing, indoors curing. The outbreak of cracking by the change of temperature and humidity was affected by relative humidity more than temperature and the cracking had a tendency to increase as relative humidity lowered.

Studies on Genetics and Breeding in Rainbow Trout, Oncorhynchus mykiss Ⅷ. Ultrasturctural Changes of Oocytes in Reproductive Cycles (무지개 송어의 유전육종학적 연구 Ⅷ. 난모세포의 고아학 및 미세구조적 변화)

  • 윤종만;김영곤;박홍양
    • Korean Journal of Animal Reproduction
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    • v.15 no.3
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    • pp.207-220
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    • 1991
  • This study was carried out to investigate the ultrastructural changes of ooplasm and follicular membrane of oocytes, obtained from 150 of 3-year-old female rainbow trout(Oncorhynchus mykiss). All data were collected from March in 1989 to February in 1990, and from August to October in 1991. The size of the nucleoli and number of the yolk granules increased as the oocyte growed. Yolk granules were deposited in the oocyte as crystalline granules. Due to the presence of large early and late maturing oocytes, their ovaires were enlarged, transparent and granular. The lattice was broken down at hydration, leaving the egg transparent. As thepercentages of fish in LPO and EMO stage increased from September to October, Mean GSI values increased. Follicle cells such as granulosa cell and thecal cell change a squamous into cuboid shape in LPO and EMO stage. Seasonal changes in the microscopic appearance of the ovaries were well correlated with those in bothgonadosomatic index and macroscopic apearance. Under the natural conditions,t he ovarian follicle influences the histological development and periodical secretion of the hormones, sufficient for a oogenesis and gonadal steroid production. The electrophoretic pattern of major band in mature stage was much thicker(70∼110k dalton) than that in previtellogenic phase.

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Breeding and Reproductive Studies on Korean Native Loach (Misgurnus anguillicaudatus) IV. Electron Microscopic Observation on Vitellogenesis and Maturation in Oocytes (한국산 미꾸리에 관한 육종.번식학적 연구 IV. 난모세포의 난황 형성 및 성숙에 관한 전자현미경적 관찰)

  • 윤종만;이종영;이경호;박인홍
    • Korean Journal of Animal Reproduction
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    • v.16 no.3
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    • pp.247-260
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    • 1992
  • This study was carried out to investigate the histomorphological changes of ovaries obtained from 100 of 1-year-old female Korean loach(misgurnus anguillicaudatus). The light microscopic and ultrastructural changes ofooplasm and follicular membranes of oocytes, were observed by lightand transmission electron microscope during the reproductive cycle. All data were collected from November in 1991 to May in 1992. The results obtained in this study were as follows: The size of the nucleoli and number of the yolk granules increased as the oocytes grown. Yolk granules were loosely deposited in the oocytes as crystalline granules. Due to the presence of large early and late maturing oocytes, their ovaries were enlarged, transparent, granular and yellowish in color. The lattice was broken down at hydration, leaving the egg transparent. As the percentages of fish in LMO and RO stage increased from March to April, mean gonadosomatic index(GSI) values(18.49%) increased. Zona radiata change a squamous into cuboid shape in EMO stage. Processes from the granulosa cells and from the oocyte, microvilli grow and make contact with other in the pore canals of the zona radiata during vitellogenesis, but are withdrawn as the zona radiata becomes more compact and devoid of pore canals during oocyte maturation. Seasonal changes in the microscopic appearance of the ovaries were well correlated with those in both GSI and macroscopic appearance.

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Development of Two Dimensional Chloride Ion Penetration Model Using Moving Mesh Technique (Moving Mesh Technique을 이용한 2차원 염해 침투 예측 모델의 개발)

  • Choi, Won;Kim, Hanjoong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.6
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    • pp.1-7
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    • 2015
  • Most of chloride diffusion models based on finite difference method (FDM) could not express the diffusion in horizontal direction at each elevation. To overcome these weakness, two dimensional chloride ion penetration model based on finite element method (FEM) to be able to combine various multi-physics simultaneously was suggested by introducing moving mesh technique. To avoid the generation of mesh being able to be distorted depending on the relative movement of water level to static concrete, a rectangular type of mesh was intentionally adopted and the total number of meshes was empirically selected. The simulated results showed that the contents of surface chloride decreased following to the increase of elevation in the top part of low sea level, whereas there were no changes in the bottom part of low level. In the DuraCrete model, the diffusion coefficient of splashed zone is generally smaller than submerged zone, whereas the trend of Life365 model is reverse. Therefore, it could be understood that the developed model using moving mesh technique effectively reflects $DuraCrete^{TM}$ model rather than $Life365^{TM}$ model. In the future, the model will be easily expanded to be combined with various multi-physics models considering water evaporation, heat of hydration, irradiation effect of sun and so on because it is based on FEM.

Transdermal Permeation of $[{^3}H]Acyclovir$ Using Niosome (니오솜을 이용한 $[^{3}H]$아시클로버의 경피투과)

  • Park, Sae-Hae;Lee, Soon-Young;Yong, Chul-Soon
    • Journal of Pharmaceutical Investigation
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    • v.28 no.1
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    • pp.43-50
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    • 1998
  • Niosomes are vesicles formed from synthetic non-ionic surfactants, offering an alternative to chemically unstable and expensive liposomes as a drug carrier. Non-ionic surfactant and cholesterol mixture film leads to the formation of vesicular system by hydration with sonication method. The formation of niosome was ascertained by negative staining of TEM. The entrapment efficiency of niosomal suspension was gradually increased with increasing the ratio of cholesterol to surfactant. It was found that the niosome with 6 : 4 (polyoxyethylene 2-cetyl ether: cholesterol) ratio was more stable than those with other ratios. The topical application of acyclovir(ACV) in the treatment of herpes simplex virus type 1(HSV-1) skin disease has a long history. There are an increasing number of reports, however, in which topical ACV therapy is not as effective as oral administration. Lack of efficacy with topical ACV has been hypothesized to reflect the inadequate delivery of drug to the skin. We investigated the permeation of niosome containing $[^{3}H]ACV$ in hairless mouse skin using Franz diffusion cell model. Permeation coefficient(P) of aqueous ACV was $6.7{\times}10^{-4}\;(cm/hr)$ and that of ACV in niosome was $23.4{\times}10^{-4}\;(cm/hr)$, suggesting about 3.5 times increase in the transdermal permeation.

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Solvent Effect on $Rb^+$ to $K^+$ Iron Mutation: Monte Carlo Simulation Study

  • Kim, Hak Seong
    • Bulletin of the Korean Chemical Society
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    • v.21 no.5
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    • pp.503-509
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    • 2000
  • The solvent effects on the relative free energies of solvation and the difference in partition coefficients (log P) for $Rb^+$ to $K^+$ mutation in several solvents have been investigated using Monte Carlo simulation (MCS) of statistical perturbation theory(SPT). In comparing the relative free energies for interconversion of one ion pair, $Rb^+$ to $K^+$, in $H_2O$(TIP4P) in this study with the relative free energies of the computer simulations and the experimental, we found that the figure in this study with the relative free energies of the computert simulations and the experimental, we found that the figure in this study is $-5.00\pm0.11$ kcal/mol and those of the computer simulations are $-5.40\pm1.9$, -5.5, and -5.4 kcal/mol. The experimental is -5.1 kcal/mol. There is good agreement among various studies, taking into account both methods used to obtain the hydration free energies and standard deviations. There is also good agreement between the calculated structural properties of this study and the simulations, ab initio and the experimental results. We have explained the deviation of the relationship between the free energy difference and the Onsager dielectric function of solvents by the electron pair donor properties of the solvents. For the $Rb^+$ and $K^+$ ion pair, the Onsager dielectric function of solvents (or solvent permittivity), donor number of solvent and the differences in solvation dominate the differences in the relative free energies of solvation and partition coefficients.

Rate Augmentation of Exothermic Hydration in the CaO Packed Bed (CaO 충전층의 수화발열반응 촉진)

  • Chung, Soo-Yull;Kim, Jong-Shik
    • Solar Energy
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    • v.14 no.2
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    • pp.91-101
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    • 1994
  • Heat release characteristics of a CaO packed bed reactor which is used for a chemical heat storage device has been studied. We employed Cu-plate fins to release the heat of reaction of the CaO packed bed inside the reactor fast and effectively. Two-dimensional analysis of unsteady state heat flow inside the bed was performed as a function of time and under various conditions of the Cu-plates. It is noted that the time required to release the heat of reaction with Cu fins is reduced more than twice fast compared to that without Cu fins. That was largely dependent upon the number of Cu-plate, as well.

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Terahertz Spectral Characteristics of Electrolyte Solutions under Different Magnetic Fields

  • Shao, Siyu;Huang, Haiyun;Peng, Bo;Wang, Guoyang;Ye, Ping;Wang, Jiahui;Su, Bo;Cui, Hailin;Zhang, Cunlin
    • Current Optics and Photonics
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    • v.6 no.3
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    • pp.337-343
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    • 2022
  • Microfluidic chips are new devices that can manipulate liquids at the micrometer level, and terahertz (THz) time-domain spectroscopy has good applicability in biochemical detection. The combination of these two technologies can shorten the distance between sample and THz wave, reduce THz wave absorption by water, and more effectively analyze the kinetics of biochemical reactions in aqueous solutions. This study investigates the effects of different external magnetic field intensities on the THz transmission characteristics of deionized water, CuSO4, CuCl2, (CH3COO)2Cu, Na2SO4, NaCl, and CH3COONa; the THz spectral intensity of the sample solutions decrease with increasing intensity of the applied magnetic field. Analysis shows that the magnetic field leads to a change in the dipole moment of water molecules in water and electrolyte solutions, which enhances not only the hydrogen-bond networking ability of water but also the hydration around ions in electrolyte solutions, increasing the number of hydrogen bonds. Increasing the intensity of this magnetic field further promotes the hydrogen-bond association between water molecules, weakening the THz transmission intensity of the solution.

Effect of Saccharides on the Gelation and Retrogradation of Starch (전분의 겔화와 노화에 미치는 당류의 영향)

  • 김경이
    • Food Science and Preservation
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    • v.10 no.4
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    • pp.506-511
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    • 2003
  • DSC was used to investigate the thermal mechanism of acorn and corn starch with or without saccharides on gelation and retrogradation. When the samples were starch-saccharide-water system (s-s-w), from measuring of gelation enthalpy and temperatures of initial gelation, peak and conclusion(T$\_$0/, T$\_$p/, T$\_$c/), those of s-s-w system were higher than those of stank-water system (s-w). The retrogradation enthalpy of acorn starch and corn starch was straightly increasing by DSC measurement as storage times. This increase meant slowly becoming recrygtallization of amylopectin. In retrogyadation process, the starch-saccharide-water system's enthalpy was also increased. After 7 days went, the value of the enthalpy was steady. Saccharides were retarding retrogrodation because of stopping the recrystallization of amylopectin. Especially in using fructose and maltose, the retrogradation effect of maltose was well. These elements took effect the number of juntion zone, one of equatorial OH and dynamic hydration number. As these three elements were increasing, a starch-Rel-system was stabilizing.

Minimized Radiation Dose of Patients Receiving High Dose Radioiodine(I-131) Therapy (고용량 방사성옥소(I-131) 치료환자의 피폭선량 저감화 연구)

  • Lee, Gui-Won
    • Journal of radiological science and technology
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    • v.30 no.4
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    • pp.435-442
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    • 2007
  • The number of thyroid diseases treated with radioiodine(I-131) is increasing steadily. The sharp increase in patients who require high dose radioiodine therapy greatly increased the need for new therapy rooms. Accordingly, interest in radiation exposure is rising as well, and is a major psychological stress factor for the patient and those who come in close contact with the patient. This study aimed to minimize the radiation exposure on discharge. Based on various previous reports, the decision for discharge should be individualized depending on many factors related to the patient's living or working environment. Educating patients repeatedly on the importance of sufficient oral hydration, while the adequate amount was relative to the patient's individual condition, greatly lowered the detected radiation measurement within the same admission period. In some cases, the period of admission could be abbreviated.

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