• Title/Summary/Keyword: Hydration behavior

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HYDRATION DEPENDENCE OF DRIED ORIENTED PURPLE MEMBRANE FILMS ACTIVITY

  • Lee, Ki-Hwan;Boucher, Francois;McIntosh, Alan R.
    • Journal of Photoscience
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    • v.2 no.2
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    • pp.69-72
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    • 1995
  • Dry orderly oriented purple membrane from Halobacterium halobium was obtained by a new technique of preparation. This oriented purple membrane film was very stable, nearly permanently, and showed long term reproducibility with respect to its photochemical behavior. In addition, we have investigated the photooptical properties in terms of the M$_{412}$ intermediate of the bacteriorhodopsin photocycle with respect to the humidity of the film. The relative optical density, i.e. its apparent concentration of the M$_{412}$ intermediate was decreased with the humidity increase as a function of the intensity of the exciting flash within our experimental range. It is suggested that the bound water molecules play an important role in the structure of the bacteriorhodopsin.

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Plan IE Design Of Extradosed Bridge Supported by Single Plane Cables (일면지지식 Extradosed교의 계획 및 설계)

  • 이종대;이두화;권소진;김종수;손준상
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.615-620
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    • 2001
  • The aim of this paper is to open up a relatively new type in bridge engineering by introducing plan and design of extradosed bridge which is implemented in Sungnam-Janghowon T/K project. The topic encompasses parametric study including the behavior of the bridge relevant to the cable layout, the distance from pier table to the first cable's location, the height of pylon, the stiffness of cross section and wind vibration to ascertain sectional type of bridge and span length. For the purpose of the knowledge base presented here, the important feature of design is recommended such as modeling method, camber control, finite element analysis and heat hydration of pier table. We can verify the issue related to the characteristics of extradosed bridge as a result of study and design endeavor.

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Dissolution of Protons in Oxides

  • Norby, Truls
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.128-135
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    • 1998
  • The paper gives a brief introduction to protonic defects and their chemistry, thermodynamics and transport in oxides. The temperature dependence of the equilibrium concentration of protons is illustrated and compared for different acceptor-doped oxides. The difficulties of saturating as well as emptying the oxides of protons are discussed. In order to illustrate the possibility of lattice relaxation of defects, a conceptual study is made of a case where the enthalpy of dissolution of protons(water) at the cost of oxygen vacancies is assumed dependent on the concentration of vacancies. It is shown how this changes the behavior of hydration curves vs temperature and water vapour pressure. finally, a discussion is given on the water uptake in heavily oxygen deficient oxides; how water uptake may affect order-disorder in the oxygen sublattice and eventually lead to defective, disordered or ordered oxyhydroxides or hydroxides of potential interest as intermediate temperature proton conductions.

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Experimental Study on Fracture Behavior of Low-Heat Concrete, by Three-Point Bent Test (3점 휨시험에의한 저발열콘크리트의 파괴거동에 곤한 실험적 연구)

  • 조병완;박승국
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.199-204
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    • 1998
  • To analysis the failure character of Low-Heat concrete which is used to prevent the thermal crack caused by hydration heat, static loading test was performed by this test method, "Determination of the Fracture Energy of Motar and Concrete by Means of Three-Point Band Tests on Notched Beam" (suggested by RILEM 50-FMC Committe). This study compared and analysised the fracture energy of Mode I (opening mode), the most general pattern in the view of water-cemente ratio(W/C), compressive strength and age of Ordinary Portland Concrete and Low-Heat Concrete under the same mixture. The test results show that the case of Ordinary Portland Concrete and Low-Heat Concrete, low Water-Cemente ratio(W/C) cause the increase of fracture energy, and high failure-strength decrease failure-deflection, and the fracture energy of Low-Heat Concrete is similar to Ordinary Portland Concrete as the age increase. increase.

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Ultrasonic Measurement in Bovine Serum Albumin Solution (Bovine Serum Albumin 수용액의 초음파 측정)

  • Jong-Rim Bae;Seung Hyun Chang
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.329-334
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    • 1992
  • Ultrasonic absorption was measured in bovine serum albumin (BSA) aqueous solution (50 g/l) in the frequency range from 100 kHz to 1600 MHz at neutral pH. Three experimental techniques were used to cover the wide frequency range : plano-concave resonator, conventional Bragg reflection, and high-resolution Bragg reflection methods. The absorption spectrum at neutral pH fitted the relaxation curve well using the distribution function of a mirror image of Davidson-Cole function. The relaxaition behavior was interpreted in terms of various degree of hydration of BSA molecules.

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A Study on Behavior of Novel Non-Metallic Anchoring System for FRP Tendons (FRP 긴장재의 비금속 정착 시스템의 거동에 관한 연구)

  • 서관세;조병완;이계삼;김영진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.983-988
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    • 2000
  • Anchoring systems with structural stability and endurance have been one of the most important elements for PSC structures, especially for the structures using non-corrosive FRP tendons. FRP tendons are in increasing use for underground and coastal structures constantly contacted with fresh water or sea water because of their superiority to metallic ones in corrosion-resistance. In this study new non-metallic anchoring system for FRP tendons has been tested and investigated. The newly developed anchoring system utilizes FRP pipes and HEM (Highly Expansive Mortar). The major factors considered in this experiment were expansive pressure of HEM during its hydration and the strength of GFRP(Glass Fiber Reinforced Plastic) Pipe. Anchoring forces of the new anchoring system were investigated from the pull-out testes. The authors analyzed pull-out procedures of the FRP tendons in the various pipe filled with HEM and suggested an improved idea to develop novel non-metallic anchoring system for FRP tendons

Cement Paste Hardened Body with High Temperature Exposure Time Fourier Transform Infrared Spectroscopy (고온 노출 시간에 따른 시멘트 페이스트 경화체의 푸리에 변환 적외분광 분석)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.120-121
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    • 2019
  • In this study, FT-IR analysis was performed by exposing cement paste to high temperature in order to characterize the change of hydration behavior of concrete structure damaged by fire accident. As the holding time increased, the Al-O vibration region increased due to the increase of Si-O symmetric Ca2(SiO4) and Brownilerite, and the OH stretching region tended to increase due to thermal decomposition of Ca(OH)2.

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SAMs of 2-Aminoethanethiol Modified with 3,4-Dihydroxyphenylalanine for the Electrocatalytic Oxidation of NADH on Gold Electrodes

  • Cha, Seong-Keuck
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.786-790
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    • 2004
  • 2-Aminoethanethiol (aet) has been used to make self-assembled monolayer (SAMs) on gold electrodes, which are subsequently modified with 3,4-dihydroxy phenylalanine (dpa). Such modified electrodes having various types of Au/aet-dpa were employed in the electrocatalytic oxidation of NADH. The purpose of this study to characterize the responses of such modified electrodes in terms of the immobilization procedure, pH of the solution and applied potential. The reaction of the surface immobilized dpa with NADH was studied using the rotating disk electrode technique and a value of $2.2{\times}10^4M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M Tris/$NO_3^-$buffer (pH=8.0). The hydration behavior of the films was characterized by quartz crystal microbalance. When used as a NADH sensor, the Au/aet-dpa electrode exhibited good sensitivity and an excellent correlation (r ${\geq}$ 0.99) for NADH concentration which extended to $3.8{\times}10^{-3}$ M.

Comparative Experimental Study on Structural Behavior of Multi-component Self-Compacting Concrete (다성분계 고유동 콘크리트의 장${\cdot}$단기거동 비교 분석)

  • Noh Jea Myoung;Kwon Ki Joo;Nah Hwan Seon;Joung Won Seoup
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.735-738
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    • 2004
  • In this study, it was founded to make the optimal mixture for producing concrete which is self-compacting, yet, and generates low heat of hydration by using fly ash, blast furnace slags and limestone powders as binders in addition to cement while using super-plasticizers and viscosity agents as admixture agents. The structural behaviors of the concrete produced with the selected mixture were compared with those of the concrete currently using for construction of nuclear power plants. The study shows that the blended high fluidity concrete including limestone is better in workability and durability than the concrete currently in use for nuclear power plants.

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Skin Hydration Effect of Brasenia schreberi Mucilage Polysaccharide Extract (순채 점액질 다당체 추출물의 피부 보습 효과 연구)

  • Ahn, Seyeon;Gil, Soyeon;Kwon, Ohsun;Chang, Yunhee;Jin, Mu Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.3
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    • pp.223-230
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    • 2017
  • In this study, we evaluated the skin moisturizing effect of Brasenia schreberi (B. schreberi) mucilage polysaccharide on human skin and in vitro and the potent cosmetic ingredient for skin. To protect skin from various environmental stresses and aging, we should increase moisture content of skin and prevent water loss. We have found that polysaccharides extracted from mucilage of B. schreberi improved the roughness of skin with its lubricating behavior. In vitro, the expression of transglutaminase 1 (TGM1) gene, which plays a role in cross-linking the skin barrier, was increased when the keratinocytes were treated with B. schreberi polysaccharides. In addition, the expression of hyaluronan synthase 3 (HAS3) gene, an enzyme that synthesizes water-binding matrix hyaluronic acid, aquaporin 3 (AQP3), which regulates the movement of water and glycerol were also increased. In addition, an experiment to evaluate its potential as a cosmetic ingredient has shown anti-inflammatory and collagen synthesis-promoting effects. As a result, the mucilaginous polysaccharide from natural products which has not existed before, showed moisturizing effect, anti-inflammation and collagen synthesis-promoting effects for skin protection and hydration.