• Title/Summary/Keyword: Hydration Analysis

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A Study on Hydration kinetics and Mechanical Properties of Cement Paste Incoporating Limestone Filler (석회석 미분말을 혼입한 시멘트 페이스트의 수화반응 및 역학적 특성 분석에 관한 연구)

  • Shin, Ki-Su;Bang, Mi-Jin;Park, Ki-Bong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.230-231
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    • 2017
  • The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.

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The Correlation Analysis of Fluid Intake, Skin Hydration and Skin pH of College Students (대학생의 수분섭취, 피부 수분보유도 및 피부 pH와의 관계)

  • Kim, Nam-Jo;Hong, Hae Sook
    • Journal of Korean Biological Nursing Science
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    • v.17 no.2
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    • pp.132-139
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    • 2015
  • Purpose: The purpose of this study was to verify the correlation analysis between fluid intake on skin hydration and pH of college students. Methods: The subjects were 129 female nursing students in D city. Data were collected by a self-administered questionnaire, using a skin moisture checker and skin pH meter on faces, hands, and feet. The collected data were analyzed by descriptive statistics, t-test, ANOVA, and Pearson correlation analysis, using SPSS WIN, 20. Results: The daily fluid intake was composed of 57% pure water, 21% caffeinated beverages, 22% non-caffeinated beverages. There were significant differences in average skin hydration on the three body parts according to pure water, caffeinated beverages, and non-caffeinated beverages; however, there was no significant difference measured by fluid intake. There was a significant positive correlation between fluid intake and skin hydration: between pure water and skin hydration. There was significant negative correlation between caffeinated beverages and skin hydration: between non-caffeinated beverages and skin hydration. Conclusion: The results suggest that fluid intake, pure water, caffeinated beverages, and non-caffeinated beverages have an effect on skin hydration and pH. Therefore, it is good to increase the amount of fluid intake but, it is recommended to increase the amount of intake of pure water rather than beverages to improve skin status.

Degree of hydration-based thermal stress analysis of large-size CFST incorporating creep

  • Xie, Jinbao;Sun, Jianyuan;Bai, Zhizhou
    • Steel and Composite Structures
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    • v.45 no.2
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    • pp.263-279
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    • 2022
  • With the span and arch rib size of concrete-filled steel tube (CFST) arch bridges increase, the hydration heat of pumped mass concrete inside large-size steel tube causes a significant temperature variation, leading to a risk of thermal stress-induced cracking during construction. In order to tackle this phenomenon, a hydration heat conduction model based on hydration degree was established through a nonlinear temperature analysis incorporating an exothermic hydration process to obtain the temperature field of large-size CFST. Subsequently, based on the evolution of elastic modulus based on hydration degree and early-age creep rectification, the finite element model (FEM) model and analytical study were respectively adopted to investigate the variation of the thermal stress of CFST during hydration heat release, and reasonable agreement between the results of two methods is found. Finally, a comparative study of the thermal stress with and without considering early-age creep was conducted.

Microscopic Characterization of Cement Composites with Carbon Nanotubes (탄소나노튜브가 첨가된 시멘트복합체의 미시적특성분석)

  • Kim, Young-Min;Lee, Gun Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.176-177
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    • 2019
  • As a result of the Rietveld analysis to determine the effect of carbon nanotubes on the hydration products of cement composites, the quantitative difference of hydration products according to the addition rate of carbon nanotubes was not significant. Ettringite, an early hydration product, was measured to be slightly higher than the planes with carbon nanotubes over all ages. Therefore, it seems that carbon nanotubes have no effect on the hydration production in cement paste.

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Analysis of hydration of ultra high performance concrete (초고성능 콘크리트의 수화모델에 대한 연구)

  • Wang, Hai-Long;Wang, Xiao-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.13-14
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    • 2014
  • Ultra high performance concrete (UHPC) consists of cement, silica fume (SF), sand, fibers, water and superplasticizer. Typical water/binder-ratios are 0.15-0.20 with 20-30% of silica fume. The development off properties of hardening UHPC relates with both hydration of cement and pozzolanic reaction of silicafume. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of UHPC. The degree of hydration of cement and degree of reaction of silica fume are obtained as accompanied results from the proposed hydration model. The properties of hardening UHPC, such as degree of hydration of cement, calcium hydroxide contents, and compressive strength, are predicted from the contribution of cement hydration and pozzolanic reaction. The proposed model is verified through experimental data on concrete with different water-to-binder ratios and silica fume substitution ratios.

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Hydration Heat Analysis of Wall according to Placement Length (벽체 타설길이별 수화열 해석)

  • 김태홍;하재담;유재상;이종열;권영호;배수호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.301-304
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    • 2003
  • Nowadays, hydration heat analysis using FEM is common in thermal crack control of concrete structure. Many kinds of general FEM programs for hydration heat analysis are used in practice. But there are some problems in this using. In this study hydration heat analysis of wall according to placement length are performed. In this results we could get two conclusions. First, general structures like wall having general geometry and construction condition have similar behavior. So it is not necessary to analysis thermal crack in every case. Second, the results of 2D analysis is possible to be applied instead of those of 3D analysis because the results of 2D analysis is similar to 3D analysis in long wall having about 15~18m or over length at 3m height.

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Field Application of Mass Concrete Applying Hydration Heat Differential Method and Insulation Curing Method (수화발열량차 및 단열양생 공법을 활용한 매스콘크리트의 현장적용)

  • Han, Jun-Hui;Lim, Gun-Su;Shin, Se-Jun;Jeon, Choung-Keun;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.227-228
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    • 2023
  • This study is tocompare and analyze the results of hydration heat analysis and on-field measurements using the method with hydration heat difference and insulation curing method for controlling hydration heat in mass concrete. As a result of the analysis, the temperature difference between the center and the surface was predicted very similarly, and the mass concrete surface was controlled to a safe level when evaluating with a temperature crack index, and after being finished, it was confirmed that there was no hydration crack.

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The Analysis of Early Age Properties of Hydration Heat and Autogenous Shrinkage according to Specimen Size and Retardation of Hydration (시험체 크기 및 수화지연 효과에 따른 초기재령 수화발열 및 자기수축 특성 분석)

  • Kim, Gyu-Yong;Koo, Kyung-Mo;Lee, Hyoung-Jun;Lee, Eui-Bae
    • Journal of the Korea Concrete Institute
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    • v.21 no.4
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    • pp.481-488
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    • 2009
  • It has been reported that the magnitude and the development rate of autogenous shrinkage of cement paste, mortar and concrete were affected by history and magnitude of inner temperature at an early age. But it was not enough to explain the relation between hydration heat and autogenous shrinkage at an early age, because there was no certain analysis on histories of hydration heat and autogenous shrinkage in previous studies. In our prior study, to understand the relationship between hydration heat and autogenous shrinkage of concrete at an early age, the analysis method for histories of hydration heat and autogenous shrinkage was suggested. Based on this method, early age properties of hydration heat and autogenous shrinkage of high strength concrete with different sizes and hydration retardation were investigated in this study. As a result of the study, properties of hydration temperature and autogenous shrinkage were different according to specimen size and hydration retardation. However, there was a close relationship between hydration temperature and autogenous shrinkage at an early age, especially between HHV and ASV as linear slopes of the sections where hydration temperature and autogenous shrinkage increase rapidly; the higher HHV, the higher ASV and the greater ultimate autogenous shrinkage. And it was found that, among the setting time, bend point and temperature increasing point, they were close relationship each other on cement hydration process.

A Parameter Study on Heat of Hydration in Mass Concrete Affected by Foundation Depth and Various Thermal Properties (지반 깊이 및 열특성 영향에 따른 매스콘크리트의 수화열 해석)

  • 채숙희;양성철;박종원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.799-804
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    • 2002
  • This paper is mainly Intended to show an effect of foundation depth on heat of hydration in mass concrete. From the analysis, it was found that the foundation depth which is not affected by the heat conduction is more than 5 m. But this study shows that, an optimum foundation depth for the FEM analysis for heat of hydration in mass concrete is approximately 1 m from this study. And in order to study tile significance of various parameters, a sensitivity analysis of heat transfer in mass concrete is performed and the amount of heat liberated at complete hydration of unit weight of cement and the reaction velocity of hydration are the most sensitive parameters factors of other various parameters.

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Reaction Characteristics of Geopolymer Paste Incorporating Fly-ash and GGBS (플라이애쉬와 고로슬래그 미분말을 혼입한 지오폴리머 페이스트의 반응특성 분석)

  • Shin, Ki-Su;Park, Ki-Bong
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.4
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    • pp.321-330
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    • 2020
  • The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. In previous studies, it has been found that the addition of LF to reduce the cementitious paste volume would substantially increase the compressive strength, and reduce the heat generation. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.