• Title/Summary/Keyword: Hybrid film

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Synthesis and Luminescence Preparation of Organic/Inorganic Polymer Hybrid from Novolac Derivatives

  • Konishi, Gen-ichi;Kimura, Tsuyoshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.316-316
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    • 2006
  • The preparation of an organic/inorganic polymer hybrid from a novolac derivatives is described. The hybrid was prepared by the acid-catalyzed solgel reaction of phenyl-trimethoxysilane (PhTMOS) in the presence of anisole novolac. The resulting film was transparent and showed a high heat stability. The dispersion of two components might be due to the utilization of the p-p interaction between the phenyl ring of the silica matrix and that of novolac. This makes it possible to prepare a hybrid glass having a highly content of novolac derivatives.

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Hybrid Passivation for Organic-Thin Film Transistor on Plastic

  • Han, Seung-Hoon;Kim, Yong-Hee;Kim, Sung-Hoon;Kim, Chang-Hyun;Jeon, Tae-Woo;Lee, Sun-Hee;Choi, Min-Hee;Choo, Dong-Jun;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.979-982
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    • 2008
  • We studied hybrid passivation using parylene-C, metal, photoacyl and indium zinc oxide for pentacene OTFT to assure stability in subthreshold region. After the passivation, the changes in S and $V_{on}$ of OTFT were negligible and $I_{off}$ maintained its initial value of ${\sim}10^{-12}$ A. Therefore, the hybrid passivation is suitable for practical applications based on OTFT.

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Study on the Effect of Performance Factors on the Evaporator Using Liquid Desiccant Falling Flim for Dehumidification (습식건조제 이용 제습에서의 증발기 성능인자 영향 연구)

  • Park, M.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.3
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    • pp.512-520
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    • 1995
  • This study investigates the simultanceous heat and mass transfer between a falling desiccant film and air in cross flow at the interface. The application of this work is the optimization of falling film evaporators for use in potential hybrid air conditioning systems. The specific geometry considered is liquid TEG films falling along the vertical cooled surfaces of a channel with air in cross flow. The equations to describe the coupled heat and mass transfer between a falling desiccant film and air in cross flow for a falling film evaporator have been presented and solved numerically. The effects of important design and operating variables on the evaporator performance predicted by the parametric numerical analysis and suggestions for performance improvements of the evaporator are presented.

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A GDD Model for Super Sweet Corn Grown under Black P. E. Film Mulch (흑색 P. E. Film 피복에서 초당옥수수의 생육기간을 표시하는 GDD모델 개발)

  • Lee, Suk-Soon;Yang, Seung-Kyu;Hong, Seung-Beom
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.53 no.1
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    • pp.42-49
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    • 2008
  • GDD models of corn were developed in bare soil, while sweet and super sweet corns are grown under black polyethylene (P. E.) film mulch in Korea. To develop a suitable GDD model under black P. E. film mulch, a super sweet com hybrid "Cambella-90" was planted from 1 April to 30 June in 2003 at the 10-day intervals under black P. E. film mulch and in bare soil. In bare soil the best GDD model was $GDD\;=\;{\sum}[H"+L')/2\;-\;10^{\circ}C]$, where H" was daily maximum temperature but is was substituted for $30^{\circ}C$ - (daily maximum temperature - $30^{\circ}C$) when higher than $30^{\circ}C$ and L' was daily minimum temperature, but it was substituted for $10^{\circ}C$ when lower than $10^{\circ}C$. The same GDD model could be adapted for com grown under black P. E. film mulch, but base temperature was substituted for $9^{\circ}C$. To determine planting date for the scheduled harvests, accumulated GDDs were calculated using 30-year average temperature data during the growing season. Under black P. E. film mulch planting dates were determined by subtracting GDD of the hybrid, $970^{\circ}C$, from accumulated GDD of scheduled harvest dates.

A study on the Initial Nanopore Formation in the Calix Arene Based Porogen Templated Porous Thin Film (칼릭스아렌 포로젠을 이용한 다공성 박막의 초기 나노기공 형성과정에 관한 연구)

  • Kim, Do-Hun;Yim, Jin-Heong
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.669-675
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    • 2011
  • Fourier Transform Infrared Spectroscopy and in-situ Position Annihilation Lifetime Spectroscopy(PALS) analysis of hybrid film, which consist of silsesquioxane(SSQ) and 4-tert-butyl calix[4]arene-O,O',O",O'"-tetraacetic acid tetraethyl ester(CA[4]) have been investigated in order to understand initial formation of nanopore in the next generation porous low-k dielectrics(k < 2.0). SSQ/CA[4] can provide effective homogeneous thin film having porous structure. The porogen decomposition behavior were completely different in the two kinds of SSQ/CA[4] based hybrid film (i.e. SSQ/CA[4] 10 and SSQ/CA[4] 20%). Relatively small pores(1.5 nm) come from dispersion of uni-molecular CA[4] in the SSQ matrix have been generated at $300^{\circ}C$, while mesopores(2.5~3.0 nm) induced from self assembled CA[4] have been generated at $250^{\circ}C$. It might be due to highly interconnected structure of SSQ/CA[4] 20% hybrid thin film resulting in facile evacuating of decomposed fragment of CA[4] molecule.

Staggered and Inverted Staggered Type Organic-Inorganic Hybrid TFTs with ZnO Channel Layer Deposited by Atomic Layer Deposition

  • Gong, Su-Cheol;Ryu, Sang-Ouk;Bang, Seok-Hwan;Jung, Woo-Ho;Jeon, Hyeong-Tag;Kim, Hyun-Chul;Choi, Young-Jun;Park, Hyung-Ho;Chang, Ho-Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.4
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    • pp.17-22
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    • 2009
  • Two different organic-inorganic hybrid thin film transistors (OITFTs) with the structures of glass/ITO/ZnO/PMMA/Al (staggered structure) and glass/ITO/PMMA/ZnO/Al (inverted staggered structure), were fabricated and their electrical and structural properties were compared. The ZnO thin films used as active channel layers were deposited by the atomic layer deposition (ALD) method at a temperature of $100^{\circ}C$. To investigate the effect of the substrates on their properties, the ZnO films were deposited on bare glass, PMMA/glass and ITO/glass substrates and their crystal properties and surface morphologies were analyzed. The structural properties of the ZnO films varied with the substrate conditions. The ZnO film deposited on the ITO/glass substrate showed better crystallinity and morphologies, such as a higher preferred c-axis orientation, lower FWHM value and larger particle size compared with the one deposited on the PMMA/glass substrate. The field effect mobility ($\mu$), threshold voltage ($V_T$) and $I_{on/off}$ switching ratio for the OITFT with the staggered structure were about $0.61\;cm^2/V{\cdot}s$, 5.5 V and $10^2$, whereas those of the OITFT with the inverted staggered structure were found to be $0.31\;cm^2/V{\cdot}s$, 6.8 V and 10, respectively. The improved electrical properties for the staggered OITFTs may originate from the improved crystal properties and larger particle size of the ZnO active layer.

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Properties of Paint Protection Film Containing Poly(urea-urethane)-based Self-Recovery Coating Layer (Poly(urea-urethane) 자기복원 코팅층을 가진 도장 보호필름 물성 연구)

  • Minseok Song
    • Journal of Adhesion and Interface
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    • v.24 no.2
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    • pp.69-75
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    • 2023
  • Recently, the application of paint protection films (PPFs) for automobiles having a self-recovery coating layer has been grown up. In this study, we report the evaluation results on the basic physical properties of a poly(vinyl chloride)- based PPF containing poly(urea-urethane) hybrid self-recovery coating layer. Depending on the main chemical composition and the thickness of poly(urea-urethane)-based coating layer for PPF, the self-recovery performance by an optical microscope and the stain resistance through color difference value are measured. To improve the surface properties and show its easy-cleaning effect against the polluted things, silicone-modified polyacrylate is introduced to the self-recovery coating composition. The contact angle of water on the coated surface is confirmed to show its hydrophobic surface. Finally, accelerated weathering test of paint protection film with poly(urea-urethane) hybrid coating layer is performed to check the possibility of discoloration and deformation due to long-term exposure on harsh condition.