• Proceedings of the KIEE Conference
• /
• 1997.07d
• /
• pp.1308-1310
• /
• 1997

Several methods for electrode fabrication of phosphoric acid fuel cell(PAFC) have been studied. The conventional methods that include a coating method and a rolling method, have disadvantages of a very complicated drying process and a hot pressing process for making a large electrode. In this study, to solve these problems, the mixing method of coating and rolling processes has been developed. In the mixing method, the electrode was coated on the electrode support and, after drying the coated layer, was rolled at room temperature and then sintered at $350^{\circ}C$. The single cell performances of the electrodes fabricated by several methods were examined and the mixing method appeared a good cell performance of 0.65 V, $260\;mA/cm^2$. Also the single cell with an area of $2000\;cm^2$ was manufactured and its performance attained 0.593 V, 300 A.

• Journal of the Korean institute of surface engineering
• /
• v.36 no.2
• /
• pp.200-205
• /
• 2003

Thermoelectric p-type $Fe_{0.98}$ $Mn_{ 0.02}$$Si_2$ bulk specimens have been produced by mechanical alloying and consolidation by vacuum hot pressing. The subsequent isothermal annealing was not able to fully transform the mestastable as -milled powders into the $\beta$ $-FeSi_2$ phase, so that the obtained matrix consisted of not only thermoelectric semiconducting $\beta$-FeSi$_2$ but also some residual, untransformed metallic $\alpha$ $- Fe_2$$Si_{ 5}$ and $\varepsilon$-FeSi mixtures. Interestingly, $\beta$ - $FeSi_2$ was more easily obtained in the low density specimen when compared to the high density specimen. The oxidation at 700 and $800^{\circ}C$ in air led to the phase transformation of the above described iron - silicides and the formation of a thin silica surface layer.

• Journal of Korean Ophthalmic Optics Society
• /
• v.5 no.2
• /
• pp.207-210
• /
• 2000

The SiC-TiC composites materials for glasses lens cutting were fabricated by hot-pressing and annealing. The amount of TiC was 0, 10, 20, 30wt% in the mixture of ${\beta}-SiC$. The microstructure of materials for glasses lens cutting was very dependent on the TiC amount. The introduction of larger amount of TiC improved fracture toughness, optical microscope and XRD analysis of the surface of samples were carried out. An in situ-toughened microstructure, consisted of distributed elongated SiC, matrix like TiC grains was developed by using ${\beta}-SiC$. Typical hardness and fracture toughness of materials for spectacle lens cutting were 14.9 GPa and $5.7MPa{\cdot}m^{1/2}$, respectively.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09b
• /
• pp.729-730
• /
• 2006

The research involves the development of a powder metallurgical route for producing good quality TiAl targets for making physical vapour deposition (PVD) coatings. Mixtures of elemental titanium and aluminium powders were mechanically milled using a novel discus milling technique under various conditions. Hot isotropic pressing (HIP) was then employed for consolidation of the mechanically alloyed powders. A cathodic arc vapour deposition process was applied to produce a TiAlN coating. Microstructural examination was conducted on the target material and PVD coatings, using X-ray diffractometry (XRD), X-ray photoelectron spectrometry (XPS) and scanning electron microscopy (SEM). It has been found that combining mechanical alloying and HIP enable us to produce fairly good quality of TiAl based target. The PVD coatings obtained from the TiAl target showed very high microhardness values.

• Journal of Powder Materials
• /
• v.5 no.1
• /
• pp.15-21
• /
• 1998

The effect of $\alpha$/$\beta$ phase on the mechanical properties and contact damage of silicon nitrides $Si_3N_4$) was investigated. Silicon nitride materials were prepared from two starting powders, at selective increasing hot-pressing temperatures to coarsen the microstructures: (i) from relatively coarse $\alpha$-phase powder, essentially equiaxed $\alpha$-$Si_3N_4$ grains, with limited, slow transformation to $\beta$-$Si_3N_4$ grain; (ii) from relatively fine $\alpha$-phase powder, a more rapid transformation to $\beta$-$Si_3N_4$, with attendant grain elongation. The resulting micro-structure thereby provided a spectrum of $\alpha$/$\beta$ phase ratios, grain sizes, and grain shapes. Fracture strength, hardness, and toughness were measured, and contact damage and strength degradation after indentation were investigated by Hertzian indentation using spherical indenter. A brittle to ductile transition in $Si_3N_4$ depended on $\alpha$/$\beta$ phase ratio as well as grain size. Silicon nitride with elongated $\beta$ grains showed a superior, contact damage resistance.

• Journal of Korea Foundry Society
• /
• v.26 no.4
• /
• pp.184-190
• /
• 2006

Presence of inclusions in Ti castings imparts detrimental effects on the mechanical performance of castings. However, actual inclusions do not occur very frequently and they are difficult to locate. As a result, acquirement of specimens for mechanical tests and thus in-depth research of the adverse influence of inclusions are challenging. To address this problem, artificial inclusion seeding methodology is developed to emulate actual inclusions in Ti investment castings. Firstly, to validate that this new methodology does not result in inherent mechanical property degradation, Ti specimens with machined, backfilled and HIPed holes are produced and compared to control (unaltered), cast Ti material. Fatigue test results indicate that this 'machine-and-HIP methodology without seeding' does not result in any fundamental mechanical property alteration, which would bias ensuing comparative results. Secondly, based on this result, validation of the artificially seeded inclusions being equivalent to 'as cast' inclusions is performed by comparing their fatigue behaviors. Test specimens created by the novel artificial inclusion seeding methodology are equivalent to Ti casting specimens containing actual cast-in inclusions, and an adverse effect of inclusions in investment castings is confirmed.

• Journal of the Korean Ceramic Society
• /
• v.38 no.12
• /
• pp.1080-1084
• /
• 2001

Alumina-based nanocomposites have improved mechanical properties such as hardness, fracture toughness and fracture strength compared to monolithic ceramics. In this study, alumina with 5 vol% of nanosized SiC was sintered by a hot pressing technique at 1600$\^{C}$, 30 MPa for 1h in an argon gas atmosphere. Microstructures and mechanical properties in alumina-SiC nanocomposite were investigated. Moreover, tribological properties in air and water were compared each other. Relationships of wear properties with mechanical properties such as hardness, strength, and fracture toughness as well as microstructure were studied. Based on experimental results it was found that nanosized SiC retarded grain growth of matrix alumina. Mechanical properties such as hardness, fracture toughness and strength were improved by the addition of nanosized SiC in alumina. Improved mechanical properties resulted in increased sliding wear resistance. Tribological behavior of nanocomposites in water seemed to be governed by abrasive wear.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.53-53
• /
• 2008

Piezoelectric transformers have been widely used such as DC-DC convertor, invertor, Ballast, etc. Because, the y have some merits compared with electro-magnetic transformers such as step-up ratio, high efficiency, small size and lg hit weight, etc. Piezoelectric transformer require high electromechanical coupling factor kp in order to induce a large out put power in proportional to applied electric field. And also, high mechanical quality factor Qm is required to prevent mechanical loss and heat generation. In general, PZT system ceramics should be sintered at high temperatures between 1200 and $1300^{\circ}C$ in order to obtain complete densification. Accordingly, environmental pollution due to its PbO evaporation. Hence, to reduce its sintering temperature, various kinds of material processing methods such as hot pressing, high energy mill, liquid phase sintering, and using ultra fine powder have been performed. Among these methods, liquid phase sintering is basically an effective method for aiding densification at low temperature. In this study, In order to comparis on low temperature sintering and solid state sintering piezoelectric transformers, rosen type transformers were fabricated u sing two PZT ceramics compositions and their electrical properties were investigated.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.10 no.6
• /
• pp.78-84
• /
• 2001

In the present study, SiCSi-$Si_3 N_4$-SiC ceramic composites that contained up to 30 wt% of dispersed SiC particles were fabricat-ed cia hot-pressing with an oxynitride glass. The microstructure, the mechanical properties and the cutting performance of resulting ceramic composites were investigated. By fixing the composition as $Si_3 N_4$-20wf%SiC, the effect of sintering time on the microstructure, the mechanical properties and the cutting performance were also investigated. The longer sir-tering time is, the bigger the grain size of SiC is. The fracture toughness(-$K_k$) of the $Si_3 N_4$-SiC ceramic composites increased with the increase of gain size, while the flexural strengthh($\sigma$) decreased. For machining SCM440, the insert with 20wt%r SiC sintered for 8 hours showed the longest tool life while the insert with 20wt% SiC sintered for 12 hours showed the longest tool life for machining gray cast iron.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.6 no.4
• /
• pp.552-557
• /
• 1996

Microstructural development of $Si_3N_4$/20 vol% SiC nanocomposites doped 2 wt% $Al_2O_3$ and 6 wt% $Y_2O_3$ as sintering additives were analyzed by sintering interruption. Density of samples was significantly increased between $1500^{\circ}C$ and $1700^{\circ}C$, and near full density was achieved at $1800^{\circ}C$. Transformation rate from $\alpha-Si_3N_4$ to $\betha-Si_3N_4$ was increased at $1700^{\circ}C$ and $1800^{\circ}C$, and then elongated matrix grains were appeared. Small size SiC particles had suppressive effect on densification rate and transformation of $Si_3N_4$ phase.