• Title/Summary/Keyword: Host-guest

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A Dilation-Improved Embedding of Pyramids into 3-Dimensional Meshes (피라미드의 3-차원 메쉬로의 신장율 개선 임베딩)

  • Chang, Jung-Hwan
    • The KIPS Transactions:PartA
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    • v.10A no.6
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    • pp.627-634
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    • 2003
  • In this paper, we consider a graph-theoretic problem,, the so-called "graph embedding problem" that maps the vertices and edges of the given guest graph model into the corresponding vertices and paths of the host graph under the condition of maintaining better performance parameters such as dilation, congestion, and expansion. We firstly propose a new mapping function which can embed the pyramid model with height N into the 3-dimensional mesh massively parallel processor system with the height $(4^{(N+1)/3}+2)/3$ and the regular 2-dimensional mesh of one side $2^{(2N-1)/3}$, and analyze the performance of the embedding in terms of the dilation parameter that reflects the number of communication steps between two adjacent vertices under the embedding. We prove that the dilation of the embedding is $2{\cdot}4^{(N-2)/3}+4)/3$. This is superior to the previous result of $4^{N+183}+2)/3$ under the same condition.condition.

Interactions between Water-Soluble Polyparacyclophanes and Drugs (II) -Interaction between Water-Soluble Polyparacyclophanes and Fluorescent Hydrophobic Naphthalene Derivatives in Aqueous Solution- (수용성 폴리파라시클로판류와 약물과의 상호작용(제 2보) -수용액중 수용성 폴리파라시클로판류와 형광 소수 나프탈렌 유도체류와의 상호 작용-)

  • Chun, In-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.18 no.3
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    • pp.113-123
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    • 1988
  • A series of water-soluble polyparacyclophanes bearing two diphenylmethane or two diphenyl ether skeletons were investigated to develop useful host compounds by using 1-anilinonaphthalene-6-sulfonate (ANS) and 2-p-toluidinylnaphthalene-6-sulfonate (TNS) as fluorescent hydrophobic substrates in aqueous solution. It was noteworthy that remarkable fluorescent enhancements and blue shifts of ANS and TNS were observed only in the presence of 1,6,20,25-tetraaza[6.1.6.1] paracyclophane (CPM 44) and 1,6,21,27-tetraaza [7.1.7.1] paracyclophane (CPM 55) for diphenylmethane skeleton, and 1,7,21,27-tetraaza-14,34-dioxa [7.1.7.1] paracyclophane (CPE 55) and 1,8,22,29-tetraaza-15,36-dioxa [8.1.8.1] paracyclophane (CPE 66) for diphenyl ether skeleton, comparing with ${\alpha}-\;and\;{\beta}-cyclodextrins$. However, their acyclic analogues such as 4,4'-dimethylaminodiphenylmethane and 4,4'-dimethylaminodiphenyl ether, and paracyclophanes whose cavities were smaller showed only small effects under the same conditions. These facts suggested that hosts and substrates were in an intimate contact which would not occur without larger structures, and thus that guest molecules were strongly incorporated in the hydrophobic cavities of these larger paracyclophanes. The effects of pH on the fluorescent intensity of ANS-CPM 44, ANS-CPM 55, ANS-CPE 55, ANS-CPE 66, TNS-CPM 44, TNS-CPM 55, TNS-CPE 55 and TNS-CPE 66 systems were not significant below pH 2.0, but their fluorescent intensities were markedly reduced with increasing ionic strength.

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Analysis of the Characteristics of a White OLED using the Newly Synthesized Blue Emitting Material nitro-DPVT by Varying the Doping Concentrations of Fluorescent Dye and the Thickness of the NPB Layer (신규 합성한 청색발광재료 nitro-DPVT를 사용한 백색 유기발광다이오드의 형광색소 도핑농도 및 NPB 층의 두께 변화에 따른 특성 분석)

  • Jeon, Hyeon-Sung;Cho, Jae-Young;Oh, Hwan-Sool;Yoon, Seok-Beom
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.4
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    • pp.379-385
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    • 2006
  • A stacked white organic light-emitting diode (OLED) having a blue/orange emitting layer was fabricated by synthesizing nitro-DPVT, a new derivative of the blue-emitting material DPVBi on the market. The white-emission of the two-wavelength type was successfully obtained by using both nitro-DPVT for blue~emitting material, orange emission as a host material and Rubrene for orange emission as a guest material. The basic structure of the fabricated white OLED is glass/ITO/NPB$(200{\AA})$/nitro-DPVT$(100{\AA})$/nitro-DPVT:$Rubrene(100{\AA})/BCP(70{\AA})/Alq_3(150{\AA})/Al(600{\AA})$. To evaluate the. characteristics of the devices, firstly, we varied the doping concentrations of fluorescent dye Rubrene from 0.5 % to 0.8 % to 1.3 % to 1.5 % to 3.0 % by weight. A nearly pure white-emission was obtained in CIE coordinates of (0.3259, 0.3395) when the doping concentration of Rubrene was 1.3 % at an applied voltage of 18 V. Secondly, we varied the thickness of the NPB layer from $150{\AA}\;to\;200{\AA}\;to\;250{\AA}\;to\;300{\AA}$ by fixing doping with of Rubrene at 1.3 %. A nearly pure white-emission was also obtained in CIE coordinates of (0.3304, 0.3473) when the NPB layer was $250-{\AA}$ thick at an applied voltage of 16 V. The two devices started to operate at 4 V and to emit light at 4.5 V. The external quantum efficiency was above 0.4 % when almost all of the current was injected.

The Historical Research into Jeol (배례(절) 역사적 고증)

  • 표성은;이길표
    • Journal of Families and Better Life
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    • v.8 no.1
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    • pp.115-127
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    • 1990
  • The Korean have admired and lived with decorums through Jeol, a representative practical formality which expresses the decorums intensively. Jeol is the way of greeting native to Korea and an intangible culture close to Korean life style. To be remained as a culture, the traditional propriety Jeol should reconcile to the present life feflecting our history. On this viewpoint, the purpose of this research is to furnish the authority of the creative inheritance on the settlement of Jeol and other decorums suitable to the present. This research is consisted of 1) the study of the meaning of Jeol and 2) the hidtorical research through records. 'Jurye' is regarded as the oldest literature on the systematic explanation about Jeol and has been very often used down the ages. Jindong in 'Jurye' and Kodu in 'Karyejipram' are the same Jeol which expresses the grief in funeral rites. In 'Seonghosaseol', Abae which stands one knee is explained and investigated as the case of offense by the literature. And it is also interpreated as a Jeol with respect, while many other Jeol is to fall an both of kness, Abae is not performed generally. 'Yeki' has brief explanation about Kongsu Manner (to hold hands), Jeol between the king and minister, host and guest, Buinbae, Jeol in custom, wedding ceremony and funeral ceremony and Jeol in drinking manner. In 'Chunchukongyangjeon'. there is the explanation about Jeol of the minister who comes back after his duty to the king. 'Sunjajiphae' interprets Bae and Kyesang and informs that Kuesu is the most respectful Jeol only to the king, 'Seojeon' proves the Jeol habitually used in all kinds of ceremonies and etiquettes. 'Jeongbomunheonbigo' introduces the custom of Jeol in Shilla, Koguryo, Buyeo, Koryo eras by using literature and shows the commoness of both kneeling down generally. The result of this research has the meaning for the creation of life culture in the basis of the spirit 'Onkojisin'(reviewing the old and learning the new) by establishing the present Jeol with tradition.

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Red Emission Properties of Organic EL Having Hole Blocking Layer (정공블록킹층을 설치한 유기 EL의 적색발광특성)

  • Kim, Hyeong-Gweon;Lee, Eun-Hak
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.6
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    • pp.17-23
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    • 2000
  • In this study, we prepared red organic light-emitting-diode(OLED) with a fluorescent dye(Sq)-doped and inserted between emission and cathode layer 1,3-bis(5-p-t-butylphenyl)-1,3,4-oxadiazol-2-yl)benzene (OXD7) or/and tris(8-hydroxyquinoline) aluminum ($Alq_3$) layers for increasing electroluminescent(EL) efficiency. This inserting effect has been observed and EL mechanism characteristics have been examined. The hole transfer layer is a N,N'-diphenyl-N,N'-bis-(3-methyl phenyl)-1,1'-diphenyl-4,4'-diamine (TPD), and the host and guest materials of emission layer is $Alq_3$ and bis[1-methyl-3,3'-dimethyl-2-indorindiylmethyl] squaraine (Sq), respectively. For the inserting of $Alq_3$, emission efficiency increased. But we can not obtained highly pure red emission owing to the emission of inserting $Alq_3$ layer. The inserting of OXD7 makes hole block and accumulate. Because of increasing recombination probability of electron and hole, highly pure red color can be held. Simultaneously brightness characteristics and emission efficiency could improve.

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Strategy for Solving Future Energy and Global Warming Using Icy materials (얼음 물질을 이용한 미래 에너지와 지구 온난화 처리 방안)

  • Shin, Kyu-Chul;Lee, Huen
    • Journal of Plant Biotechnology
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    • v.34 no.2
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    • pp.81-93
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    • 2007
  • Gas hydrates are known to form by physical interactions between host water and guest gas molecules and thus can be treated as a special type of icy materials. The gas hydrates are recently highlighted because of their use to future energy source even though they were discovered naturally in the deep-sea marine sediments a long time ago. However, the present and future urgent task is to develop the efficient and safe production technology for recovering methane from gas hydrates. Here, we propose one of potential recovery processes using swapping phenomenon occurring between gaseous carbon dioxide and methane hydrate deposits. Such a swapping process provide several technological and economical advantages over conventional processes. The carbon dioxide can be directly sequestered into methane hydrate layer and simultaneously methane can be produced with a high recovery rate more than 90%. In addition, the icy powders can be effectively used as a new medium for storing hydrogen. To increase hydrogen storage capacity the icy hydrate networks need to be redesigned to create the more empty cages in which hydrogen gas can be enclathrated. Functionalized icy materials might be used in a variety of energy and environmental fields.

The Inclusion Complex Formation of Cyclodextrin and Congo Red in Aqueous Solution (수용액상에서 Cyclodextrin과 Congo Red 간의 복합체 형성)

  • Kim, Chang Suk;Kim, Dong Won;Bahn, Woo Kyoung
    • Analytical Science and Technology
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    • v.15 no.2
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    • pp.115-119
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    • 2002
  • The formation of inclusion complexes between cyclodextrin(CD) and Congo red was studied by spectrophotometric methods at various temperatures. The cavity sizes are 0.49 nm, 0.62 nm for $\alpha$-and $\beta$-CD, respectively. Therefore, $\alpha$-CD was not found to form an inclusion complex with Congo red due to steric hinderance. In the $\beta$-CD use two $\beta$-CD molecules formed an inclusion complex with one molecule of Congo red, from the slope of the S-shaped curve increased. Two prominent isosbestic points appear at 346 nm and 478 nm. The formation constants were decreased with the increasing temperatures, due to low binding energy between $\beta$-CD and Congo red. The thermodynamic parameters were calculated from the plot of $lnK_f$ vs 1/T. The $\Delta$H, $\Delta$S and $\Delta$G were -50.73 kJ/mol, $-108.96J/K{\cdot}mol$ and -18.26 kJ/mol, respectively.

Priority-based Hint Management Scheme for Improving Page Sharing Opportunity of Virtual Machines (가상머신의 페이지 공유 기회를 향상시키기 위한 우선순위 큐 기반 힌트 관리 기법)

  • Nam, Yeji;Lee, Minho;Lee, Dongwoo;Eom, Young Ik
    • Journal of KIISE
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    • v.43 no.9
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    • pp.947-952
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    • 2016
  • Most data centers attempt to consolidate servers using virtualization technology to efficiently utilize limited physical resources. Moreover, virtualized systems have commonly adopted contents-based page sharing mechanism for page deduplication among virtual machines (VMs). However, previous page sharing schemes are limited by the inability to effectively manage accumulated hints which mean sharable pages in stack. In this paper, we propose a priority-based hint management scheme to efficiently manage accumulated hints, which are sent from guest to host for improving page sharing opportunity in virtualized systems. Experimental results show that our scheme removes pages with low sharing potential, as compared with the previous schemes, by efficiently managing the accumulated pages.

Host-Guest Interactions of Cyclic and Acyclic Polyethers with Alkylammonium Ions (고리 및 비고리 폴리에테르와 알킬암모늄 이온과의 호스트-게스트 상호작용)

  • Jeong, Jong Hwa;Kim, Dae Yeon;Lee, Sim Seong
    • Journal of the Korean Chemical Society
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    • v.38 no.7
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    • pp.509-515
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    • 1994
  • The interactions of 11 kinds of primary and secondary alkylammonium ions with cyclic (12C4, 15C5, 18C6, DT18C6 and DA18C6) and acyclic$(Q_2O_5)$ polyethers were investigated by NMR titration and conductometry. All of the alkylammonium ions under investigation form the relatively stable 1 : 1 complexes with crown ethers and acyclic polyether by H-bond. The interactions of alkylammonium ions with analogeous hosts having different size were in the order of 18C6 > 15C5 > 12C4, and the strengthes of donor atoms toward the alkylammonium ions were in the order of N > O > S. 18C6 forms more favorable interactions with primary alkylammonium ions than secondary alkylammonium ions, otherwise DA18C6 shows the opposite behaviors. The stability constants for complexations of 18C6 with the alkylammonium ions were determined conductometrically in methanol at 25$^{\circ}C$. The major factors affecting the stability of complexes were the type of alkylammonium ions, the length of alkyl-chain and the steric hindrance due to the structure of alkyl groups on complexation.

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Properties of Polymer Light Emitting Diodes Using PFO : MEH-PPV Emission Layer and Hole Blocking Layer (PFO : MEH-PPV 발광층과 정공 차단층을 이용한 고분자 발광다이오드의 특성)

  • Lee, Hak-Min;Gong, Su-Cheol;Shin, Sang-Bae;Park, Hyung-Ho;Jeon, Hyeong-Tag;Chang, Ho-Jung
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.2
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    • pp.49-53
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    • 2008
  • The yellow base polymer light emitting diodes(PLEDs) with double emission and hole blocking layers were prepared to improve the light efficiency. ITO(indium tin oxide) and PEDOT : PSS[poly(3,4-ethylenedioxythiophene) : poly(styrene sulfolnate)] were used as cathode and hole transport materials. The PFO[poly(9,9-dioctylfluorene)] and MEH-PPV[poly(2-methoxy-5(2-ethylhe xoxy)-1,4-phenylenevinyle)] were used as the light emitting host and guest materials, respectively. TPBI[Tpbi1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene] was used as hole blocking layer. To investigate the optimization of device structure, we prepared four kinds of PLED devices with different structures such as single emission layer(PFO : MEH-PPV), two double emission layer(PFO/PFO : MEH-PPV, PFO : MEH-PPV/PFO) and double emission layer with hole blocking layer(PFO/PFO : MEH-PPV/TPBI). The electrical and optical properties of prepared devices were compared. The prepared PLED showed yellow emission color with CIE color coordinates of x = 0.48, y = 0.48 at the applied voltage of 14V. The maximum luminance and current density were found to be about 3920 cd/$m^2$ and 130 mA/$cm^2$ at 14V, respectively for the PLED device with the structure of ITO/PEDOT : PSS/PFO/PFO : MEH-PPV/TPBI/LiF/Al.

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